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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Chemistry » C2H4 Molecular Geometry and Bond Angles

C2H4 Molecular Geometry and Bond Angles

C2H4 molecular geometry has a trigonal planar and undergoes sp² hybridization. The bond angle between the orbitals is 120o with no free rotation about a carbon double bond.

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C2H4 is the chemical formula of a colourless and flammable gas known as Ethylene. It is said to be a hydrocarbon that has two carbon atoms connected to it with a double bond. It is lighter than air. C2H4 is an example of sp² hybridization, meaning one s orbital, and two p orbitals are mixed to give three sp² orbitals. Here, one 2p orbital does not change, and it will help form a pi bond. Each of the sp² carbon atoms has a trigonal planar geometry and an angle of 120o between the bonds. As per VSEPR theory, C2H4 molecular geometry and electron geometry are the same, i.e. trigonal planar.

C2H4 Molecular Geometry Importance

Molecular structure defines the arrangement of atoms in a molecule or ion. In the case of C2H4 , each carbon in its molecule undergoes sp² hybridization, and the two hydrogens make the structure look like a two-dimensional triangular planar. The bonded pair of hydrogen attached to carbon repels each other, and as a result, the figure thus formed is a trigonal planar. Lewis structure helps to find out C2H4 molecular geometry as Lewis diagram determines the number of lone pairs and bond pairs a molecule comprises.

The A-X-N method can find out the C2H4 molecular geometry and bond angles. Here, the central atom is represented by ‘A’. In this case, A=1. The number of atoms that have bonded with the central atom is denoted by ‘X’. Here, the two carbon atoms are bonded, and both atoms have two hydrogen atoms attached to them. ‘N’ denotes the number of lone pairs attached to the central atom, and C2H4  has no lone pair, meaning N=0. So, we got AX3 for the C2H4  molecule by the A-X-N method. As the molecule does not have any lone pairs, we may ignore N. AX3 defines the shape of C2H4  as a Trigonal Planar with 120 degree bond angles.

C2H4 Molecular Geometry Questions

How to find out the C2H4 molecular geometry and bond angles?

The three steps to find out the C2H4 molecular geometry and bond angles are:

1. Firstly, discover the number of lone pairs that the central atom of C2H4  has.

Another term for a lone pair is unshared pair. In accordance with the Lewis structure of C2H4 , it is found that there is no lone pair present on the central atom.

We can also use the formula for the confirmation of lone pairs i.e.

L.P = (V.E – N.A)/2

L.P stands for the lone pair on the central atom, V.E stands for the Valence electron of that particular central atom, and N.A stands for the number of atoms attached to the central atom.

Valence electrons of carbon = 4. The atoms that are attached to the carbon atoms = 4

Therefore, Lone pair = (4 – 4)/2. So we got to know that the molecule has no lone pair.

2. Find out the hybridization of C2H4 

To determine the C2H4  molecular geometry, it is required to find out the hybridization of C2H4 . The formula to find out hybridization is:- H = N.A. = L.P.

H stands for hybridization, N.A. stands for the number of atoms attached to the central atom, and L.P. stands for lone pairs on that particular atom. When we look at the Lewis dot structure of C2H4 , we find out that carbon is the central atom of the molecule, and each carbon atom is linked with three atoms, i.e. one carbon and two hydrogen atoms. In the earlier step, we found that it has 0 lone pairs, so we use that information here in this formula.

H = 3 + 0

The number of hybridization comes out to be three, which means it is an sp² hybridization.

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Van’t Hoff Factor

Conclusion 

Ethylene is a colourless gas lighter than air and is also soluble in water. The chemical formula for Ethylene is C2H4  which means it has two carbon atoms and four hydrogen atoms. The two carbon atoms are linked to each other, and each atom is attached to two hydrogen atoms. C2H4  molecular geometry is a trigonal planar, and its electron geometry is also the same. The angle between the bonds is 120o. Also, the free rotation of the two carbon double bonds is restricted. We can take the help of Lewis’s structure to find out the molecular geometry as it defines the number of bond pairs and lone pairs that are contained in the molecule.

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Frequently asked questions

Get answers to the most common queries related to the JEE Examination Preparation.

Why is C2H4 in a single plane?

Ans. C2H...Read full

How many bonds are in C2H4 ?

Ans. According to the Lewis structure of C2...Read full

What type of bonds make up the C=C bond in C2H4 ?

Ans. In the molecular structure of C2H...Read full

How many σ bonds and π bonds exist in the molecule?

Ans. A sigma bond is the strongest bond formed by the overlapping of atomic orbitals, and that is why every bond mus...Read full

How is C2H4 planar?

Ans. When the structure of C2H...Read full

Ans. C2H4  is in a single plane because the two carbons molecules joined together have no free rotation about their axis. The p orbitals are upright to the plane, and the remaining σ bonds lie on the plane. It is not possible to rotate the molecule without breaking the π bond. Also, it is required for the p orbital to stay parallel to each other.

 

Ans. According to the Lewis structure of C2H4 , there are four C–H sigma bonds present and one C=C double bond, i.e. one sigma and one pi bond. The four C-H bonds contain eight shared pairs of electrons, and one C=C bond contains four shared pairs of electrons. Therefore, the total number of bonds is 12.

Ans. In the molecular structure of C2H4 , we can see that a double covalent bond is present between the two carbon atoms, and a single is present between the carbon and hydrogen atoms.

Ans. A sigma bond is the strongest bond formed by the overlapping of atomic orbitals, and that is why every bond must have at least one sigma bond. The lateral overlap makes a pi bond of atomic orbitals. There are six sigma bonds in the C2H4  molecule.

Ans. When the structure of C2H4  is drawn, it is found that both the carbon atoms are sp2 hybridised. One carbon and two hydrogen atoms together form a triangular shape, and so do the other carbon and hydrogen atoms. Also, both carbon atoms have a linear double bond, and the two hydrogen atoms connected to it are also in a plane. Therefore, C2H4  is a Planar.

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