JEE Exam » JEE Study Material » Chemistry » Why is the Hybrid Orbital during Hybridization better than their Parent Atoms?

Why is the Hybrid Orbital during Hybridization better than their Parent Atoms?

Hybridization is an example of a topic we may learn about by looking at how various atoms interact. Hybridisation will be discussed in depth in the article below, including its types, regulations, ideas, and instances. The process of joining atomic orbitals of various forms with approximately the same energy to generate the same number of hybrid orbitals with the same configuration, orientation, and energy with the least degree of repulsion is known as hybridisation. Furthermore, when any element is hybridised, it takes one of five shapes. A tutorial on the five fundamental shapes of hybridisation notes is provided here. Moreover, any molecule’s form is determined by the sort of hybridisation it experiences. Linear, trigonal planar, tetrahedral, Trigonal by-pyramidal, and octahedral are the five basic shapes.

What do you mean by hybrid orbitals?

Hybrid orbitals result from a model that combines atomic orbitals on an atom in ways that result in a new set of orbitals with geometries suitable for forming bonds in the VSEPR model’s expected directions. There are various types of configuration such as sp, sp2, and sp3.

sp

Sp hybridisation, usually known as diagonal Hybridisation, occurs when two s & one p orbitals belonging to the same primary shell of an atom combine to generate two new identical hybrid orbitals. The molecule generated as a result of this Hybridization has a linear shape with an angle of 180 degrees.

The resulting hybrid orbitals contain 50 per cent s and 50 per cent p character.

In the bond formation of compound BeH2,

  • At ground state, Be=1s22s22p0
  • At excited state, Be=1s22s12p1x2p0y2p1z

Sp2

This sort of Hybridisation is known as sp2 and occurs when one s and two p orbitals from the same main shell of an atom combine to generate three new equivalent hybrid orbitals. It is also known as Hybridization of Trigonal Hybridization. After its Hybridization, the molecule takes on the shape of a triangle planner with a 120-degree angle. The hybrid orbitals make approx. 33.33% s character & 66.66% p character.

In the bond formation of compound BH3,

  • At ground state, B=1s22s22p1x2p0y2p0z
  • At excited state, B=1s22s12p1x2p1y2p0z

sp3

When one p orbital goes in the process of mixing energy to form a new orbital, such kind of hybridisation is called sp hybridisation. The molecules possessing sp hybridization used to have a linear shape with an angle of 180°. The molecule formed as a result of this Hybridisation is tetrahedral, with an angle of 109o28′. About 25% of the hybrid orbitals generated have s character, and 75% have p character.

Importance of hybrid orbitals 

  • Orbitals belonging to the same atom and having similar energies (same shell) can hybridise
  • The number of hybrid orbitals produced is equal to the number of mixed orbitals produced.
  • The hybridisation process involves both half-filled and fully-filled orbitals
  • Only during the bonding procedure does hybridization occur
  • The form of the molecule is determined by the type of hybridisation used
  • Hybrid orbitals are equivalent in terms of energy and shape
  • Hybrid orbitals are only used to form sigma bonds

Conclusion

We learned about the numerous ideas related to hybrid orbitals and various configurations such as sp, sp2, sp3, sp3d, and sp3d2. Orbitals that have been hybridised. Because all materials in our environment behave in strange and unexpected ways, hybridisation is a critical topic. These elements’ electrical components, as well as their characteristics, are fascinating to investigate. Because of the uniqueness of their features and applications, we can come up with a variety of practical applications for such elements. When it comes to the physical attributes of the elements in our surroundings, we can notice a vast spectrum of them. Hybridisation, or how it allows for the unique mixing of different molecules, is an important topic in science.

faq

Frequently Asked Questions

Get answers to the most common queries related to the JEE Examination Preparation.

What are orbitals?

Orbital is a mathematical statement representing the properties of up to two electrons in the proximity of such a nu...Read full

What do you mean by hybrid orbitals?

Hybrid orbitals are considered to be a combination of atomic orbitals overlaid in various quantities on top of one o...Read full

Define Linear shape of hybridisation.

It is the first and most fundamental form of hybridisation. As the name implies, two orbitals are linked to one atom...Read full

What is the difference between hybrid orbitals and molecules?

The interaction of the same atomic orbitals forms hybrid orbitals, while the interaction of the different atomic orb...Read full

Write important points of hybridisation?

In atoms, hybrid orbitals need not exist. Only covalently bound atoms can generate th...Read full