JEE Exam » JEE Study Material » Chemistry » What Are Esters?

What Are Esters?

Esters are organic compounds produced from the reaction of alcohols and acids; these compounds are widely used in lubrication industries.

Esters are organic compounds; the reaction of alcohols and acids produces these compounds. Esters are vital industrial compounds and are found organically in nature. The major use of esters is in the fragrance and lubrication industries. 

Esters react with different compounds and possess different chemical properties.

They are named according to the corresponding carboxylic acids. Esters are composed of singly-bonded carbon and one double and one singly-bonded oxygen.

Esters

Let us look into the answer to the question: what is an ester? An ester is an organic compound derived from carboxylic acid in which a hydrogen atom of the hydroxyl group is replaced by an alkyl group.

Esters are named according to the carboxylic acid in their chain. 

The hydrocarbon groups can be methyl, ethyl, phenyl, or other hydrocarbon groups. Esters are commonly found in nature, in organisms, and in various chemicals. Esters have a pleasant, fruity smell to them. The easter compounds are generally used in fragrance industries. 

Important Points

  • The Esters are characterised by a carbon bound with other three different atoms in the following manner,

  1. A single bond to a carbon; 

  2. a double bond to an oxygen; 

  3. a single bond to an oxygen.

  4. The singly-bound oxygen is bonded to another carbon.

  • Names of the Ester are derived from the parent alcohol or the acid. 

  • Simple esters can be called by their regular expressions; all the esters can be named using the IUPAC naming system.

Properties of Esters

Ester compounds have the following properties:

  • Esters are colourless in nature; however, the most significant physical property of Ester is its odour. They have a pleasant smell.

  • Esters with higher acids are colourless solid compounds.

  • Esters are soluble in water in normal conditions. 

  • Esters are highly volatile and are highly flammable.

  • With the increase in the mass of Ester, the solubility in water decreases.

  • The methyl and ethyl ester compounds have lower boiling points at room temperature than the parent acids.

  • In comparison with acyl chlorides, anhydrides, and various acids, the Esters are less chemically reactive compounds.

How are Esters Produced?

Esters are formed when carboxylic acid is burned with alcohol in front of the catalyst. In this reaction, concentrated sulfuric acid is used as a catalyst, a dry form of hydrogen chloride gas is used in some cases. This reaction method is used to convert alcohol to ester.

Fischer esterification is the most general and widely used reaction for producing ester compounds. Fischer esterification reaction involves the reaction of a carboxylic acid with an alcohol and a dehydrating agent. 

RCOCl + R′OH → RCO2R′ + HCl. 

(RCO)2O + R′OH → RCO2R′ + RCO2H. 

In this reaction, sulfuric acid is used as a catalyst to increase the duration of this esterification process. A different reaction to produce ester compounds is a reaction with Acyl chlorides and acid anhydrides; this chemical reaction is called the Alcoholysis. In Alcoholysis reactions, Acyl chlorides and acid anhydrides react with alcohol compounds, and the resultant compound is an ester. 

How are Esters stored?

The Esters are stored in Carbon, aluminium, or stainless steel containers or tanks in a physical space. A storage tank is prepared by lining with baked phenolic resin to store critical Ester products. Esters are characterised by having high volatility and high flammability properties. Both the high and low boiling point esters are stored with dry nitrogen to prevent the reaction with air and moisture molecules from the storage tank.

In many industries, Ester products are transferred by using lines made up of carbon steel. The esters are used and carried out with an explosion-proof, motor-driven centrifugal pump in industries. 

Usage of Esters

Now let us look at the importance of Esters by understanding their usage.

Esters are used in the following ways:

  • Industries that manufacture perfumes, essential oils, and pheromones use various esters. 

  • In producing synthetic lubrication, Esters have been very useful in reducing the complications on the environment.

  • Due to their low-temperature flowability and high-temperature operations, esters are also used in jets as engine lubricants. 

  • Esters are also used as synthetic refrigeration lubricants. 

  • Esters are majorly used in automotive appliances. 

  • Esters have high lubrication properties; that is why esters usually are combined with Polyalphaolefins in synthetic motor oils to add additives.  

Conclusion

The above article explores the meaning and importance of esters. Esters compounds use the -oate suffix in their quotation. . The most important physical property of esters is their fragrance. These compounds are widely used in fragrance and lubrication industries. Because esters are highly reactive with the atmosphere and have high inflammation properties, they are stored with liquid nitrogen to avoid accidents.

faq

Frequently Asked Questions

Get answers to the most common queries related to the JEE Examination Preparation.

What are the main components of organic chemistry?

Ans. There are mainly four elements that are considered essential to organic chemistry; the four elements are Hydrog...Read full

What are hydrocarbons?

Ans. Any element made up of hydrogen and carbon molecules is called a hydrocar...Read full

How are organic and inorganic compounds different?

Ans. Organic compounds are those carbon-containing compounds derived from living organisms or are directly derived f...Read full

What are the boiling point properties of Esters?

Ans. The boiling points of most ester compounds are generally low at room temperatures. ...Read full