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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Chemistry » Uncertainty Principle

Uncertainty Principle

In this lecture we are going to learn about Catenation definition of Catenation and Catenation of carbon and hydrogen

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Introduction

The uncertainty principle is without a doubt one of the most well-known parts of quantum mechanics, if not the most famous. It has frequently been cited as the greatest distinguishing aspect of quantum mechanics as compared to classical models of the physical world, and for good reason. The uncertainty principle (for position and momentum) asserts, in broad terms, that one cannot give exact simultaneous values to the position and momentum of a physical system because of the uncertainty principle. This is because the values of these quantities can only be determined with some characteristic “uncertainties” that cannot all be reduced to zero at the same time. But what exactly is the meaning of this principle, and is it even a quantum physics principle in the first place? Is it indeed a principle of quantum mechanics? (In his initial work, Heisenberg only refers to uncertainty relations as a type of relation.) And, more specifically, what does it mean to say that a quantity is only determined up to a given degree of uncertainty? These are the central problems that we shall examine in the next sections, with a particular emphasis on the perspectives of Heisenberg and Niels Bohr.

In the physical literature, the concept of “uncertainty” is used in a variety of ways to indicate different things. For example, it could refer to an observer’s inability to recognise a quantity, or to the experimental inaccuracy with which a number is measured, or to some ambiguity in the definition of a quantity, or to a statistical dispersion among an ensemble of similarly prepared systems. Furthermore, such uncertainties are referred to by a variety of other terms, including inaccuracy, spread, imprecision, indefiniteness, indeterminateness, indeterminacy, latitude, and so on. Even Heisenberg and Niels Bohr, as we will see, could not agree on a single language for quantum mechanical uncertainties. To avoid a debate about which name is the most appropriate in quantum mechanics, we will just refer to the principle as the “uncertainty principle” because it is the most commonly used in the literature, which will save time.

Heisenberg’s uncertainty principle

Heisenberg’s uncertainty principle argues that it is impossible to precisely measure or compute both the position and the momentum of an item at any time in the past. This principle is founded on the fact that matter is both a wave and a particle. When it comes to the macroscopic world, Heisenberg’s uncertainty principle can be ignored (the uncertainties in the location and velocity of objects with relatively large masses are small), but it has a huge impact when it comes to the quantum world. Given the extremely small masses of atoms and subatomic particles, any improvement in the precision of their positions will be matched by an increase in the uncertainty associated with their velocities.

Heisenberg’s uncertainty principle is a fundamental theory in the realm of quantum mechanics that explains why it is impossible to measure more than one quantum variable at the same time. According to yet another implication of the uncertainty principle, it is impossible to obtain an exact measurement of the energy of a system in a finite amount of time. When measuring both position and momentum simultaneously, Heisenberg’s uncertainty principle imposes a restriction on the precision of the measurement. It follows that the more precise our measurements of location are, the less precise our measurements of momentum will be and vice versa. The quantum system is where the Heisenberg uncertainty principle has its physical origins in terms of physics. The process of determining position by taking a measurement on the system causes it to be sufficiently disturbed that the determination of q becomes imprecise, and vice versa. We will learn more about this principle in greater depth later on.

As stated by Heisenberg’s uncertainty principle, it will not be feasible to precisely estimate both the position and the velocity of particles that show both particle and wave natures at the same time. The uncertainty principle is named after the German scientist Werner Heisenberg, who proposed it in the year 1927 and was the first to use it. When Heisenberg was attempting to construct an intuitive model of quantum physics, he came up with this concept to guide him. He recognised that there were some underlying limitations that hindered our ability to know specific quantities when we tried to act on them.

This principle essentially states that when measuring the position and the velocity or momentum of microscopic matter waves at the same time, an error will be introduced such that the product of the errors in measuring the position and the momentum is equal to or greater than an integral multiple of a constant will be introduced.

It is exclusively due to the wave-particle duality of a wave that one of the pivotal moments in the development of the uncertainty principle can be traced. Every particle is believed to have a wave nature, and the likelihood of detecting particles is highest in the areas where the waveforms are the most prominent and complex. A larger degree of undulation in the particle results in a wavelength that is more unclear or ambiguous. We are, on the other hand, able to determine the particle’s angular momentum. Based on everything we’ve learned so far, we can conclude that particles with known positions will not have a fixed velocity. A particle with a well-defined wavelength, on the other hand, will have a decisive or precise velocity when observed. Overall, if we have an accurate reading of one quantity, this will only result in a significant amount of ambiguity in the measurement of the other quantity.

Formula and Application

For example, if x denotes the error in location measurement and p is the error in momentum measurement, the equation

∆X × ∆p ≥ h/4π

Because momentum is equal to mass times velocity, Heisenberg’s uncertainty principle formula can be stated as follows:

∆X × ∆mv ≥ h/4π

or ∆X × ∆m × ∆v ≥ ​h/4π

Where V denotes the inaccuracy in the measurement of velocity, and mass denotes the assumption that mass remains constant during the experiment,

∆X × ∆V ≥ h/4πm

Position and momentum measurements are accurate, and this immediately suggests a greater degree of uncertainty (error) in the measurement of the other component.

By putting the Heisenberg principle into practise with respect to an electron in an atom’s orbit, with h = 6.626 10-34 Js and m = 9.11 10-30 kg, we may find that

∆X × ∆V ≥10-4 m2 s-1.

If the position of the electron is properly measured to its size (10-10m), the inaccuracy in the measurement of its velocity will be equal to or greater than 106m or 1000Km, respectively.

The Heisenberg principle applies only to dual-natured microscopic particles and not to a macroscopic particle with a very modest wave nature, as is the case with microscopic particles.

CONCLUSION

Electrical and magnetic radiations, as well as microscopic matter waves, have a dual nature that includes both mass/momentum and wave character. It is possible to properly detect the position, velocity, and momentum of macroscopic matter waves at the same time. For example, it is possible to identify the location and speed of a moving car at the same time with the least amount of mistake. Nonetheless, in the case of minuscule particles, it will not be able to fix the particle’s position while also measuring the particle’s velocity or momentum.

faq

Frequently asked questions

Get answers to the most common queries related to the JEE Preparation.

In what year did the first person come up with the concept of finding an electron in an orbital?

ANS.In his own words, Heisenberg was the first to conceive about or develop this concept.

Is it possible to ascertain that an electron is placed at a specific exact location with 100 percent accuracy at a specific fixed time by measuring its position and speed?

ANS.No, we are unable to do so.

What scientists came up with the concepts of the uncertainty principle and the wave nature of matter? Who were the thinkers behind these concepts?

ANS.It was Heisenberg and de Broglie who were involved.

What is an example of a violation of the Heisenberg uncertainty principle?

ANS.If an item going through spacetime has the ability to loop back in time in a specific fashion, then the trajecto...Read full

Why is the Heisenberg uncertainty principle not applicable for a bigger molecule?

ANS. The uncertainty is too small to notice. It only notices microscopic particles. This is the reason why the Heise...Read full

ANS.In his own words, Heisenberg was the first to conceive about or develop this concept.

ANS.No, we are unable to do so.

ANS.It was Heisenberg and de Broglie who were involved.

ANS.If an item going through spacetime has the ability to loop back in time in a specific fashion, then the trajectory of that object may allow a pair of its components to be measured with perfect accuracy, thus violating Heisenberg’s principle of uncertainty.

ANS. The uncertainty is too small to notice. It only notices microscopic particles. This is the reason why the Heisenberg uncertainty principle is significant only for the smaller particles.

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