Types of Hybridisation

Hybridisation is a concept in organic chemistry used to explain chemical bonding when the valence bond theory fails to provide an adequate explanation. This hypothesis is beneficial for explaining organic molecules’ covalent bonding. Hybridisation is the intermixing of atomic orbitals of various shapes with approximately the same energy to produce the same number of hybrid orbitals with the same condition, energy, or orientation, with the most negligible repulsion between them. So let’s discuss more about types of hybridisation in detail. For better understanding you must read this topic thoroughly. You will clear all your doubts. 

Types of Hybridisation

Depending on the types of orbitals included in mixing, hybridisation could be characterised as sp³, sp², sp, sp³d, sp³d², or sp³d³

sp Hybridisation

Sp hybridisation is a type of hybridisation in which only the 1s and 1p orbitals of the same element are involved. The production of the acetylene molecule is an instance. 

sp² Hybridisation

Sp² hybridisation combines and recasts nearly identical 1s and 2p orbitals of the same atom to generate three new sp² hybrid orbitals with equal energies, maximal symmetry, and determinate orientation in space. Consider the synthesis of an ethylene molecule.

sp³ Hybridisation

sp³ hybridisation is a type of hybridisation in which 1s and 3p orbitals of the same element are mixed and recast to generate a new hybrid orbital with the same energy, symmetry, or fixed orientation in space. Types of hybridisation examples include the development of a methane molecule.

sp³d Hybridisation

The hybridisation is termed sp³d whenever 1s and 3p orbitals of the same element mix and recast to generate hybrid orbitals with the same energies or equal orientation in space. PCl₅ is an example of a molecule. The central phosphorus atom in PCl₅ experiences sp³d hybridisation, resulting in the formation of five sp³d hybrid orbitals.

sp³d² Hybridisation

sp³d² hybridisation occurs when 1s, 3p, and 2d-orbitals of the same elements combine and recast to generate hybrid orbitals with the same energy and equal orientation in space. The formation of SF₆ demonstrates this hybridisation.

Rules for Identifying the Types of Hybridisation

• Follow the methods below to identify the type of hybridisation in a chemical or an ion.

• Determine the system’s total number of valence electrons.

• Calculate the number of duplex and octets.

• The number of electrons in a lone pair

• The number of occupied orbitals is calculated by multiplying the number of duplex and octets by the electron density in lone pairs.

• If there are no lone pairs of electrons, the orbitals or molecules seem to have the same form.

Types of Hybridisation and Their Nature

Hybridisation, as a concept, assists in the understanding of molecular structure and shape. The shapes of the molecules are summarised in the table below:

As a result of the preceding material, we may deduce that hybridisation is a mathematical notion in which atomic orbitals are mixed to generate new hybrid orbitals appropriate for electron pairing to produce chemical bonds in the valence bond theory. A hybrid orbital is generated when an altogether new orbital is distinct from its constituents.

Features of Hybridisation

• Hybridisation happens when the energies of atomic orbitals are equivalent.

• The number of atomic orbitals that mix equals the number of hybrid orbitals generated.

• Hybridisation does not necessitate the participation of all half-filled orbitals. Even orbitals that are filled and have a little different energy can take part.

• During bond formation, hybridisation happens, not in a single gaseous atom.

• You could anticipate the shape of a molecule if the hybridisation of the molecule is understood.

• The hybrid orbital’s larger lobe always seems optimistic, whereas the smaller lobe on the opposite end has always been negative.

Conclusion

Hybridisation is mixing atomic orbitals of diverse forms and then almost identical electricity to produce a range of hybrid orbitals with the same shape, electricity, or orientation, with the least amount of repulsion between them. Quantum mechanics lies at the heart of this admixture. The atomic orbitals with the same power level may participate in hybridisation the best. Each full-crammed and half-crammed orbital could also participate in this procedure if given the same amount of electricity. The atomic orbitals of comparable electricity are mixed during the hybridisation process, including mixing two ‘s’ orbitals or ‘p’ orbitals, mixing an ‘s’ orbital with a ‘p’ orbital, and an ‘s’ orbital with just a ‘d’ orbital.