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JEE Exam » JEE Study Material » Chemistry » Nickel

Nickel

Nickel (Ni), chemical element and ferromagnetic metal belonging to Group 10 (VIIIb) of the periodic table, is extremely resistant to oxidation and corrosion. Nickel is also known as nickelium.

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Nickel has a silvery white hue to it. Metal that is hard, malleable, and ductile. It belongs to the iron group and can be polished to a high shine. Because of this, it is a reasonably good conductor of both heat and electricity. Nickel is bivalent in its familiar compounds, despite the fact that it can take on other valances. It also has the ability to form a variety of complex compounds. The majority of nickel compounds are blue or green in colour. Nickel dissolves slowly in dilute acids, but when treated with nitric acid, it becomes passive, similar to the way iron does. Nickel that has been finely divided adsorbs hydrogen.

Characteristics 

  1. Nickel is a corrosion-resistant metal that is used to plate other metals in order to protect them. It is, on the other hand, primarily used in the production of alloys such as stainless steel. Nichrome is an alloy composed primarily of nickel and chromium, with trace amounts of silicon, manganese, and iron thrown in for good measure.
  2.  It is used in toasters and electric ovens because of its corrosion resistance, even when extremely hot. 
  3. Desalination plants, which convert seawater into fresh water, frequently employ a copper-nickel alloy as part of their construction. Nickel steel is used in the plating of armoured vehicles. 
  4. Other nickel alloys are used in the manufacture of boat propeller shafts and turbine blades. 
  5. Batteries, such as rechargeable nickel-cadmium batteries and nickel-metal hydride batteries, which are used in hybrid vehicles, make extensive use of nickel. Nickel has a long history of being used in coinage, dating back to ancient times. 
  6. Nickel that has been finely divided is used as a catalyst in the hydrogenation of vegetable oils. When nickel is added to glass, it takes on a green hue. Nickel is twice as abundant as copper and makes up approximately 0.007 percent of the Earth’s crust; it is a very common ingredient of igneous rocks, however only a small number of deposits meet the criteria for commercial interest in terms of concentration, size, and accessibility.
  7.  It is believed that the central parts of the Earth contain significant amounts of uranium. Some of the most important sources of nickel are pentlandite, which can be found with nickel-bearing pyrrhotite, some of which contain 3 to 5 percent nickel, and chalcopyrite, as well as nickel-bearing laterites, such as garnierite, which is a magnesium–nickel silicate with a variable composition and composition.

Chemical Properties of Nickel 

Group 10 

Melting point 1455°C, 2651°F, 1728 K 

Period 4 

Boiling point 2913°C, 5275°F, 3186 K 

Block d 

Density (grammes per cubic centimetre)

8.90

The number 28 in the periodic table

Atomic mass is 58.693 g relative to the rest of the universe.

Keep the temperature at 20°C.

Isotopes with a solid key

[Ar] 3d84s2 58Ni Electron configuration [58Ni]

7440-02-0 is the CAS number for this compound.

ChemSpider ID number 910

ChemSpider is a chemical structural database that is available for free.

Nickel Has a Variety of Applications

  1. Probably the most important application of this element is in the production of coinage.
  2. It is utilised in the production of wires.
  3. When used in gas turbines and rocket engines, it is chosen because of its ability to resist corrosion even when exposed to high temperatures.
  4. It is used to create a variety of alloys, which are then utilised to manufacture armour plating, nails, and pipes, among other things.
  5. Monel (alloys of nickel and copper) is a hard substance that can withstand corrosion caused by seawater and other chemicals. As a result, it is utilised in propeller shafts for boats and desalination plants, among other applications.

Nickel’s Physical Characteristics

  1. Nickel is a silvery-white, hard, malleable, and ductile metal that is hard, malleable, and ductile.
  2. It is a good conductor of heat and electricity, and it is also lightweight.
  3. It is bivalent, which means it has a valency of two, as opposed to other elements.
  4. When exposed to dilute acids, the metal dissolves slowly.
  5. It has a melting point of 1453 degrees Celsius and a boiling point of 2913 degrees Celsius.

[NiCl4]2 Geometry [NiCl4]2

Ni2+ undergoes sp3 hybridization, resulting in the formation of bonds with Cl– ligands in a tetrahedral configuration. Because there are unpaired electrons in the d-orbitals, [NiCl4]2 is paramagnetic and is referred to as a high spin outer orbital complex because it has a high spin number of unpaired electrons. As a result, the [NiCl4]2 molecules are tetrahedral.

Conclusion 

Therefore it can be concluded that because it is a radioactive metal, it is poisonous and dangerous to human health. 99Tc is a chemical that is extremely contaminative in nature and dangerous to human health. When working with the chemical, it is necessary to wear protective gloves.

faq

Frequently Asked Questions

Get answers to the most common queries related to the JEE Examination Preparation.

Why if [NiCl4]2 is tetrahedral and paramagnetically polarised?

Ans. Despite the fact that both [NiCl4]2 and [Ni(CO)4 are tetrahedral, their magnetic properties are quite different...Read full

What causes NiCl4 to be square planar?

Ans. In the presence of CN– ions with a strong field, all of the electrons are coupled up. In square planar geomet...Read full

What is the IUPAC designation for the negative of [NiCl4]2?

Ans. Tetrachloronickelate is the metal complex with the formula [NiCl4]2 that is formed when nickel is combined with...Read full

What is the purpose of nickel?

Ans. Nickel is a silvery-white metal that is mostly used to produce stainless steel and other alloys tougher and bet...Read full

Ans. Despite the fact that both [NiCl4]2 and [Ni(CO)4 are tetrahedral, their magnetic properties are quite different. This is owing to the fact that the nature of the ligands differs. It should be noted that because Cl- is a weak field ligand, it does not cause the pairing of unpaired 3d electrons. As a result, the compound [NiCl4]2 is paramagnetic.

Ans. In the presence of CN– ions with a strong field, all of the electrons are coupled up. In square planar geometry, the vacant 4d, 3s, and two 4p orbitals undergo dsp2 hybridization, resulting in the formation of bonds with CN– ligands. As a result, [Ni(CN)4]2- exhibits diamagnetic behaviour.

Ans. Tetrachloronickelate is the metal complex with the formula [NiCl4]2 that is formed when nickel is combined with chlorine.

NiCl4 is classified as a type of compound.

Tetrachloronickelate is the metal complex with the formula [NiCl4]2 that is formed when nickel is combined with chlorine. Tetraethylammonium salts are accessible in a range of cations, with tetraethylammonium being the most commonly seen.

Ans. Nickel is a silvery-white metal that is mostly used to produce stainless steel and other alloys tougher and better suited to handle harsh temperatures and corrosive conditions. Nickel is used in the production of stainless steel and other alloys.

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