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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Chemistry » Liquid Meniscus in Capillarity

Liquid Meniscus in Capillarity

This article considers the issue of the state of the capillary meniscus around a charged colloidal molecule, which is appended to a liquid interface: oil, water or air, water.

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A meniscus is a curve in the surface of a molecular substance (water) when it encounters another material. Imagine water holding to the inside of a glass to get a sense of what it’s like. Adhesion is responsible for a meniscus, and this has to do with the high surface tension of water. The molecules in the glass beaker’s wall attract water molecules. And since water molecules prefer to stick together, when the molecules contacting the glass adhere to it, more water molecules latch to the ones touching the glass, forming the meniscus. The word “cohesion” refers to the intermolecular connection between structurally or functionally related (other water molecules in this case).

Liquid meniscus in capillarity  

Capillary action

In a small space, a liquid can flow. Capillary action occurs when the connection to the dividers is more grounded than the strong forces between the liquid atoms. They’ll ascend the glass as far as the powerful water forces will let them until gravity prevents them from rising any higher. A molecule’s intermolecular attraction to another atom is known as union (other water particles for this situation).

The surface tension makes the water rise into the tube, while the bond makes the water adhere to the sides, and attachment carries the other particle with it. The more modest the tube measurement, the higher the water will rise because of surface tension. Trees utilise a capillary action to help water from their foundations to their leaves through their dainty veins.

Liquid Meniscus Profile

The electric field created by charges at the molecule/non-polar liquid limit affects the meniscus profile. The focus directions from the meniscus surrounding silanized glass circles connected to the tetradecane/water interface were digitised. The hypothetical meniscus form is calculated using three methods, yielding mathematically surprising results. For sufficiently small particles, it has been shown that the meniscus profile may be conveyed as a superposition of pure electric and gravitational disfigurements.

Taking Measurements With a Liquid Meniscus in Capillarity  

The estimate must depict the meniscus when reading a scale on a holder with a liquid meniscus in capillarity, such as a graded chamber or volumetric carafe. Make sure the line you’re looking at is parallel to the meniscus’s focus point. This is the lowest section of the meniscus for water and most liquids. When estimating mercury, start at the highest point of the meniscus. Regardless, you’re guessing based on the meniscus’s focal point. Make sure the liquid is level for a level meniscus.

In most cases, mounting the compartment on a lab seat will suffice. You won’t be able to look at the liquid level or down into it. Bring the meniscus up to eye level.

You can either get the dishes to carry it to your level or, in all likelihood, twist down to take estimations in circumstances where you’re worried about dropping the holder or spilling its substance. Utilise a similar strategy to take estimations each time to ensure that any mistakes you cause will be predictable. Great arrangements between the forecasts and the estimations are detectable, assuming that a dependable model for the unique contact point is accessible. Albeit just the capillary-rise issue is exhibited, the idea of this technique is similarly relevant to a free surface stream nearby a contact line where good power rules the stream.

Liquid Meniscus in Capillarity Examples

  1. If Fc = √2Fa tan α = ∞ ∴ α = 900 

(where α is angle of contact ,Fc is force of cohesion and Fa  is force of adhesion)

The resultant power acts upward and downward. Henceforth the liquid meniscus should be even. 

Model: Pure water in a silver-covered capillary tube.

  1. Fc < √2Fa tan α = positive ∴ α is an intense point, the resultant power coordinated external the liquid. Henceforth, the liquid meniscus should be sunken vertical. 

Model: Water in a capillary glass tube.

  1. Fc > √2Fa tan α = negative ∴ α is the coldhearted point. The resultant power is coordinated inside the liquid. Subsequently, the liquid meniscus should be arched vertical.

Model: Mercury in a capillary glass tube.

Why Does a Meniscus Occur at the Outer Layer of a Liquid?

The meniscus is the bend brought about by surface tension on the upper surface. It may very well be either curved or sunken. A raised meniscus happens when the atoms have a more grounded appreciation for one another (attachment) than for the holder (bond) material, making the outer layer of the liquid cavern descend.

Conclusion

Liquids that rise in small-bore tubes placed into the liquid are said to wet the tube, but liquids that are depressed inside thin tubes below the surface of the surrounding liquid do not wet the tube. Water is a liquid that wets capillary glass tubes; mercury does not. Capillarity is absent when the surface is not moist. Capillarity is the outcome of surface or interfacial forces. The rise of water in a thin tube put in water is generated by forces of attraction between the molecules of water and the glass walls and among the molecules of water themselves. The gravitational pull of the water column that has reached a specific height is countered by these attractive forces.

faq

Frequently Asked Questions

Get answers to the most common queries related to the JEE Examination Preparation.

How can capillary rely upon the state of the liquid meniscus in a tube?

Ans: When liquid water is constrained in a tube, the surface (meniscus) develops a sunken appearance because water w...Read full

What is responsible for the capillary action property of liquids?

Ans . A fine action happens because water is tacky, on account of the powers o...Read full

How might we decide the volume of a liquid with a meniscus that bends up?

Ans : It reveals that the liquid has more grounded glue force than durable pow...Read full

Do all liquids have capillary action?

Ans : Not all liquids are great at capillary action. It will not work out in case a liquid’s durable powers ar...Read full

For what reason does water rise in the capillary tube?

Ans:” Water rises inside the capillary tube because of the bond between water atoms and the glass dividers of ...Read full

Ans: When liquid water is constrained in a tube, the surface (meniscus) develops a sunken appearance because water wets the surface and creeps up the wall. The lasting powers within the drops are more grounded than the adhesive powers between the drops and the glass. Thus, mercury does not wet the glass.

Ans . A fine action happens because water is tacky, on account of the powers of union (water particles like to remain nearby) and grip (water atoms are drawn in and stick to different substances)

Ans : It reveals that the liquid has more grounded glue force than durable power when it bends upwards. When the liquid meniscus bends up in an aligned compartment, the volume isn’t completely determined by examining the bending point’s lower end characteristics.

Ans : Not all liquids are great at capillary action. It will not work out in case a liquid’s durable powers are more grounded than its bond to another surface. Mercury is a simple illustration of this.

Ans:” Water rises inside the capillary tube because of the bond between water atoms and the glass dividers of the capillary tube. This grip, along with surface pressure in the water, delivers an outcome called capillarity, with a trademark inward surface.

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