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Enthalpy of Solution

The complete UPSC notes on Enthalpy Of Solution Of CuSO4 by Unacademy. Electrolysis CuSO4, CuSO4 aqueous are all discussed here.

CuSO4 aqueous is the chemical formula of copper sulfate pentahydrate and is referred to as CuSO4. Used in hydroponics and gardening applications, used as a preservative and fungicide, and to lower the pH in swimming pools.

What is Enthalpy of the solution of CuSO4?

  • When a process occurs under constant pressure, the amount of heat absorbed or released is equal to the change in enthalpy. However, since “enthalpy” is a fascinating and unique word, most people choose to use it instead of the more often used “heat content” terminology. 

  • Entropy and enthalpy are both derived from the Greek word for “turning,” and they are both derived from the term for “warming,” respectively. When it comes to pronunciation, the first syllable of entropy is often emphasised, while the second syllable of enthalpy is typically emphasised. 

  • The enthalpy of solution of CuSO4 is -16 kcal and that of CuSO4.

  • It is referred to as the enthalpy change of solution because it measures the amount of heat that is either emitted or absorbed during the dissolution process (at constant pressure).

Electrolysis CuSO4 

  • When we dissolve an electrolyte in water, its molecules break apart into positive and negative ions, despite the fact that its atoms are securely linked together by ionic bonds. Positively charged ions are called cations, whereas negatively charged ions are called anions. In the solution, both cations and anions are free to move about. 

  • When copper sulphate, also known as CuSO4, is introduced to water, it dissolves. CuSO4 splits into Cu+ + (cation) and SO4-(anion) ions and moves freely in the solution since it is an electrolyte.

  • Two copper electrodes will now be immersed in the solution.

  • Cu+ + ions (cation) will be drawn to the cathode, which is the electrode attached to the battery’s negative terminal. Each Cu+ + ion will accept electrons from the cathode and become neutral copper atoms when it reaches the cathode.

  • Similarly, the SO4 (anion) ions will be drawn to the anode, which is the electrode attached to the battery’s positive end. As a result, SO4 ions will migrate to the anode, where they will give up two electrons and form the SO4 radical.

  • However, since the SO4 radical cannot exist in an electrically neutral state, it will attack the copper anode and produce copper sulphate.

  • After accepting electrons, neutral copper atoms are deposited on the cathode in the procedure described above. Simultaneously, SO4 interacts with the copper anode to form CuSO4, but it cannot exist as a single molecule in water, thus CuSO4 splits into Cu+ +, SO4 and dissolves in water. 

  • As a result, copper is deposited on the cathode during electrolysis CuSO4 using copper electrodes, and the same quantity of copper is removed from the anode. If we utilise carbon electrodes instead of copper or other metal electrodes during copper sulphate electrolysis, the electrolysis reactions will be somewhat altered. Because SO4 cannot combine with carbon, it will react with the water in the solution, forming sulfuric acid and liberating oxygen.

  • Electrolysis is the term for the procedure mentioned above.

CuSO4 aqueous 

CuSO4 aqueous solution is acidic in nature because copper sulphate dissolves in water and then undergoes a chemical reaction, resulting in acidity. CuSO4 (s) + 2H2O = CuOH2l + H2SO4 (aq) CuSO4 (s) + 2H2O = CuOH2l + H2SO4   (aq) As we can see from the chemical equation above, the sulphuric acid produced is a strong mineral acid, which causes the acidity of the solution to rise. 

Conclusion

The enthalpy of solution of CuSO4 is 16 kcal.  Electrolysis is an electrochemical process in which current flows from one electrode to the next in an ionised electrolyte solution. Positive ions, or cations, are drawn to the negative electrode, or cathode, while negative ions, or anions, are drawn to the positive electrode, or anode.

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