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Chemical Properties of Hydrogen

Hydrogen gas is very combustible and burns at quantities ranging from 4% to 75% by volume. Learn the chemical properties of hydrogen.

The most common element in the universe is hydrogen. Its name is derived from the Greek terms hydro, which means water, and genes, which means to create. In its molecular state, it is found as dihydrogen. It is the most essential component of the solar system, accounting for 70 per cent of the Earth’s total mass. Hydrogen makes up the majority of large planets like Jupiter and Saturn. When the Earth’s crust and seas are merged, it makes up 15.4 per cent of the planet’s surface.

Chemical Properties Of Hydrogen

The Hydrogen gas (H2) is very combustible and would burn in the open air at quantities ranging from 4 per cent to 75 percent by volume. The below equation describes the combustion enthalpy of hydrogen, which is -286 kJ/mol.

2H2 (g) + O2 (g)  →  2H2O (l) + 572kJ (286kJ/mol H2)

In a chlorine-hydrogen mixture, hydrogen gas might explode. A heat, spark, or even sunshine can cause specific mixes to explode. The temperature for hydrogen autoignition (spontaneous combustion) occurs at 500 degrees Celsius. UV light is emitted by refined hydrogen-oxygen flames, undetectable to the naked eye. So, as a result, detecting the burning hydrogen (H) leak is risky and necessitates using the flame detector. 

Hydrogen flames rise quickly in the air and cause minor damage as hydrocarbon fires because hydrogen is buoyant. H2 reacts with oxidising elements, reacting violently and spontaneously with fluorine and chlorine to generate hydrogen halides.

Despite its stability, H2 forms compounds with most elements. Hydrogen could have a half positive charge when reacting with high electronegative elements like oxygen or halogens. Still, it shows half negative charge when reacting with more electro-positive compounds like alkali metals. 

Hydrogen could participate in a type strength non-covalent bonding known as hydrogen bonding when it interacts with fluorine, oxygen, or nitrogen. Hydrogen bonding is essential for the stability of many organic molecules. Hydrides are chemical compounds that have hydrogen bonds with metalloids and metals.

The H+ ion is formed when hydrogen is oxidised and removes its electron. The hydronium ion (H3O+) is the name given to H+ in the aqueous solutions. In acid-base chemistry, this species is required.

Enthalpy of fusion(KJ/mol) 

0.117

Ionisation enthalpy(KJ/mol) 

1312

Reaction with halogens Forms 

Halides

Reaction with metals 

Forms Metal hydrides

Reaction with nitrogen 

Forms Ammonia

Bond dissociation enthalpy (KJ/mol)

435.98

Electron gain enthalpy (KJ/mol) 

-73

Isotopes of the Hydrogen

1H, 2H, and 3H are the three isotopes of hydrogen that exist in nature. Protium is the formal term for 1H, which occurs in 99.98% abundance. Deuterium is a chemical element with 1 proton, 1 electron, and 1 neutron. Tritium is a chemical element with 1 proton, 1 electron, and 2 neutrons. It is radioactive & has a half-life of 12.32 years before decaying into helium-3 via beta decay.

Chemical structure of Hydrogen

In the nucleus of hydrogen, there is one positively charged proton, one negatively charged electron, and zero, one or two neutrons. Isotopes are different forms of the same chemical that have different neutron counts. The number of neutrons in the nucleus influences the mass of the hydrogen atom. It’s important to distinguish between hydrogen isotopes and hydrogen allotropes.

Importance of Hydrogen 

  • The hydrogenation of the vegetable oils such as cottonseeds, soya beans, and others produces dihydrogen, which is utilised to produce vanaspati fat.

  • It’s used to make a lot of organic compounds, including methanol. In the existence of a cobalt catalyst, CO (g) reacts with 2H2 (g) to produce methanol.

  • It is primarily utilised in the production of metal hydrides.

  • Hydrogen is necessary to produce hydrogen chloride, a precious chemical.

  • It is used to convert strong metal oxides to metals in metallurgical processes.

  • It is used as rocket fuel in space research.

  • Hydrogen is utilised to make ammonia, then used to make nitric acid and nitrogen-based fertilisers.

Conclusion

In this article, we covered the chemical properties of hydrogen, its chemical structure and its uses. Hydrogen, with the simplest atomic structure H2, is the most abundant element in the universe and the third most abundant on Earth’s surface. It is prepared in laboratories, industries and institutions by different chemical processes. It is one of the most crucial compounds used as the fuel in rockets, used as a reducing agent in metallurgy, in the production of vegetable ghee etc. The various compounds of hydrogen are water, hydrides and hydrogen peroxide.

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