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JEE Exam » JEE Study Material » Chemistry » Bond Angle

Bond Angle

The following article explains what a bond angle is, its necessity and its role in bond formation with the help of different parameters.

Table of Content
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We study a wide range of subjects, some of which are interrelated. One such relation between math and science is the bond parameters like angle, length, etc., which go hand in hand with geometrical bond formation among atoms. Different atoms come together to give and take electrons, or share electrons between them to acquire stability. 

When this formation of bonds takes place, various mathematical parameters are responsible for the correct geometry to take shape. These geometrical parameters are vital because they are the basis of the proper structure and stability of molecules and compounds.

The different parameters that need to be taken into account are:- 

  1. Bond angle
  2. Bond length
  3. Bond enthalpy, etc.

The primary differences between molecular and electron geometry can be defined as follows:

  1. Molecular geometry is the arrangement of atoms with a central atom in 3-dimensional space. 
  1. On the other hand, electron geometry is the arrangement of electron groups. 

The VSEPR structure predicts the 3D shape of molecules and ions but is ineffective in presenting detailed statistics regarding the bond size or the bond itself.

VSEPR models are based totally on the idea that electrons around a central atom will configure themselves to reduce repulsion, which dictates the molecule’s geometry.

It can predict the structure of almost all compounds that have a central atom.

What is a bond angle? 

Different molecules or compounds are formed based on various critical structural parameters. One such parameter is the bond angle. It is an essential parameter because if the angle between the attached electrons or atoms is incorrect, the atom becomes unstable and cannot survive in the environment. Thus, when the different atoms form bonds, they are not explicitly acquiring stability if the angles are not respectfully satisfied.

We can define the bond angle as a geometric angle between two adjacent bonds. 

In the case of covalent bond molecules, it originates from the same atom.

A good understanding of the variations of the chemical bond from quantum chemical calculations is now seen in modern chemistry.

Configuration

Linear

Trigonal

Tetrahedral

Bent

Trigonal pyramidal

Bonding Attachments

2

3

4

3

4

Hybridization

sp

sp2

sp3

sp2

sp3

Bond Angle

180°

120°

109.5°

118°

<109.5°

The bond angle of some molecules     

The geometry and bond angle of H₂O

Before we move ahead and solve the geometry of the particular molecule, it is necessary to examine the number of electrons participating in bonding and the rest of the free electrons existing as lone pairs.

In this case, the molecular geometry of water would be bent. Notice that four electrons are attached, surrounding the center atom of oxygen. This would make the electron geometry tetrahedral, or so they thought. But, this generally is not the outcome of the molecular structure. Two of these attachments are bonds, and the other two are lone pairs. Therefore, the resulting molecular geometry is a bent structure. 

Now that we recognize the geometry of the water molecule, we can find out the bonds present in the structure from a 105° perspective to essentially be about from our chart, which is relatively significant.

The geometry and bond angle of BF3

If we draw the geometrical structure for boron trifluoride, we will see three attachment points and three bonds linked to the central boron atom, which is reasonably significant. 

Based on the chart, the molecular geometry for boron trifluoride would be trigonal planar form, with a perspective of 120° between the bonds present in the structure, which is reasonably significant.

Conclusion    

The molecule formation takes specific geometry for each one, which is only possible while considering the different bond parameters. Bond angle is one kind of parameter that helps in molecular structure formation. It can be defined as the geometric angle between the two adjacent bonds of the same molecule. For better understanding, we can consider the examples of two different molecules, water and boron trifluoride. The bond formation is given along with the bond angles shaping the whole geometry.

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Frequently asked questions

Get answers to the most common queries related to the JEE Examination Preparation.

What is the importance of bond parameters?

Answer. The molecule formation takes specific geometry for each one, which is only possible while considering...Read full

Explain briefly what you know about bond angles.

Answer. The bond angle is an essential parameter because if the angle between the attached electrons or atoms...Read full

How do different configurations help identify bond angles in a particular molecule?

Answer. Different configurations result from different bond angles and can be identified on that basis....Read full

Explain the geometrical structure and bond angle of water.

Answer. Four attachments or electrons surround oxygen, presumably making the electron geometry tetrah...Read full

Answer. The molecule formation takes specific geometry for each one, which is only possible while considering the different bond parameters. Bond angle is one parameter that helps in molecular structure formation.

These geometrical parameters are essential because it is based on them that proper structure is formed and the molecule or compound gains stability.

Answer. The bond angle is an essential parameter because if the angle between the attached electrons or atoms is not correct, then the atom becomes unstable and cannot survive in the environment. Thus, when the different atoms form bonds, they are not explicitly acquiring stability if the angles are not respectfully satisfied. We can define the bond angle as a geometric angle between two adjacent bonds.

Answer. Different configurations result from different bond angles and can be identified on that basis.

Suppose the bond angle between two attached atoms is 180°, then its configuration is more likely to be linear.

Another example that we can take is the 118° bond angle in which there are three bond attachments (2 bonds and 1 lone pair).

Answer. Four attachments or electrons surround oxygen, presumably making the electron geometry tetrahedral. But this generally is not the outcome of the molecular structure. Two of these attachments are bonds, and the other two are lone pairs. Therefore, the resulting molecular geometry is a bent structure.

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