Silver nitrate is an inorganic substance with the chemical formula AgNO3 and is one of the metal nitrates. Because of its adaptability, the compound can be converted into a variety of other silver compounds, such as those used in colour photography. It has far lower light sensitivity than other halides. In a trilateral planar configuration, the silver ions in solid silver nitrate are tri-coordinated with each other.
Silver Nitrate is made in the following ways
When making silver nitrate, it is commonly done by reacting a compound of silver, such as silver foil or silver bullion, with nitric acid in a closed container. Upon completion, silver nitrate, water, and nitrogen oxides will be produced as byproducts of the process. The byproducts of the reaction will be determined by the concentration of nitric acid employed.
In the presence of 3 Ag + 4 HNO3 (cold and diluted), the reaction produces
3 AgNO3 +2 H2O + NO
In the presence of 2 HNO3 (hot and concentrated) + Ag , the reaction produces
AgNO3 + H2O + NO2
Silver Nitrate’s Physical and Chemical Characteristics
This subsection is a list of some of the most significant physical and chemical properties of silver nitrate.
Physical Characteristics
- Silver nitrate has a molar mass of 169.872 grams per mole and is a halogen compound.
- In its solid state, AgNO3 has a colourless appearance and has no odour. It is a compound.
- There are 4.35 grams per cubic centimetre of density in the solid state of the substance. Its density in the liquid state at 210°C equates to 3.97 g/cm3 when measured in cubic centimetres.
- Silver nitrate has melting and boiling temperatures of 482.8 degrees Celsius and 713 degrees Celsius, respectively. This chemical, on the other hand, has a tendency to disintegrate at temperatures close to its boiling point.
- Silver nitrate, like the majority of ionic substances, dissolves rapidly in aqueous solutions. In water, it has a solubility of 122g/100mL at 0°C and a solubility of 256g/100mL when the temperature is 250°C.
- The orthorhombic crystal structure of AgNO3 can be found in nature.
Chemical Characteristics
- The poisonous and corrosive properties of AgNO3 make it a potentially hazardous substance.
- Using silver nitrate and ethanol together results in a highly explosive reaction.
- Copper takes the place of the silver contained in this compound, resulting in the formation of copper nitrate. Using the chemical equation:
2AgNO3 + Cu → Cu(NO3)2 + 2Ag,
we can see that the reaction is taking place.
- When heated to 440°C, this chemical entirely decomposes, releasing oxygen, nitrogen dioxide, and silver into the atmosphere.
- It should be noted that, despite the fact that metal nitrates normally dissolve to yield metal oxides, the breakdown process of silver nitrate results in the formation of elemental silver due to the fact that silver oxide decomposes at an even lower temperature than AgNO3
Silver Nitrate applications
- Biological applications, chemical synthesis, and medicine are just a few of the many disciplines where silver nitrate is used.
- In addition to being a fairly versatile chemical, silver nitrate can be modified by substituting various ligands that can bind to the silver ion for the nitrate ion.
- As a result of its capacity to precipitate silver halides when exposed to halide ions, this chemical is utilised in the production of photographic films, among other applications.
- A precipitation reaction of silver nitrate can be used to create a wide variety of silver-based explosives.
- In the field of inorganic chemistry, this molecule is used to extract halides from their corresponding compounds.
- This reaction is used in analytical chemistry to test for the presence of halide anions such as iodide, bromide, or chloride ions, which are present in the solution.
- It is possible to separate alkene mixtures with the help of this compound because the silver cation forms reversible bonds with the alkenes in the mixtures.
- Applied as an antiseptic in many medical settings, silver nitrate is effective when diluted with water to a concentration of 0.5 percent.
- The eyes of a newborn baby born to a woman who has gonorrhoea can be treated with a diluted solution of AgNO3 , which fights the gonococcal bacteria and prevents the baby from developing blindness as a result of the disease.
- The use of this chemical for the treatment and eradication of undesirable warts in humans has also been documented.
Conclusion
Pure silver nitrate is used as an intermediate in the production of various silver salts, such as colloidal silver compounds used in medicine and silver halides used in photographic emulsions. It is also utilised in the production of colloidal silver compounds.
Aquatic silver nitrate solutions are utilised in the volumetric measurement of halides, cyanides, and thiocyanates, as well as the detection of reducing agents and of the cations of different acids that generate insoluble silver salts, among other applications in analytical chemistry.