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NEET UG 2026 » NEET UG Study Material » Chemistry » Silver Nitrate
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Silver Nitrate

Silver nitrate is a chemical compound with the formula AgNO3 that can be found in nature. In its most basic form, it is an ionic connection formed between the silver cation (Ag+) and the nitrate anion (NO3–). Because of the ionic structure of this chemical, it rapidly dissolves in water and decomposes into its constituent ions when exposed to light.

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Silver nitrate is an inorganic substance with the chemical formula AgNO3 and is one of the metal nitrates. Because of its adaptability, the compound can be converted into a variety of other silver compounds, such as those used in colour photography. It has far lower light sensitivity than other halides. In a trilateral planar configuration, the silver ions in solid silver nitrate are tri-coordinated with each other.

Silver Nitrate is made in the following ways

When making silver nitrate, it is commonly done by reacting a compound of silver, such as silver foil or silver bullion, with nitric acid in a closed container. Upon completion, silver nitrate, water, and nitrogen oxides will be produced as byproducts of the process. The byproducts of the reaction will be determined by the concentration of nitric acid employed.

In the presence of 3 Ag + 4 HNO3 (cold and diluted), the reaction produces

 3 AgNO3 +2 H2O + NO 

In the presence of 2 HNO3 (hot and concentrated) + Ag , the reaction produces

AgNO3 + H2O + NO2

Silver Nitrate’s Physical and Chemical Characteristics

This subsection is a list of some of the most significant physical and chemical properties of silver nitrate.

Physical Characteristics

  1. Silver nitrate has a molar mass of 169.872 grams per mole and is a halogen compound.
  1. In its solid state, AgNO3 has a colourless appearance and has no odour. It is a compound.
  1. There are 4.35 grams per cubic centimetre of density in the solid state of the substance. Its density in the liquid state at 210°C equates to 3.97 g/cm3 when measured in cubic centimetres.
  1. Silver nitrate has melting and boiling temperatures of 482.8 degrees Celsius and 713 degrees Celsius, respectively. This chemical, on the other hand, has a tendency to disintegrate at temperatures close to its boiling point.
  1. Silver nitrate, like the majority of ionic substances, dissolves rapidly in aqueous solutions. In water, it has a solubility of 122g/100mL at 0°C and a solubility of 256g/100mL when the temperature is 250°C.
  1. The orthorhombic crystal structure of AgNO3 can be found in nature.

Chemical Characteristics

  1. The poisonous and corrosive properties of AgNO3  make it a potentially hazardous substance.
  1. Using silver nitrate and ethanol together results in a highly explosive reaction.
  1. Copper takes the place of the silver contained in this compound, resulting in the formation of copper nitrate. Using the chemical equation:

 2AgNO3  + Cu → Cu(NO3)2 + 2Ag,

we can see that the reaction is taking place.

  1. When heated to 440°C, this chemical entirely decomposes, releasing oxygen, nitrogen dioxide, and silver into the atmosphere.
  1. It should be noted that, despite the fact that metal nitrates normally dissolve to yield metal oxides, the breakdown process of silver nitrate results in the formation of elemental silver due to the fact that silver oxide decomposes at an even lower temperature than AgNO3 

Silver Nitrate applications

  1. Biological applications, chemical synthesis, and medicine are just a few of the many disciplines where silver nitrate is used.
  2. In addition to being a fairly versatile chemical, silver nitrate can be modified by substituting various ligands that can bind to the silver ion for the nitrate ion.
  1. As a result of its capacity to precipitate silver halides when exposed to halide ions, this chemical is utilised in the production of photographic films, among other applications.
  1. A precipitation reaction of silver nitrate can be used to create a wide variety of silver-based explosives.
  1. In the field of inorganic chemistry, this molecule is used to extract halides from their corresponding compounds.
  1. This reaction is used in analytical chemistry to test for the presence of halide anions such as iodide, bromide, or chloride ions, which are present in the solution.
  1. It is possible to separate alkene mixtures with the help of this compound because the silver cation forms reversible bonds with the alkenes in the mixtures.
  1. Applied as an antiseptic in many medical settings, silver nitrate is effective when diluted with water to a concentration of 0.5 percent.
  1. The eyes of a newborn baby born to a woman who has gonorrhoea can be treated with a diluted solution of AgNO3 , which fights the gonococcal bacteria and prevents the baby from developing blindness as a result of the disease.
  1. The use of this chemical for the treatment and eradication of undesirable warts in humans has also been documented.

Conclusion

Pure silver nitrate is used as an intermediate in the production of various silver salts, such as colloidal silver compounds used in medicine and silver halides used in photographic emulsions. It is also utilised in the production of colloidal silver compounds.

Aquatic silver nitrate solutions are utilised in the volumetric measurement of halides, cyanides, and thiocyanates, as well as the detection of reducing agents and of the cations of different acids that generate insoluble silver salts, among other applications in analytical chemistry.

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Frequently asked questions

Get answers to the most common queries related to the NEET UG Examination Preparation.

What are some of the applications for silver nitrate?

Silver nitrate is a chemical compound that is commonly employed in numerous organic synthesis reactions in a variety...Read full

Is silver nitrate a potentially hazardous substance?

The presence of silver nitrate in organic compounds must be avoided due to its oxidising properties. In spite of its...Read full

What is the process of making silver nitrate?

Silver nitrate is typically made by mixing silver and nitric acid in a reaction vessel. Silver bullions and silver f...Read full

What is the balanced equation of silver nitrate and Zinc?

The balanced chemical reaction is as follows:   2AgNO...Read full

How to use silver nitrate sticks?

Silver nitrate sticks are used to treat and eliminate granulation tissue around your child’s stoma. They are a...Read full

Silver nitrate is a chemical compound that is commonly employed in numerous organic synthesis reactions in a variety of ways. For example, the deprotection and oxidation processes are examples of such reactions. The Ag+ ion binds alkenes in a reversible manner, and silver nitrate that has been selectively adsorbing alkene mixtures can be utilised to separate alkene mixtures. The resultant adduct can be dissolved with ammonia (in order to liberate the free alkene) to get the free alkene. In the past, silver nitrate was used to stain objects with a silver hue (a process that employs silver or silver compounds to selectively change the appearance of a specific object). Because of its antibacterial properties, this chemical is extensively used in the medical field.

The presence of silver nitrate in organic compounds must be avoided due to its oxidising properties. In spite of its widespread use (especially in extremely low doses) for the prevention of gonorrhoea and to halt bleeding from the nose, silver nitrate is often exceedingly poisonous and corrosive. It should be avoided at all costs. With the exception of the development of a violet, brown, or black stain on the region of the skin that was in contact with the silver nitrate, short-term exposure to this substance has no acute negative effects. Exposure to this chemical over an extended length of time, on the other hand, is frequently associated with harm to the eyes. Generally speaking, this chemical is considered to be an irritant to the skin and eyes.

Silver nitrate is typically made by mixing silver and nitric acid in a reaction vessel. Silver bullions and silver foils are two examples of silver objects that are commonly employed in these reactions. In this reaction, the compounds generated include silver nitrate, water, and nitrogen oxides, among others. The by-products of this chemical reaction are dependent on the concentration of nitric acid that is utilised in it. It is vital to note that this chemical reaction must be carried out in a fume hood due to the release of harmful nitrogen oxides during the course of the chemical reaction.

The balanced chemical reaction is as follows:

  2AgNO3(s) + Zn(s) = Zn(NO3)2 + 2AgNO3(s)

 Zinc causes the development of zinc nitrate when combined with silver nitrate, which results in the production of silver as a byproduct during or at the conclusion of the process. The process takes place because zinc, which results in zinc nitrate, is significantly more reactive than silver, and this, in turn, results in the formation of silver nitrate. It should be noted that this procedure involves a substitution reaction, in which zinc is used in place of silver.

Silver nitrate sticks are used to treat and eliminate granulation tissue around your child’s stoma. They are available in a variety of sizes.

If your child has a sensitivity to silver, you should avoid using silver nitrate.

It is possible that silver nitrate will be painful to apply. Giving your child acetaminophen or ibuprofen before the application may assist him or her stay comfortable during the procedure. Always use a barrier cream to protect your child’s healthy skin before administering silver nitrate to the stoma to prevent irritation.

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