Actinides are the elements that come after Actinium and have atomic numbers ranging from 89 to 103. They include naturally occurring elements such as thorium, protactinium, uranium, and eleven transuranic elements generated deliberately through nuclear processes. Regardless, all actinides are hazardous.
Actinides
- The actinide series receives its name from its initial element, actinium.
- The symbol An refers to any element in the actinide series, with atomic numbers spanning from 89 to 103 on the periodic table.
- The actinide series elements are all nuclear in origin, producing a great deal of energy during radioactive decay.
- Uranium and thorium are the most abundant natural actinides on Earth. These elements can be found in both nuclear reactors and nuclear weapons. Uranium and thorium are utilised in a variety of applications, whereas americium is being used in smoke detector ionisation chambers.
The general electrical configuration of actinides is as follows:
[Rn] 5f1 – 14 6d0 – 1 7s2
Actinide Physical Properties
- All actinides are radioactive.
- These elements have no stable isotopes.
- The electropositivity of actinides is relatively high.
- Actinides are highly dense metals with a variety of forms. Actinium is an exception since it possesses fewer crystalline phases.
- Metals tarnish fast when exposed to air. Some metals are pyrophoric (ignite spontaneously in the air), particularly when finely divided particles are present.
- Many different allotropes can be formed—plutonium has at least six different allotropes.
- Actinide metals are soft.
- Some of them are thin enough to be cut with a knife.
- These elements are malleable and ductile.
- All of the actinides are paramagnetic.
- When they react with hot water or dilute acid, they release hydrogen gas.
- All of these elements are silver-coloured at normal temperature and pressure.
Real-World Applications
Because of the actinides’ characteristics, you won’t encounter many of these elements in your daily life. That doesn’t imply they don’t have real-world uses.
Uranium
- In the actinides family, uranium is the most prevalent rare earth element.
- Its many isotopes have uses in a wide range of sectors.
- In fact, all of these isotopes, all of the metals in the actinides family, are radioactive by nature and have varying half-lives.
- The “half-life” of a sample is the length of time it takes for half of it to degrade.
- The most prevalent isotope, uranium-238, has a lengthy ½ that half of the isotope present now has been there since our planet’s creation, around 4.5 billion years ago.
Uranium Applications
- Power generation: Uranium-235 is the only naturally occurring fissionable isotope on the earth.
- This fission process may provide clean energy in a nuclear power plant.
- Nuclear warfare is perhaps the most well-known application of uranium.
- The same fission process that generates clean energy may also generate enormous quantities of destructive power.
- When uranium’s radioactivity is depleted through use, what remains is an ultra-dense metal.
- Depleted uranium can be found in bullets, armour, and ship ballast.
Thorium
- Thorium is most likely the most common actinide, but it doesn’t imply there’s a lot of it.
- Every year, thorium mines will generate just a few hundred tonnes of it.
Thorium Applications
- Nuclear fuel: While uranium-235 is the sole fissionable fuel, it is not the only alternative.
- When thorium-232 is bombarded with neutrons, it transforms into thorium-233, which ultimately decays into uranium-233.
- Welsbach mantle: Thorium is also utilised in the Welsbach mantle, a form of gaslight.
- It emits a dazzling white light when heated by a gas flame.
- Thorium has an extremely high melting point of 3,100 degrees Fahrenheit and a boiling point of 8,100 degrees Fahrenheit, making it a good option for high-temperature crucibles.
Plutonium
- Plutonium is a fissionable actinide that does not naturally occur in the Earth’s crust.
- Rather, it’s a consequence of neptunium-238 disintegration.
- Scientists found it in 1941, but it wasn’t widely known till 1946, after World War II.
Plutonium Applications
- Power for spacecraft for long-term missions.
- The Curiosity rover, which is actively investigating Mars’ surface, employs a radioisotope power generation system fuelled by 4.8 kilos of plutonium-238.
- Nuclear weaponry: Like uranium, plutonium is used in the creation of nuclear weapons.
- Pacemakers: While a plutonium-powered pacemaker is no longer available, it was an option for decades since it extended the device’s lifespan.
Californium
- An actinide that does not naturally occur on the globe is Californium.
- Instead, it’s what’s left behind after bombarding Curium-242 with Helium ions.
- It doesn’t survive long, though, especially in comparison to other actinides.
- Californianium-252 has a half-life of around 2.6 years, whereas Californianium-245 does have a half-life of just 45 minutes.
Californianium Applications
- Californianium emits neutrons, which can be used to identify valuable metals.
- When embedded in a detecting device, it can rapidly detect and classify precious metals like gold and silver, eliminating the need to send samples to a lab.
- Moisture gauges: The same neutrons may be used to detect water and oil layers in wells.
- Metal fatigue detection: Californium neutrons can discern metal fatigue in aircraft, trying to prevent minor issues from becoming major ones.
Americium and Curium
- Marie Curie and her husband, Pierre, are responsible for the name Curium.
- Marie was a world-renowned chemist who contributed significantly to the world’s understanding of radioactive isotopes.
- Both Americium and Curium are rare elements with few uses.
Curium and Americium Applications
- Curium and americium both provide tremendous quantities of energy and might be ideal for spaceship fuel if we step away from plutonium-powered ships and rovers.
- Smoke detectors: Approximately 80% of smoke detectors in the United States include americium-241, which allows the device to detect smoke in the atmosphere.
- Cancer treatment: Americium-241 is a radioactive isotope that is used in brachytherapy to treat cancer.
Conclusion
Actinides are radioactive in nature, which is one of their most essential features. The term radioactive alludes to the nucleus breaking down into smaller particles. The elements of the Actinide series emit a lot of energy when they decay radioactively. Actinide elements are utilised in nuclear reactors and nuclear weapons, and these elements have features of D and F block elements.