Electron configuration describes the distribution of electrons within atoms and molecules among various orbitals (including shells and subshells).
There are four principle orbitals (s, p, d, and f) that are filled based on the element’s energy level and valence electrons. Each of the four orbitals can accommodate a different number of electrons. The s-orbital can hold two electrons, while the other three orbitals can hold six, ten, and fourteen electrons, respectively. The s-orbital denotes elements from groups 1 and 2, the p-orbital elements from groups 13, 14, 15, 16, 17, or 18, and the f-orbital elements from groups Lanthanides and Actinides. The main focus of this module, however, will be on the electron configuration of transition metals in the d-orbitals (d-block).
The inner transition elements
The inner transition elements are located between lanthanum (Z=57) and hafnium (Z=72), as well as actinium (Z=89) and rutherfordium (Z=104). There is some debate about whether lanthanum and actinium should be considered transition metal group 3B elements, with the elements following them being the lanthanides and actinides, or whether lanthanum and actinium should be considered the first elements of the lanthanides and actinides, with lutetium and lawrencium being transition metal group 3B elements. The above arrangement is more traditional, but there appears to be a growing trend toward the latter scheme.
Lanthanides (except for promethium, a synthetic element), scandium (Sc), and yttrium (Y) are sometimes referred to as “rare earth elements” or “rare earth metals” (or just “rare earths”). This term is no longer commonly used, owing to the ambiguity of which elements “should” be included in this category, as well as the fact that many of these “rare” elements are not particularly rare. Cerium is the 25th most abundant element in the Earth’s crust, and even the least abundant of the naturally occurring lanthanides, lutetium, is much more abundant than either silver or gold.
Procedure to fill transition metal orbitals
With an argon core, the first-row transition metal electron configuration consists of 4s and 3d subshells (noble gas). This only pertains to the first row of transition metals; for the remaining transition metal rows, changes are required when writing the electron configuration. The noble gas would be the core inscribed around the element symbol with brackets before the first row of transition metals (i.e. Ar-Ar for the first row of transition metals), and the electron configuration would follow an Ar-Ar nsxndx format.For first-row transition metals, the electron configuration is simply Ar-Ar 4sx3dx. The energy level, “n,” can be calculated simply by looking at the row number in which the element is located on the periodic table. There is an exception for the d-block and f-block, where the energy level is “n-1” (“n” minus 1) for the d-block and “n-2” for the f-block . In this situation, the “x” in nsx and ndx refers to the number of electrons in a given orbital.
Filling of orbitals of different transition element series-
First transition or 3d-series:(from Sc(21) to Zn(30))- The 3d-orbitals fill up progressively. The stability notion of half-filled or totally filled (n-l) d-orbitals is used to explain the real configurations. When 5 or 10 electrons are present in the (n-l) d-subshell, each d-orbital is either singly occupied or doubly occupied. Cu is an exception because it fills d-orbital by taking one electron of 4s orbital to attain stability of 3-d orbital.
Second Transition or 4d-series:(from Y(39) to cd(48))- This series consists of elements from Y(39) to Cd(48). 4d-orbitals are gradually filled up.Elements marked with an asterisk have anomalous configurations. Nuclear-electron and electron-electron forces are attributed factors.
Third Transition or 5d-series:(from La(57), Hf(72) to Hg(80))- This series comprises elements ranging from La(57) to Hg(80), with the exception of 14 lanthanide elements ranging from Ce(58) to Lu (71). The 5d-orbitals eventually fill up.
Fourth Transition or 6-d series:(fromAc(89),Rf(104) to uub(112)- Except for 14 elements from the actinide series from Th(90) to Lr(112), this series comprises atoms from Ac(89) to Uub(112) (103). The 6d-orbitals eventually fill up.
Conclusion
Electron configuration describes the distribution of electrons within atoms and molecules among various orbitals. The main focus of this module, however, will be on the electron configuration of transition metals in the d-orbitals. The inner transition elements The inner transition elements are located between lanthanum and hafnium , as well as actinium and rutherfordium. There is some debate about whether lanthanum and actinium should be considered transition metal group 3B elements, with the elements following them being the lanthanides and actinides, or whether lanthanum and actinium should be considered the first elements of the lanthanides and actinides, with lutetium and lawrencium being transition metal group 3B elements. They are the building blocks of life and can be found right in the middle of the periodic table.