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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Physics » Avogadro’s number

Avogadro’s number

Know all about Avogadro's number, its definition, and much more.

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Introduction

Avogadro’s number, named after Amedeo Avogadro, equals approximately 6.022 x 1023. Avogadro’s number tells us how many molecules are in 1 gram-molecule of a substance. Avogadro’s number depends on the substance and its temperature; it is a universal constant. The number is the same regardless of what type of molecules are in the substance. For example, the Avogadro number for water is the same as deuterium oxide (heavy water). It doesn’t matter what kind of particle makes up a molecule because all particles have an equal volume. We can express this by changing a gram-molecule to moles (mol). We divide grams by Avogadro’s number units to find moles. Then, we can express the mass of 1 mole in grams by dividing 1 mol by exactly 6.022 x 1023 g/mol. This number cancels out because we divided grams by Avogadro’s number to find moles and by Avogadro’s number to find grams.

Avogadro’s number Definition

Avogadro’s number is a fundamental constant in chemistry. It is the number of particles in the specified units that make up one mole of a chemical substance. Mol means a quantity of. For example, a mole of water would be 18 g (1 g = 1 mL). A mole of gold would be 196 g. For example, if you had 18 g of water and added one drop of ink to it, you would have 19 g of colored water. Therefore, a mole of water has two particles. A mole is the same as 6.022140857 × 1023 particles. This number is called Avogadro’s Number and is written as NA. It was named for Amedeo Avogadro, who first stated the concept in 1811. Molecular weight and molar mass are related to Avogadro’s number because they also involve particles or molecules. Molar mass is defined as the mass of one mole of a substance. The molecular weight is the average molecular mass of all species present in a compound. We can calculate the number of particles in any given amount of a substance. It is called Avogadro’s constant or value of Avogadro’s number, and its value is 6.022 x 1023. This is a pretty significant number. For example, there are about 8 x 1023 grains of sand in a cubic meter (roughly) of beach sand. To get the number of particles in 3 moles of a substance, you simply multiply the amount (in grams) by 6.022 x 1023. Why? Because that is how many particles there are in 12 g of the substance. If you have 12 g of a substance, you have 3 moles of it, as mass can be expressed as the number of particles times the Avogadro constant. The point here is that when we say 3 moles, we could mean almost anything. We could be talking about 3 moles of water (18 g), or 3 moles of helium (4 g), or 3 moles of uranium metal (about 140 g). It all depends on what I mean by “mole.” So, when we talk about Avogadro’s constant, we need to specify what we mean by “a mole.”

Importance

The work Avogadro did was of great importance to the understanding of chemical reactions and solutions. He gave scientists a way of measuring how much gas was in a given volume, which allowed them to calculate the relative masses of gasses. The determination of the number of molecules in one liter of gas is one way in which we can understand how many particles makeup one atom. This knowledge allows us to manipulate atoms and molecules and use them for our own purposes.
  • It provides a relationship between the Boltzmann constant and gas constant R
  • It provides a relationship between the elementary charge e and the Faraday Constant F
  • It also provides the relationship between the molar mass unit Mu and the atomic mass unit u
Avogadro’s number connects to the atomic world. In order for our macroscopic measurements to be relevant, we need a way of converting between macroscopic and microscopic units. Avogadro’s number is the conversion factor used in chemistry. These two different scales also have different units associated with each of them. The link between these two scales is provided by Avogadro’s number. If you know one scale, you can convert it to the other scale using this number. The SI unit for mass is kilograms (kg). A mole of a substance has a mass close to 1 kg, which means that the number of atoms in one mole is around 6 × 1023. And, this number is none other than Avogadro’s number.

How was the number determined?

The most famous example of his law is the ideal gas law, PV = nRT. But he argued for the law by explaining Gay-Lussac’s Law, which states that two volumes (or amounts) of gases at the same temperature and pressure will combine in a simple whole-number ratio to form one volume of a third gas. For example, one volume of hydrogen will combine with two volumes of oxygen to form two volumes of water vapor. The contributions of Avogadro and others helped develop atomic theory in chemistry and other sciences because it became possible to determine atomic weights accurately. And, knowledge of atomic weights led to further understanding of the nature and behavior of atoms, which in turn led to important developments in many fields such as physics, astronomy, chemistry, and biology.

Other Information

Avogadro’s Number is the number of atoms in 12 grams of Carbon-12, which is the most common isotope of Carbon. This number was first estimated by Amadeo Avogadro, an Italian physicist, and the chemist who studied gasses and published his findings in 1811. A big deal is made about Avogadro’s Number because it’s a huge number whose value is so large that it’s difficult to comprehend. It’s also a very important number for chemists and physicists who work with gasses because it gives them a way to calculate other numbers that are important in the study of gasses. It may seem surprising to find out that there really is a value for Avogadro’s number. After all, we’ve never seen a gas made up of particles with names such as “Avogadros.” What are these particles? How can we be sure that they exist at all? The answer to these questions requires an understanding of how scientists determine the values for scientific constants like Avogadro’s number. The first step in determining Avogadro’s number is to figure out how many molecules there are in 1 gram of any substance at STP (standard temperature and pressure).

Limitations

The problem with Avogadro’s number is that it is very large (in fact, it’s the number of atoms in about 12 grams of chemical elements). Remember the problems of scale we discussed earlier. Without really working at it, you could walk past a trillion billion atoms every day without noticing. So even if we think of a single atom as a “particle,” as chemists do, they are so numerous and move around so fast that they don’t act like particles at all. Trying to calculate a single particle’s activity is like trying to imagine what happens when you shake a snow globe containing one of those little plastic army men. It doesn’t work. You have to go back to asking what happens on average. But now, we have another problem: the average behavior depends on how many particles there are!

Conclusion

Avogadro’s number is the most important number in chemistry as well as in physics. This number is also used for other scientific purposes. It is necessary to use this number to calculate the amount of substance present in a mixture of gasses or liquids.

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