Germanium is a metalloid and silver-grey. It possesses properties similar to metal and nonmetals. It is arranged in between tin and silicon on the periodic table. German scientists incorporated it into the periodic table in 1871.
Germanium has not attained significant economic importance. Until its semiconductor properties were known, it was used as a semiconductor in electronics. Multiple options are now available as semiconductors instead of germanium. But the photocells and rectifiers give primary priority to the use of germanium.
Both germanium and germanium oxides are transparently interacting with infrared radiations. Therefore, they are used in infrared spectroscopes.
What Is Germanium?
Germanium is initially not thought to be an essential element for living beings in daily life. Several germanium compounds are tested to use in pharmaceuticals but are not yet successful. While naturally occurring germanium compounds are silicon and aluminium. They are water-insoluble and therefore have little oral toxicity.
In contrast, the synthetically derived germanium is water-soluble and has nephrotoxicity. While synthetic but chemically reactive germanium compounds have irritant and toxin properties when combined with halogen and hydrogens.
Physical And Chemical Properties Of Germanium
It is found in the solid state.
- The atomic number of germanium is 32.
- 72.6 is the atomic mass of germanium.
- The boiling point of germanium is 28330C.
- The melting point of the germanium is 938.250C.
- It appears as a face-centred diamond cubic crystal structure.
- The density of germanium is 5.323gcm-3.
- The electronegativity of germanium is 2.01 according to the Pauling scale.
- Germanium expands when it freezes like water, but other elements do not have this property.
- When it reacts with chloride, it forms germanium chloride, similar to when it reacts with bromide, creating germanium bromides.
- It has five natural isotopes and 27 synthetic isotopes.
- It is very reactive; therefore, it is not free occurring.
Germanium Occurrence:-
Germanium is not found abundantly on the earth’s crust. It is found in certain ores only. Like, argyrodite, germanite,briatite,renierite. Deposits of germanium are found on Jupiter and the stars. It is normally refined from the non-ferrous by-product, specifically zinc. Germanium concentrates are heated air oxidized to form a Gecl4 using chlorohydric acid. The hydrolyzation of germanium chloride yields germanium oxide. It is reduced in hydrogen temperature at 600-7000C to give germanium.
The most common isotopes of the germanium are Ge 74, which appears in 36.28% of the total natural germanium abundance, Ge 72, which appears in 27.54% of the natural occurrence of total germanium, Ge 79 appears as 20.84, and Ge 73, and Ge 76 appears 7.36% and 7.61% respectively of natural germanium occurrence on the earth.
Uses Of Germanium:-
- It is a semiconductor combined with arsenic and other elements and used in transistors and electronic appliances.
- The oxide compounds of germanium have a high index of refraction and dispersion; therefore, they are used in the wide-angle camera lenses and the object lens of the microscopes by making the perfect choice of selection.
- In the case of the catalyst and fluorescent lamp, it is used as an alloying agent.
- Both germanium and germanium oxide are widely used in infrared spectroscopes because they appear transparent in contact with infrared radiations.
- Germanium can treat leukaemia and lung cancers. They are used as an alternative medicine to treat leukaemia and lung, cancer patients.
- It is used in the manufacturing of weapon sightings and rectifiers as well.
- It is used as a catalyst in plastic manufacturing.
- It is also used as a fluorescent material.
- It is used in rewritable DVDs.
- It is used in windows, optical fibres, and thermal imaging cameras because it has infrared optical material.
- Used in the military, in various equipment like fire-fighting and night-vision instruments.
- It is mainly used in solar panels and solar cells.
Germanium is widely used in multiple applications. Still, the studies on the other uses of germanium in pharmaceuticals and medicine are ongoing and still have not proven the applications. While initially, it has denied using germanium in all the types of applications or utilities, its abundance of use has explained it. It is very expensive because its costly or cost-effective purifying techniques make it very cost-effective.
This article has tried to sum up all the information regarding germanium, which is very helpful for understanding the concept of germanium. And for the students, there will be the entire germanium concept in one place to go through it.
Conclusion
Germanium is a metalloid element having the shiny silver-grey colour as the metals and shares the same quality of electrical conductivity. The atomic number of germanium is 32 was also not in the periodic table mentioned before the 1870s. Germanium is not found abundantly on the earth’s crust. It is found in certain ores only. Like, argyrodite, germanite, briatite, renierite. Germanium is mined in Alaska, Tennessee, China, the United Kingdom, Ukraine, Russia, and Belgium through chemical explanations. Germanium can treat leukaemia and lung cancers, therefore used as an alternative medicine to treat leukaemia and lung cancer patients. Their many applications of germanium have been mentioned in the article.