UPSC » UPSC CSE Study Materials » Chemistry » Types Of Orbitals

Types Of Orbitals

This article will discuss orbitals, their definition and types throughout the subject of science and how orbitals affect electrons. The topic of orbitals is discussed in detail throughout the article.

What are atomic orbitals?

The atomic orbitals seem to be mathematical functions within the subject of atomic theory as well as quantum physics that describes the position as well as the wavy behaviour that an electron within an atom usually makes. This function may be used to determine the likelihood of locating any atom’s electron particle in just about any given location outside its nucleus. An atom’s nucleus seems to be surrounded by lighter electron particles. If these atoms are brought close together, and their respective outermost orbitals collide and form an overlap, they seem to form a strong chemical bond. This gives rise to the importance of learning the orbital shapes, which may help in understanding atomic relations.

Brief on atomic orbitals and their types:

These Atomic orbitals seem to be often identified as a  combination of numerals as well as letters that signify key characteristics of the electrons that represent the orbitals; these can be written in the form of 1s, 2p, 3d, as well as 4f. The values, referred to as the primary quantum numbers, seem to represent energy levels along with their proximity range from the atom’s nucleus. The energy closest to the nucleus seems always to be occupied by a 1s electron. It is observed that a 2s electron seems to be loosely bonded, and it seems to spend the majority of its period away from its nucleus.

The types of orbitals are as follows:

  • S type orbital

In this type of orbital, there seems to be one orbital for each value of n, and it seems that both l, as well as m are equivalent to zero in this particular orbital. The orbitals in discussion consist of spherical shapes. The wider the sphere shape is, the more it seems likely that the electron will be discovered further away from its nucleus. This represents a higher value of n.  The spheres seem not to be evenly distributed throughout the particle; instead, they resemble layered nests. In the s orbital type, the low energy electrons that have their n value as 1 seem to have I and m values equal to zero. Due to some quantum mechanics principles, it is observed that the s orbital seems to be the only orbital that can have its n value as n=1.

  • P-type orbital

When the n value seems to be greater than just one, more alternatives become accessible. The orbital type l seems to have properties that can take any (n-1) value.   The orbital seems to be referred to as the p orbital when l equals one, and this P orbital resembles dumbbells in its appearance. The m seems to move from positive towards a negative I with a one-step increment for each value of l. For example, if n=2 and l=1, m might be in the form of 1, 0, or -1. This implies that there seem to be three variations of the p orbital. The P orbitals seem to exist for all primary quantum numbers that seem to have a value greater than one, and when the value of n increases, they seem to represent various other structural forms.

  • D orbital type

For n=3, l = 2, when l seems to be equal to 2, m might be 2, 1, 0, -1, or -2. These types of orbitals seem to be known as d type orbitals, and there seem to be five distinct types of orbitals that correspond to various m values. The n=3, l=2, m=0 orbital seems to resemble a dumbbell like the p orbital, but it also seems to have a doughnut-shaped structure in the centre. The four other types of d orbitals seem to appear like four eggs stacked on the corners of a square structure. The only difference between the variations is that the eggs seem to face different directions in each d type.

  • F type orbital

The f orbitals seem to have n=4, l=3 orbitals and seem to be one of the most difficult types to represent. They seem to have a large variety of unique qualities. The n=4, l=3, m=0; m=1 as well as m=-1 orbitals seem to look like dumbbells just like other rentals, but they seem to have two doughnuts present at the ends of the barbell shaped structure. 

Conclusion

The article explains in brief orbitals and their definition. It further talks about how orbitals work and mentions some of its key concepts. Orbitals help in locating the presence of electron particles around the atom’s nucleus. It seems to have various types that are mentioned in the above article in detail. The article also mentions a few terms related to orbitals.

faq

Frequently asked questions

Get answers to the most common queries related to the UPSC Examination Preparation.

What is an electron?

Ans. The electron seems to be a subatomic particle that has its electric charge in the form of a negative charge. El...Read full

What is an atom nucleus?

Ans. The atomic nucleus seems to be a tiny, dense type of area situated in the core of an atomic particle and seems ...Read full

Who termed the word orbital?

Ans. Robert Mulliken suggested the term “orbital” in 1932 as an acronym for the orbital wave function....Read full