Acidic oxide is defined as an oxide that forms an acidic solution when dissolved in water.
The acidic nature of the oxide is also determined by the oxidation number of the central atom. The higher the oxidation number.
Let’s calculate the oxidation number of central atom in the given oxides;
(a)
N2O5
2(x) + 5(-2) = 0
2x – 10 = 0
x = +5
The oxidation of nitrogen is +5.
(b)
P2O5
2(x) + 5 (-2) = 0
2x -10 = 0
x = +5
The oxidation of phosphorus is +5.
(c)
NO2
x + 2(-2) = 0
x – 4 = 0
x = +4
The oxidation of nitrogen is +4.
(d)
N2O4
2(x) + 4(-2) = 0
2x – 8 = 0
x = +4
The oxidation of nitrogen is +4.
N2O5 and P2O5 have the same central atom and have the same oxidation state. But Nitrogen atoms are more electronegative than phosphorus.
Therefore, N2O5 oxide is most acidic.2