The Types of Emulsions

The colloidal dispersion of two non-miscible liquids, where one liquid acts as the medium of dispersion and the other as a dispersed phase, is known as an emulsion. In simple words, an emulsion is a mixture that consists of two liquids that don’t mix with each other. 

The word emulsion is derived from Latin, which means ‘to milk’ (milk is an example of an emulsion of water and fat). The procedure to convert a liquid mixture into an emulsion is known as emulsification. 

Some examples of emulsifiers are:

• Egg yolk containing lecithin 
• Oil and water mixture
• Espresso that contains cream on top
• Hand creams, latex, and cutting fluid

Mechanism of Emulsification

In the whole procedure of emulsification, several chemical and physical processes and mechanisms are involved, and these mechanisms are based on the following theories:

• Repulsion Theory: According to this theory, the emulsifying agent makes a film over one stage, which leads to forming globules, and these globules repel each other, and the repulsive force between them forces them to remain suspended in the dispersion medium
• Surface Tension Theory:  According to this theory, emulsification is a process that arises by the reduction of interfacial tension between the two mediums.

Methods to Identify the Type of Emulsions

We can find out the type of emulsion with the help of the following tests:

• Dilution Test:  This test can be conducted by adding water or oil to the emulsion. If water is added, and it gets mixed with the emulsion, then the emulsion is of the oil-in-water (o/w) type. If water does not mix with the emulsion, then it is known as the water-in-oil (w/o) type. Apart from water, if oil is added to the emulsion, and it gets mixed, then it is called the water-in-oil type.

• Dye Solubility Test: This test can be conducted by adding a water-soluble dye to the emulsion. If the emulsion becomes red, it means that it is the oil-in-water type and vice-versa.

• Conductivity Test: In this test, some amount of electrolyte is added to the emulsion to measure its conductance. If it shows an increase in conductance, the emulsion is of the oil-in-water type. On the other hand, if there is no change in conductance, the emulsion is water-in-oil type.

Properties of Emulsions

The following are the properties of emulsions: 

• In an emulsion, there is a dispersion medium and dispersed phase
• They show a cloudy appearance
• Tyndall’s effect is there, wherein diluted emulsions with low wavelength light get scattered into more infractions, thereby appearing slightly blue
• By using physical methods such as heating, freezing, and centrifuging, emulsions can be broken into their constituent liquids. This process of breaking down emulsifiers into constituent liquids is known as d emulsification
• Since emulsions are liquid, they do not possess an internal structure that is static
• When dispersed in equal proportions, emulsifiers appear in white colour
• Different types of emulsions can be formed by two liquids, like oil-in-water emulsion, water-in-oil emulsion, and multiple emulsions like water-in-oil-in-water emulsion

Types of Emulsion

Emulsions can be classified into two types:

• Simple Emulsions: Simple emulsions are formed by two types, i.e., oil-in-water and water-in-oil
• Complex Emulsions: Also known as multiple emulsions, there exists a complex system where both water-in-oil and oil-in-water emulsion exist together and are stabilised by surfactants

Applications of Emulsion

• Emulsions are widely used in the pharmaceutical industry to prepare lotions and creams that can be absorbed by the body easily. Several lotions and ointments are emulsions of oil-in-water and water-in-oil type
• Properties of emulsions are used in washing clothes, and the whole cleansing actions of soaps are based on it
• Commonly used disinfectants like phenyl, when poured in water, works as oil-in-water type emulsion
• The emulsification process helps in the digestion process of the human body
• Emulsions are used in the manufacturing of polymer dispersions
• Emulsifying agents are commonly used for extinguishing fires
• They are used in the manufacturing of vaccines
• They are widely used in the food industry
• Emulsions like cutting fluid are a type of coolant used in metalworking

Conclusion

An emulsion is a mixture that consists of two liquids that don’t mix with each other. The word emulsion originates from Latin and can be categorised into two types, simple and complex emulsions. We can further divide them into oil-in-water and water-in-oil types. There are three types of tests that can be conducted to identify the type of emulsion – conductivity, dye solubility, and dilution test. Further, these emulsions have wide applications, such as in the preparation of lotions and creams, pharmaceutical products, human digestion, and fire retardant materials. Emulsions can be easily identified through their properties. The properties include the Tyndall effect, cloudy appearance, and white colour when dispersed in equal proportions.