Properties of Emulsion

There are various mixtures in Chemistry made by combining different substances having different or similar mediums. The emulsion is an important type of colloid. These are used for various purposes in daily life. A lot of emulsions used are man-made and are created to perform specific functions. Furthermore, emulsions are also used in manufacturing processes in Industries.

What is Emulsion?

A colloid of two immiscible liquids in which one fluid contains a dispersion of the other fluids is known as an emulsion. To put it another way, an emulsion is a unique type of mixture made by mixing liquids that normally do not mix. The word emulsion is derived from the Latin word ‘emulsus’, which means ‘to milk’. Emulsification is the process that turns mixtures into an emulsion.

Sometimes the word colloid and emulsions are used together. However, it is important to note that for an emulsion, both the combining agent is in the liquid phase while for a colloid the combining agent can be of any medium hence not every colloid is an emulsion but every emulsion can be categorised into a colloid.

Properties of Emulsion

• Emulsions contain both continuous and dispersed phases, with the “interface” forming the boundary between them.
• Many phases integrate scatter light passing through emulsions, giving them a cloudy appearance.
• When light is diffused in equal proportions, emulsions take on a white colour.
• Higher-frequency and low-wavelength light will be dispersed in more fractions if the emulsion is watered down, and this type of emulsion will show up blue. The Tyndall effect is another name for this phenomenon.

Methods to identify and Emulsion

Dilution Test

To dilute the emulsification in this test, be it oil or water is used. If the dispersion medium is water and the emulsion is diluted with water, the emulsion will stay constant. However, if the emulsion is diluted with oil, the emulsion will break because oil is inconsistent with water. An aqueous solvent can be used to dilute the water in oil emulsions, while an oily liquid can be used to dilute the oil in water emulsions.

Cobalt Chloride Test

When immersed in cobalt chloride solution, filter paper that has been immersed in an emulsion, then dried, turns pink. This indicates that the emulsification is of the type oil in water.

Fluorescence Test

A water in oil type emulsion exhibits constant fluorescence under magnification after being exposed to ultraviolet radiation. If it only has spotty fluorescence, it’s an oil in water type emulsion.

Conductivity Test

Water can be used as a medium because it conducts electricity well. This will be a clear outcome because water is the exterior phase in an oil in water emulsion. An electric bulb is attached to two terminals dipped in emulsion, and the electrodes are immersed in the emulsion. When the emulsification is of the oil in water type, a glowing electric bulb appears.

Besides these tests, there is also a separate test that includes the Dye Solubility test and Creaming test.

Methods of Separation of an Emulsion

Gravity Separation

Gravity separation is by far the most common method for separating oil emulsions. Oil and water, for example, have different gravities in the good stream. Water separates by gravity due to density differences. The different specific gravities will normally separate after a certain time in a non-turbulent state.

Heat Treatment

When separating liquids, heating them to specific temperatures improves separation. The viscosity of oil decreases as the heat of oil and water emulsification rises. The gas and water compounds can be released more easily because of the lower viscosity. Heating oil emulsions increases the density of the oil and water mixture.

Agitation Method

When a production fluid hits the shutoff valve plate at a vessel’s inlet, it is agitated. The abrupt impact on the tray causes a rapid shift in direction and velocity, which aids in breaking the surface tension of the fluids and kicking off the separation process. Inlet diverters in dividers come in a variety of shapes and sizes, and the qualities and volume of a good stream will determine which one is used.

In addition to these methods, other methods including coalescing, chemical demulsifiers, as well as retention treatments, are used to separate oil in water or water in oil emulsions. Some of these methods are also used in industries for the separation of emulsions.

Application of Emulsion

• Oil-in-water mixtures are widely used in food. Butter, margarine, homogenised milk, mayonnaise, and other similar products are examples.
• In the field of healthcare, Emulsions are used in many pharmaceutical and cosmetic dosage forms. Emulsions are cosmetics such as moisturisers, creams, and biphasic makeup removers. Emulsions are used in many oral and topical dosage forms.
• Vaccines and microbes are delivered using microemulsions. Emulsion formulations include cod liver oil, cortisol, and polysporin.
• Emulsions are used in the production of polymer dispersions in chemical synthesis. These include the basic ingredients in glues and paints.

Conclusion

The emulsion is an important mixture in the field of chemistry which is used in various pharmaceutical and food processing industries. These mixtures are commonly used in different products. The types of emulsion display the solubility of the different components which can be experimented with and studied in chemistry.