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JEE Exam » JEE Study Material » Chemistry » K2SO4

K2SO4

The inorganic compound potassium sulfate, commonly known as sulfate of potash (SOP), arcanite, or archaically potash of sulfur, is a white water-soluble solid having the formula K2SO4. It's a common ingredient in fertilizers since it contains both potassium and sulfur.

Table of Content
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Potassium sulfate is a white solid that has a wide range of applications in fertilizers. Many of us take vitamins, minerals, and proteins in the form of tablets or other supplements to help us acquire the nutrition we need. These substances are required for us to grow, repair damaged tissue, or just operate. That is true of all living things. This means that plants, like people, need to take their vitamins, and potassium and sulfur are two of the nutrients they require.Thankfully, they can receive both from potassium sulfate, an inorganic chemical molecule.

Chemical formula:

K2SO4 is the chemical formula for potassium sulfate. Potassium (K+) and sulfate (SO42-) ions are present.The chemical formula for potassium sulfate is:

Derivation:

The criss-cross method can be used to find the chemical formula for potassium sulfate. We can simply write chemical formulas using the criss-cross approach, which uses the valencies of the various components. The positive or metal ion sign is written on the left, while the negative party’s symbol is written on the right. The positive part’s valency number is written as a subscript on the negative part’s symbol, while the negative part’s valency number is written as a subscript on the positive part’s symbol. Subscript one is a rare occurrence. The evidence of the charges is discarded. Potassium sulfate’s chemical formula can now be stated as Potassium sulfate comprises potassium (K+) and sulfate  (SO42-) radicals.The potassium ion has a valency of one, while the sulphate radical has a valency of two. We can write the chemical formula of potassium sulphate K2SO4

as by crisscrossing the valencies.

Sources:

Natural sources of the chemical include minerals rich in Stassfurt salt. Kainite, Schonite, Leonite, and Polyhalite are some of the minerals that contain potassium sulphate. When the equivalent mineral is water-insoluble, it is easier to separate Potassium Sulfate from it. Apart from natural sources, Potassium Sulfate can also be made by combining Potassium Chloride with a Magnesium Sulphate compound in a chemical reaction.

Preparation:

  • The reaction between potassium chloride and sulfuric acid produces potassium sulphate on a huge scale. Initially, potassium bisulfate is produced as an intermediary.

KCl +  H2SO4     → HCl + KHSO4

The above reaction is exothermic and takes place at room temperature. In the last step, potassium bisulfate is reacted with potassium chloride to produce potassium sulphate and hydrogen chloride.

KCl +  KHSO4    → HCl + k2SO4

The reaction described above is endothermic.

  • Potassium Hydroxide reacts with sulfuric acid to form sulfuric acid.

The interaction of potassium hydroxide and sulfuric acid produces potassium sulphate.

H2SO4    + KCl → k2SO4 + H2O 

  • Potassium and sulfuric acid react to form sulfuric acid.

When potassium combines with dilute sulfuric acid, potassium sulphate is formed.

2K + H2SO4  →K2SO4 + H2

  • Potassium bicarbonate reacts with sulfuric acid to produce sulfuric acid.

When potassium bicarbonate combines with sulfuric acid, potassium sulphate is formed.

2KHCO3  + H2SO4  →   k2SO4 + 2H2O + 2CO

Physical Properties:

  • Sulfate of potassium is a whitish solid. It also has no odor.

  • It dissolves well in water and is just mildly soluble in glycerol.

  • In acetone, alcohol, and CS2, potassium sulphate is insoluble.

  • Potassium sulphate has a melting temperature of 1342 degrees Fahrenheit and a boiling point of 1962 degrees Fahrenheit.

  • Potassium sulphate has a density of 2.66 g/cm3.

Uses:

Potassium sulphate has a wide range of applications. They are as follows:

  • The most common application of potassium sulphate is as a fertiliser.

  • Glass is made with potassium sulphate, which is a kind of crude potassium sulphate.

  • Potassium sulphate is utilised as a flash suppressor in artillery propellant charges.

  • Because potassium sulphate is tougher than soda, it’s utilised as an alternate blast media in soda blasting.

  • Potassium sulphate is used in pyrotechnics to create a purple flame when combined with potassium nitrate.

  • Muzzle flash, blast overpressure, and flareback are all reduced using potassium sulphate.

  • Potassium sulphate is an osmotic laxative used in medicine.

Agriculture Uses:

Potassium is required for several vital tasks in plants, including enzyme activation, protein synthesis, starch and sugar formation, and water flow regulation in cells and leaves.  Potassium levels in soil are frequently insufficient to sustain healthy plant growth. For plants, potassium sulphate is a great source of Potassium nutrition. The K component of K2SO4 is identical to that of other popular potash fertilisers. It does, however, provide a crucial source of Sulphur, which is required for protein synthesis and enzyme function. Sulphur, like Potassium, can be insufficient for proper plant growth. Cl- additions should also be avoided in some soils and crops. In such instances, K2SO4 is an excellent Potassium source.

Conclusion:

Potassium fertilizer is widely used to boost the yield and quality of plants that are growing in soils that are deficient in this vital component. The majority of potassium fertilizer comes from ancient salt deposits all around the world. The phrase “potash” is a broad term that refers to a variety of potassium-containing fertilizers, including potassium sulfate (K2SO4, often known as sulfate of potash, or SOP).

faq

Frequently Asked Questions

Get answers to the most common queries related to the JEE Examination Preparation.

What is the purpose of potassium sulfate?

Ans : Potassium sulfate has a wide range of applications. It is mostly used in fertilizers, glass m...Read full

Is potassium sulfate harmful to your health?

Ans : Potassium sulfate irritates the skin. It might irritate the skin and eyes.

What occurs when potassium sulfate is dissolved in water?

Ans : Potassium sulfate is very water soluble. As a result, when potassium sulfate is added to wate...Read full

What is the function of potassium sulfate in plants?

Ans : An effective source of potassium for plants is potassium sulfate. Potassium is an essential c...Read full

Is K2SO4 an acid or a base?

Ans : Neither an acid nor a base, potassium sulfate. It’s a salt made up of a strong acid (su...Read full

What is an acidification reaction, exactly?

Ans : When potassium sulfate and sulfuric acid react chemically, rhombic pyramids emerge, which mel...Read full

Ans : Potassium sulfate has a wide range of applications. It is mostly used in fertilizers, glass manufacturing, as a flash suppressor, and as an osmotic laxative, among other things.

 

Ans : Potassium sulfate irritates the skin. It might irritate the skin and eyes.

Ans : Potassium sulfate is very water soluble. As a result, when potassium sulfate is added to water, it entirely dissolves.

 

Ans : An effective source of potassium for plants is potassium sulfate. Potassium is an essential component that plants require for optimum growth.

Ans : Neither an acid nor a base, potassium sulfate. It’s a salt made up of a strong acid (sulphuric acid) and a strong base (potassium chloride) (Potassium Hydroxide).

 

Ans : When potassium sulfate and sulfuric acid react chemically, rhombic pyramids emerge, which melt at 197 degrees Celsius. At 0 oC, the resulting solution is soluble in three parts water, and the reaction’s two congeners appear side by side, uncombined. Acidification is the name for this chemical reaction involving K2SO4.

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