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JEE Exam » JEE Study Material » Chemistry » Isotopes

Isotopes

In chemistry, isotopes are two or more groups of atoms that have the same atomic number and position on the periodic table, but have different nucleon numbers due to the presence of different numbers of neutrons. Despite the fact that all isotopes of the same element have chemical properties that are nearly identical, their atomic masses and physical properties differ.

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To put it another way, the word isotope is derived from two Greek words: isos and topos, which both mean “the same place.” Therefore, the concept behind using the term “isotopes” is that different isotopes of a single element can be found in the same position on the periodic table.

Isotope

The term “isotope” refers to the variation in the atomic mass or weight of an element that is most commonly encountered.

Isotopes of a particular element are also defined as elements with the same number of protons but differ in the number of neutrons contained within the atom.

Because of the unequal numbers of neutrons in each isotope of an element, the masses of the isotopes of elements are usually different. In general, elements with odd atomic numbers will have one or two stable isotopes, whereas elements with even atomic numbers will have three or more stable isotopes, if not more. There are some exceptions, such as carbon, helium, and beryllium, which are listed below.

Physical and chemical properties of Isotopes

When we talk about the chemical properties of isotopes of a given element, we are talking about isotopes that are nearly identical or identical to one another. Different isotopes have chemical properties that are nearly identical to one another. While there are similarities between isotopes in terms of physical properties such as mass and melting or boiling point, density, and freezing point, there are significant differences.

Different types of Isotopes

1)Stable isotopes are distinguished from radioactive isotopes, which are distinguished from each other. As a result, radioactive isotopes and radionuclides are commonly referred to as radioisotopes or radionuclides.

2)Stable isotopes or stable nuclides are isotopes that do not decay radioactively and do not emit radiation.

There are approximately 339 naturally occurring nuclides or isotopes on the planet earth, according to the findings of the study.

Examples of Isotopes

1)The isotopes of hydrogen and carbon are two of the most well-known examples. When it comes to the element Hydrogen, it has three stable isotopes: protium, deuterium, and tritium. Protium is the most stable of the three isotopes. These isotopes all have the same number of protons, but each has a different number of neutrons, with protium having zero neutrons, deuterium having one neutron, and tritium having two neutrons.

2)When we look at carbon, we can see that it has three different isotopes, which are Carbon-12, Carbon-13, and Carbon-14. The atomic masses of the isotopes are represented by the numbers 12, 13, and 14. Carbon-12 is a stable isotope, whereas carbon-14 is predominantly a radioactive isotope in this context.

Facts about the Isotopes of Elements

Here are some fascinating facts about radioactive isotopes.

  • The vast majority of elements found in nature are composed of a combination of different isotopes.
  • Nuclides are another name for these elements.
  • There are approximately 1000 unstable isotopes in the universe at any given time. 
  • Some of these are found naturally in the environment, while others are created synthetically in laboratories.

Applications of Isotopes

The Application of Chemical Properties

1)An element’s isotopic signature, which is the relative abundances of its isotopes in a given sample, can be determined through the process of isotope analysis, which takes place in a laboratory. When it comes to isotope analysis, isotope ratio mass spectrometry is commonly used. It is possible that biogenic substances, in particular, will contain significant differences in C, N, and O isotopes. Using isoscapes to analyse variation in this way has a wide range of applications, including detecting food adulteration and determining where products came from in their production. The isotopic signature of trace gases found in some meteorites has been used to determine that they came from the planet Mars, according to some researchers.

2)When isotopic substitution is used to determine the cause of a chemical reaction, the kinetic isotope effect can be used to help determine the cause.

The Application of Nuclear Properties

1) It is similar to radioisotopic labelling in that it uses the observed half-life of an unstable element to determine the amount of time that has passed since a known concentration of the isotope was present. The most well-known example is radiocarbon dating, which is used to determine the age of carbonaceous materials and is the most widely used.

2) Several types of spectroscopy are based on the unique nuclear properties of radioactive and stable isotopes, which are described in detail below. For example, nuclear magnetic resonance (NMR) spectroscopy can only be used on isotopes that have a nuclear spin that is greater than zero.

Isotopes of hydrogen

The isotopes of hydrogen tritium, deuterium, and protium are the three naturally occurring isotopes of hydrogen.

Each isotope possesses its own set of characteristics. To this day, these isotopes are widely used in research. The nuclei isotopes 4H to 7H are used in the laboratory to create radioactive materials. Hydrogen has seven isotopes, seven of which are more stable than others. The least stable is 7H, and the most stable is 5H. Tritium is the radioisotope of hydrogen that is the most stable.

Protium

Protium is the first of these ( 1H )

It is one of the most frequently occurring isotopes of hydrogen. It is abundant in nature, with 99.98 percent of all resources being used. It has been reported that the nucleus of this isotope contains only a single proton, and that this proton has never been observed to decay. This is one of the reasons for this observation. Protium has a mass of 1.007825 amu (atomic mass unit). Hydrogen is generally found in compounds where it combines with other atoms, and is most commonly found in the compound H2 ( diatomic hydrogen gas).

Deuterium

Deuterium is the second element ( 2H)

Its nucleus is made up of one proton and one neutron, respectively. The deuteron is the nucleus of hydrogen 2, which is the second element in the periodic table. It is not radioactive in any way. Its compounds are used in chemical analysis as well as solvents for hydrogen 1 and other elements. Heavy water is enriched with molecules made up of deuterium rather than protium, which makes it more dense. It is used as a coolant and as a neutron moderator in nuclear reactors. In addition, hydrogen 2 is used as a fuel in nuclear fusion (commercial). It can be found in nature as deuterium gas.

Uses of Deuterium

1)Drugs

2) Nuclear weapons

3)Tracing

4)NMR spectroscopy

Tritium

Tritium is a radioactive element ( 3H )

A proton and two neutrons are found in the nucleus of this particle. In nature, small amounts of hydrogen 3 or tritium can be found as a result of the interaction of cosmic rays with atmospheric gases. At the same time, they are released in trace amounts during nuclear weapons tests. It is radioactive because it decays into helium 3 through the process known as beta decay. Hydrogen 3 has an atomic mass of 3.0160492 u, which is the same as oxygen.

Practical Applications of Tritium

1)Controlled nuclear fusion

2)Tritium in hydrogen bomb secondaries

Boosting

3)Neutron initiator

4)Nuclear weapons

5)Self-powered lighting

6)Used as an oceanic transient tracer

CONCLUSION

In chemistry, isotopes are two or more groups of atoms that have the same atomic number and position on the periodic table, but have different nucleon numbers due to the presence of different numbers of neutrons. Despite the fact that all isotopes of the same element have chemical properties that are nearly identical, their atomic masses and physical properties differ.Different isotopes have chemical properties that are nearly identical to one another. While there are similarities between isotopes in terms of physical properties such as mass and melting or boiling point, density, and freezing point, there are significant differences.The vast majority of elements found in nature are composed of a combination of different isotopes.Nuclides are another name for these elements. The isotopes of hydrogen- tritium, deuterium, and protium are the three naturally occurring isotopes of hydrogen.

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