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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Chemistry » Ionization of Water

Ionization of Water

The notes on the ionization of water are discussed here. Ionic product of water, autoionization of water

Table of Content
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Ionization of water

Water is a weak electrolyte that undergoes only little self ionization. “The ionic product of water is the product of the concentrations of H+ and OH ions in water at a given temperature.” The letter K is assigned for it. 

Importance of ionization of water 

  • Many people assume that ionization can only be achieved with high-priced equipment. However, this is not true. It is entirely achievable using a water filter with the proper filter media, which will change the molecular structure of the water molecules, charging them and decreasing their size, as well as positive ions. 
  • Drinking water heavy in negative ions may have a huge influence on you, much as when you walk barefoot on the beach and nature takes your positive ions and replaces them with negative ions, making you feel great.
  • Ionization is the process of organizing water into teeny small tidy micro-clusters by changing their size and energy. Oxidation-Reduction Potential is the name for the negative charge that is so crucial to you (ORP). 
  • Everything ages in the air; we can see it in our skin and our food. Unless we protect ourselves and our environment from oxidation, we will deteriorate over time.
  • Ionized water contains millions of electrons that function as antioxidants, counteracting body-damaging substances and cell oxidation and, as a result, prolonging cell life.
  • Healthy cells do not need to be replaced regularly, which slows the aging process, but unhealthy cells generated by radicals and oxidation accelerate the aging process. 
  • Water that has been ionized is alkaline and has a high pH. Many studies have shown that drinking ionized water is beneficial to our cardiovascular system because it includes electrically charged ions and free electrons, which protect us from free radical damage. 
  • It also eliminates and neutralizes free radicals before they cause harm to our cells. Because ionized water is high in electrons, it satisfies the requirement for free radicals and so protects our bodies from additional harm.

Ionization

  • Ionization is the process of separating or forming molecules into their respective cations and anions, depending on the situation. 
  • It is typical for molecules to have an unequally shared pair of electrons between linked atoms with a significant electronegative difference if the atoms are bonded together with an electronegativity difference of more than one. 
  • The atom with the higher electronegative potential will draw the bound pair of electrons towards itself. In contrast, the atom with the lower electronegative potential would attract fewer bonded pairs towards itself. 
  • Between the atoms in which bonding occurs, there will be a separation of charges that will take place.

Cation

  • Since it has a lower electronegative potential, an atom with a minor positive charge (cation) will not pull the shared pair of electrons towards itself, resulting in a slight positive charge. 
  • A cation is often formed by an alkaline or alkaline earth metal that is more electropositive than the surrounding environment (a positively charged ion).

Anion

  • An atom that is more electronegative as compared to other atom will draw a shared pair of electrons towards itself, resulting in the development of a negative charge, referred to as a anion. 
  • A negatively charged ion is formed when an alkaline or alkaline earth metal with a higher electropositive charge is combined with another metal.
  • The ionization of water is a process in which water is ionized.
  • It is also known as self-ionization of water or autoionization of water, and it is characterized by the deprotonation (loss of a proton H+) of the water molecule (H2O) and the formation of a negatively charged ion (anion) OH-, also known as a hydroxide ion. 
  • The proton generated by the water molecule immediately protonated another water molecule, resulting in the formation of the Hydronium ion (H3O+), which demonstrates the amphoteric (can behave as both as an acid and a base) character of water. 

Ionic product of water

  • The ionic product is a constant that is used to represent the product of concentrations of ions of water. Ionic product of water is designated as Kw. 
  • The value increases as the temperature rises, indicating that the concentration of H+ and OH- ions increases as the temperature rises.
  • By this minute ionization, the volume of hydronium and hydroxide ions present in water remains almost unchanged at any given time. 
  • As a result, the concentration of undissociated water molecules remains virtually unaltered and may thus be called a constant at any given time. 

 

Autoionization of water 

  • According to the following equation, water undergoes auto-ionization: 

H2O(l) + H2O(l)  ⇄  H3O+(aq) + OH-(aq)

or

2 H2O(l) ⇄ H3O+(aq) + OH-(aq) 

  • The equilibrium expression for the preceding reaction is given below and is addressed mathematically in the same way that other equilibrium expressions are :

Kw = [H3O+][OH-]

  • Kw has been calculated to be 1 x 10-14 at 25°C. Because it relates to the autoionization of water, this number has been designated with a distinctive symbol, Kw, although it is just a particular instance of KC.
  • If the concentration of hydronium ions or hydroxide ions in a water solution is known, You may calculate the concentration of the other ion. 

Ionization of water formula

  • The self-ionization of water can be expressed as

 H2O + H2O ⇌ H3O+  + OH−

  • The equilibrium constant for the self-ionization of water is known as KW; it has a value of 1.0×10−14.
  • The value of Kw results in the following handy equation for the relationship between pH and pOH  is: 

 pH  + pOH  = 14. 

Conclusion 

Water is amphiprotic, which means that it may behave as an acid by giving a proton to a base to generate the hydroxide ion, or as a base by taking a proton from an acid to form the hydronium ion (H3O+). Autoionization of water results in the formation of OH- and H3O+ ions. The equilibrium constant for this reaction is termed the liquid water ion-product constant (Kw), and it is defined as Kw = [H3O+][OH-]. Kw equals 1.01 1014 at 25°C; 

so, pH + pOH = pKw = 14 . 

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