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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Chemistry » Ionic Compounds

Ionic Compounds

When metals and non-metals contact, they establish ionic bonds, leading to ionic compounds' formation. This study material helps you understand ionic compounds' properties, usage, and structure.

Table of Content
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We frequently encounter terminologies such as ions, anions, cations, and ionic compounds in chemistry. Understanding diverse concepts necessitates the study of such compounds. Ions are charged atoms or molecules.

The number of electrons and protons is equal in any atom, resulting in zero net charges. Because electrons have a negative charge and protons have a positive charge and remain the same whether an atom loses or acquires electrons, the net charge on the atom changes, resulting in the production of ions. When an atom loses electrons, it forms a positive ion, and when it receives electrons, it forms a negative ion. If a positive ion is present and combines with a negative ion, an ionic compound is formed.

Properties of Ionic Compounds

The strength with which positive and negative ions attract each other in an ionic bond determines the characteristics of ionic compounds. The following are the qualities seen in ionic compounds:

  • They condense into Crystals

Ionic compounds create crystal lattices rather than amorphous materials. Although molecular substances may form crystals, they generally do so differently from ionic crystals. Molecular crystals are typically fragile as compared to ionic crystals. At the atomic level, an ionic crystal is a regular structure in which the cation and anion alternate, forming a three-dimensional structure with the smaller ion evenly occupying the gaps between the larger ions.

  • Melting and Boiling Point

The melting and boiling points of ionic compounds are very high. High temperatures are necessary to counteract the attraction between the positive and negative ions in ionic compounds. As a result, ionic compounds take a lot of energy to melt or boil.

  • Hard and Brittle

They’re both delicate and tough. Positive and negative ions get attracted to each other, making it difficult to separate ionic crystals. 

  • Conduct Electricity

Since ionic substances dissolved in water have dissociated ions that transport electric charge through the solution, they easily conduct electricity. This is also the case for molten ionic compounds (molten salts).

  • Fusion Enthalpy and Vaporisation enthalpy 

Fusion and vaporisation enthalpies are frequently greater in ionic compounds than in other molecular molecules. Their enthalpies range from 10 to one hundred times that of molecular compounds.

  • Solubility

Ionic chemicals dissolve in polar solvents like water. They are less soluble in Nonpolar Covalent solvents.

Examples of Ionic Compounds

NaCl

An ionic compound is something like table salt. The ions sodium and chlorine combine to make sodium chloride or NaCl. The sodium atom loses an electron in this molecule, becoming Na+, while the chlorine atom receives an electron, becoming Cl⁻. Because the ions balance each other, they generate a neutral substance when mixed. The positive and negative charges in all ionic compounds must be balanced.

K2O

Another example of an ionic compound is potassium oxide or K2O. You may have noted that there are two potassium atoms for each oxygen atom this time, unlike in the sodium chloride example. This is because the ionic compound’s charges must be balanced. All you have to do is glance at the periodic chart to figure out how many of each ion will be in the compound.

Ionic Compound Structure

The structure of an ionic molecule is determined by the relative sizes of the cations and anions. Ionic solids are closely held together due to the electrostatic forces of attraction between positive and negative ions.

When chloride ions attract sodium ions, the 3-D structure of Na+ and Cl- ions are formed. The same happens vice versa. It’s nothing more than a sodium chloride crystal. Because there are equal quantities of sodium and chloride ions, the structure has no charge. The structure is held in place by the forces of attraction between ions. 

The formula for Ionic Characters

The amount of charge separation in polar covalent bonds is characterised as an ionic character. It aids in determining the difference in electronegativity between the two atoms.

Δχ = χB − χA

The binding polarity and ionic nature increase as the electronegativity difference grows.

Application of Ionic Compounds

  •  Seasoning for Food

Many minerals are ionic. Humans have been using Sodium Chloride, often known as common salt, for more than 8000 years. It’s actually used to season meals. It’s a part of ourselves that we come into contact with daily.

  • Preservative

Sodium chloride, generally known as common salt, is used as a preservative. In two typical ways, sodium chloride has been used to preserve foods. The primary and most usual method is to dehydrate food by drawing water. The most important role here is that all living things require water to flourish. Bacteria and other germs cannot survive if the water is removed from the food. This lowers the risk of food poisoning. It also destroys bacteria in another manner. In reality, salt is particularly poisonous to most bacteria, killing them while also preserving food.

  • Stimulants Found in Plants

 Salt has long been thought to be a very powerful plant growth stimulant, even though there has been little research on the subject. However, most experts believe that this is not a very successful usage since it may have a significant impact on the plant and, as a result, induce salt stress in plants.

  • Growth Regulators 

Some ionic chemicals can stimulate natural hormones while also allowing for the synchronisation of plant growth. Gibberellic acid is one of the most frequent plant regulators. This, along with several other factors, enhances the effect of long-day lengths on short-day plants, resulting in improved vegetative growth.

Conclusion

Ionic bonds are significant because they allow certain chemical molecules to be synthesised. Scientists may manipulate ionic characteristics and interactions to create desired results. I hope this study material notes on ionic chemistry help better understand ionic compounds’ properties, formulas, and advantages.

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