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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Chemistry » Homologous Series

Homologous Series

A homologous series is a sequence of compounds having the same functional group and similar chemical characteristics that might be branched or unbranched, or differ by -CH2 in organic chemistry. This can refer to the length of a carbon chain, such as in straight-chained alkanes (paraffins), or the number of monomers in a homopolymer like amylose.Compounds in a homologous series often have a fixed set of functional groups, resulting in chemical and physical properties that are comparable. (The primary straight-chained alcohols, for example, have a hydroxyl at the end of the carbon chain.) These qualities often change over time, and the variations are frequently explained by fluctuations in molecular size and mass. The term "homologous series" is also applied to any group of compounds with similar structures or that share the same functional group, such as alkanes (both straight and branched), alkenes (olefins), carbohydrates, and so on. If the members cannot be arranged in a linear order by a single parameter, the collection is more appropriately referred to as a "chemical family" or "class of homologous compounds" rather than a "series."

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Introduction

A homologous series is a collection of molecules with comparable chemical characteristics and functional groups that differ by CH2 from one another. In organic molecules with the same general formula, carbon chains of various lengths have been discovered. A series of organic compounds is formed by organic compounds that differ from one another by a repeating unit and have the same general formula. The most fundamental homologous series in organic chemistry is formed of alkanes

Homologous series examples

Each subsequent member differs from the previous by one CH2 unit. CH4 and C2H6 have a -CH2 unit difference, and C2H6 and C3H8 have a -CH2 unit difference as well. CH4, C2H6, and C3H8 are all homologous as a result. Alkenes with ethene as the first member and C3H6, C4H8, and C5H10 as the subsequent members show the same effect. They differ from one another by a –CH2 unit. Alkenes have the formula CnH2n.

The functional groups are the same for all members of this series. They have identical physical qualities that increase in mass in a fixed gradation. The characteristics of CH3OH, C2H5OH, and C3H7OH are similar and vary gradually as the molecular mass of subsequent members of the series increases. This is because the number of bonds increases as the molecular mass of the molecule increases. As a result, attributes reliant on the mass and total number of bonds in a compound, such as melting and boiling temperatures, solubility, and other properties, change gradually as the molecular masses of the compounds increase. Members of a homologous series have the same chemical features because they all have the same functional groups.

This series has allowed scientists and engineers to dig deeper into a variety of chemical compounds.Based on data from other members of the same homologous series, they can predict the properties of organic compounds belonging to that series. Organic compound research has been simplified.

Significance of homologous series

  1. Homologous series is a property of carbon compounds in which the number of carbon and hydrogen atoms in hydrocarbons varies according to a single parameter.
  2. Homologous series aid in the determination of the structure of each consecutive member of the series, as well as the prediction of the properties of those members.

Conclusion

Because the functional group of the molecule does not vary, homologues have comparable chemical properties. Keep in mind that the functional group is just the part of the molecule that is reactive or can change in chemical processes. Because each molecule in a homologous series has the same functional group, the homologues have identical reactivities.

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Why are homologous series' chemical characteristics always the same?

Ans: Because the functional group of the molecule does not vary, homologues ha...Read full

What are the advantages and disadvantages of homologous series?

Ans: The term “homologous series” is also applied to any set of mo...Read full

What are the three distinguishing characteristics of a homologous series?

Ans: The following are characteristics: ...Read full

What is the difference between homologous series and functional group?

Ans: The most important distinction between functional group and homologous se...Read full

Ans: Because the functional group of the molecule does not vary, homologues have comparable chemical properties. Keep in mind that the functional group is just the part of the molecule that is reactive or can change in chemical processes.

 

Ans: The term “homologous series” is also applied to any set of molecules with similar structures or that have the same functional group, such as alkanes (both straight and branched), alkenes (olefins), polysaccharides, and so on.

Ans: The following are characteristics:

  • The homologous series’ members all belong to the same functional group.The general formula is the same for all members.
  • Due to the same functional group, members exhibit nearly identical chemical characteristics.
  • Members have a common approach for preparing food.

Ans: The most important distinction between functional group and homologous series is that a functional group is a moiety of a chemical molecule that is responsible for its reactivity, whereas a homologous series is a sequence of chemical compounds with comparable functional groups and chemical reactivity.

Functional group and homologous series are two words that are often used interchangeably. This is due to the fact that chemical compounds’ functional groups form a homologous series.

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