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JEE Main 2026 Preparation: Question Papers, Solutions, Mock Tests & Strategy Unacademy » JEE Study Material » Chemistry » Homogenous Chemical Equilibrium

Homogenous Chemical Equilibrium

In chemical reactions, the product concentrations approach a fixed value because of the low reaction rate. This is called homogeneous chemical equilibrium.

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Homogeneous chemical equilibrium is a type of equilibrium wherein all components are in the same phase. Homogeneous chemical equilibrium is the state where the concentrations of all substances in a solution are the same. Homogeneous chemical equilibrium is a chemical system at equilibrium where reactions do not occur, and the chemical potential of the system is zero. This equilibrium is the most important in organic chemistry. In a homogeneous chemical system, the concentrations of all chemical species are relatively equal. A system with a high concentration is typically a gas, and a system with a low concentration is typically a liquid.

Details of homogeneous chemical equilibrium

In homogeneous chemical equilibrium, the concentrations of the reactants and products are in a state of equilibrium. A chemical reaction will produce a solution of products resulting in a decrease in the concentration of reactants and a concomitant increase in the concentration of products. The equilibrium constant is defined as the ratio of the concentrations of the reactants and products in a solution in the absence of any change in the concentration or activity of the solution.

How does a homogeneous chemical equilibrium form?

Homogeneous chemical equilibrium is the state of equilibrium in which all the constituents of a chemical system are present in the same phase (gas, liquid, solid, or solution). This type of equilibrium is usually established by changing the temperature or pressure. The constituents in the system tend to move towards equilibrium, and the system is in thermodynamic equilibrium.

Importance of homogeneous chemical equilibrium

Homogeneous chemical equilibrium is one of the most important principles of chemical physics because homogeneous chemical equilibrium is the state of a chemical mixture in which all reactants reach an equilibrium concentration. For example, if we have a reaction that creates 4 moles of water and 2 moles of oxygen gas.

 

Aqueous solutions are characterised by homogeneous chemical equilibrium. These solutions are not stable, and they transform when conditions change. For example, the reaction of water and air is not spontaneous, as it is in equilibrium.

 

Homogeneous chemical equilibrium is essential for chemical reactions at thermodynamic equilibrium but not in chemical equilibrium. It is important because it provides the maximum possible yield of the reaction.

Factors affecting homogeneous chemical equilibrium

Homogeneous chemical equilibrium is the most widely researched field in chemistry. The factors that influence homogeneous chemical equilibrium include temperature, pressure, volume, concentration, and solubility.

  • Temperature:

When temperature increases, the rate of chemical reaction increases because the molecules become less tightly bound and have more space available to interact with other molecules. When the temperature decreases, the rate of chemical reaction decreases because the molecules become more tightly bound and have less space available to interact with other molecules.

  • Pressure:

The equilibrium constant for a homogeneous chemical equilibrium is the ratio of the concentrations of the reactants and products in the equilibrium state and is therefore independent of the pressure. A change in pressure will change the total amount of gas in the system, which means that the equilibrium gas can only be in one location. An increase in pressure will cause the reactants to become less concentrated and the products to become more concentrated, and vice versa. Homogeneous equilibrium is always at maximum pressure. With increasing pressure, the equilibrium between the gas is driven to homogeneity.

  • Volume:

The dependence of homogeneous chemical equilibrium on volume is often expressed as Q = kVn, where Q is the reaction heat, k is a constant, and n is the number of moles of the reaction product (or solute). In a homogeneous system of a chemical element of known composition, the fraction of the atoms of a given component in a compound remains constant as the system volume increases or decreases. In the case of a compound composed of two or more chemical elements, the ratio of their concentrations will not vary as the volume of the system changes.

 

Concentration:

When the concentration of a certain chemical is increased, the equilibrium will shift to the right. The higher the concentration of the chemical, the higher the concentration of the other ions.

Examples of homogeneous chemical equilibrium

Aqueous solutions, a mixture of water and an acid dissolved in the water, are called homogeneous or a single phase. Aqueous solutions are very common and occur in many biological systems as well as inorganic systems. Homogeneous solutions are not true solutions because they lack dissociated ions.

 

A binary mixture of hydrogen and oxygen gas is considered an equilibrium. If one gas is taken away, there is a continuous reaction until equilibrium is reached. The two gases do not react to form a third gas. An example of this is that with equal amounts of water, there is no continuous reaction until equilibrium is reached.

Conclusion

Homogeneous chemical equilibrium is where the concentrations of the reactants and products are the same in all the phases. The products of a reaction are in equilibrium with the reactant species present. A chemical reaction is called homogeneous if the rate of reaction in a solution is constant throughout the solution. In this case, the reaction rate depends on the amount of reactants present, with a constant amount of products produced.

Understanding how a chemical bond is formed would involve understanding the concept of homogeneous chemical equilibrium. For example, the atoms in the solid are forced to be in a state of chemical equilibrium as they would be if it were a liquid.

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Frequently Asked Questions

Get answers to the most common queries related to the JEE Examination Preparation.

1. When are two substances said to be in homogeneous chemical equilibrium?

A1. Two substances are said to be in homogeneous chemical equilibrium when the concentrations of any substance are c...Read full

2. What is homogeneous equilibrium? How is it important for the formation of the Earth?

A2. Homogeneous chemical equilibrium is a form of chemical equilibrium in which the formation of compounds is balanc...Read full

3. What is the reaction rate of homogeneous chemical equilibrium?

A3. In a homogeneous chemical equilibrium, the reaction rate is equal to the product rate, and the forward reaction ...Read full

4. Give all the details about homogeneous chemical equilibrium.

A4. Homogeneous chemical equilibrium is the state of a mixture of gases where the concentrations of the gases are co...Read full

A1. Two substances are said to be in homogeneous chemical equilibrium when the concentrations of any substance are constant over time. The constant concentrations of the substances result in the same amount of each substance being at the boundary between the aqueous and non-aqueous phases of the solution.

A2. Homogeneous chemical equilibrium is a form of chemical equilibrium in which the formation of compounds is balanced by the formation of elements. It is an important concept to understand because the composition of the Earth is almost entirely based on homogeneous chemical equilibrium, and it is the only phase in which the Earth can exist. Homogeneous chemical equilibrium is the state of equilibrium that exists when the relative rates of the forward and reverse reactions are equal.

A3. In a homogeneous chemical equilibrium, the reaction rate is equal to the product rate, and the forward reaction rate is equal to the rate of the reverse reaction. The equilibrium constant is a measurement of how much of the products of a reaction are produced compared to the reactants.

A4. Homogeneous chemical equilibrium is the state of a mixture of gases where the concentrations of the gases are constant. In this state, a chemical reaction can proceed at a constant rate regardless of the temperature, and the reaction products are in equilibrium. In homogeneous equilibrium, a chemical reaction will not occur unless the concentrations of the reactants are above a certain threshold. For example, a reaction where the gases mixed are too diluted will not occur.

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