The Davisson and Germer Experiment was the first to prove that electrons are waves and to validate the de Broglie equation. In 1924, De Broglie hypothesized the dual nature of matter, but Davisson and Germer’s experiment did not validate the conclusions until much later. The findings proved quantum mechanics for the first time in an experimental setting. In this experiment, we will explore electron scattering by a Ni crystal.
The construction of the Davisson and Germer experiment includes a vacuum chamber in which the medium has no effect on electron deflection or scattering. The main elements of the experimental setup are as follows:
It is a Tungsten filament which produces electrons via thermionic emission, which means it emits electrons when heated to a specified temperature.
Two oppositely charged plates (+ve and -ve plate) are used to accelerate electrons at a known potential.
The accelerator is contained within a cylinder with a narrow channel for electrons flowing along its axis. Its function is to accelerate an electron beam that is narrow and straight (collimated).
Finding a nickel crystal is the objective. The electron beam is generally fired on the Nickel crystal. The crystal is set up so that it may be rotated around a fixed axis.
To collect the dispersed electrons from the Ni crystal, a detector is employed. The detector is moved in a semicircular arc.
The following are some of the conclusions we may derive from this experiment:
The Davisson and Germer experiment assumed that waves reflected from two different atomic layers of a Ni crystal will have a fixed phase difference. These waves will interact constructively or destructively after they have reflected. A diffraction pattern emerges as a result of this process.
In Davisson and Germer’s experiment, waves were used instead of electrons. A diffraction pattern was created when the electrons pulled together. As a result, the dual nature of matter has been established. The following diagram shows how the de Broglie equation and Bragg’s law are linked:
We have the following de Broglie equation:
λ = h/p
= h/ √(2mE)
= h/ √ (2m eV)
Where, m = mass of an electron
e = charge on an electron
h = Plank’s constant.
As a result, an electron has a wavelength determined by the equation for a given V.
The following equation expresses Bragg’s Law:
nλ = 2d sin (90° − θ ⁄ 2)
The wavelength of the waves that create a diffraction pattern can be derived from the equation for a variety of values because the value of d from the X-ray diffraction research was previously known.
The Davisson and Germer experiment give a scattering angle and a corresponding potential difference V at which electron scattering is maximum. As a result, applying these two values from Davisson and Germer’s data to both equations yields identical results for. De Broglie’s wave-particle duality is demonstrated as a result, and his equation is verified, as seen below:
λ = h/ √(2mE)
V = 54V
λ = 12.27/ √ (54) nm
= 0.167 nm
Using X-ray scattering, the value of ‘d’ has now been determined to be 0.092 nm. As a result, the angle of scattering is 50° when V = 54 V, and we can utilize this in the equation to get:
nλ = 2(0.092 nm) sin (90 ̊ – 50 ̊/2)
for n = 1, λ = 0.165 nm
The result of the experiment matches the theoretical values derived from the de Broglie equation quite well.
Electrons are dispersed off a crystalline nickel surface in the Davisson–Germer experiment. Electron matter wave diffraction patterns are noticed. They provide proof of the existence of matter waves. Diffraction investigations with various particles reveal matter waves. When electron beams are conducted through atomic crystals, diffraction occurs, as demonstrated by the Davisson and Germer experiment. This demonstrates that electrons’ wave nature can cause interference and diffraction.