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JEE Exam » JEE Study Material » Chemistry » Charles Law

Charles Law

Charles law was introduced in the eighteenth century by French physicist Jacques Charles. In his unpublished works, he explains this law in depth.

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Joseph and Etienne Montgolfier created the first hot air balloon in June 1783 by blowing a 30-foot [30 m]-long balloon into the sky. In order to adapt to the ground, the envelope had to walk one and a half kilometres above ground level. The word quickly travelled throughout France. As soon as he heard about the aircraft, Jacques-Alexandre-Cesar Charles was awestruck and proceeded to do the same investigation on his balloons and came up with Charles’ Law. Five balloons were filled with various gases, but with the same volume and pressure. Jacques Charles conducted a simple experiment. In other words, they were below 80 degrees Fahrenheit [80 degrees Celsius]. He observed that they all grew in the same manner.

What is Charles Law?

Charles’ law states that the gas volume is directly proportional to the total temperature at constant pressure. The law also states that Kelvin’s temperature and volume will be directly proportional to the pressure exerted on a dry gas sample.

Formula

Charles Law formula is written as,

VI /TI=VF /TF

VI =Initial volume

VF=Final volume

TI=Initial temperature

TF=Final temperature

It’s important to understand that these are absolute temperatures measured in Kelvin, not in degrees Fahrenheit or degrees Celsius.

Explanation

Physics professor James Clerk Maxwell came up with a quasi-explanation for the phenomenon. He claimed that the volume of space a gas occupies is determined by the velocity of its particles. Containing particles are continually tripping and colliding with one another. In the container, the fast assault of many gas particles consumes a lot of energy. This pressure is the result of the force. Despite the low impact force, a collision like this may exert a lot of pressure on the container area in combination.

A square inch of rubber is struck by about 1024 million helium atoms per second, travelling at velocities of up to a mile per second, inside a helium balloon. Pressure on gas may be described as “gas pressure.” The size of the impact and the force acting on a certain region are directly proportional to the gas pressure in the surrounding space. As a result, the more disagreement there is, the more stressful it is. Particle motion and collision frequency are both affected by gas temperature, as was discovered throughout the study. To put it another way, heated gases exert greater stress on the walls and generate higher pressures because they exert more pressure. That’s why it’s called the Gay-Lussac Law:

Important Note Regarding Charles’ Law

With a tighter or unchanged container capacity, the pressure in the container rises as the temperature increases. A good example of this may be seen in air pumps, which release steam or hot air when their piston is pushed or pulled. When it comes down to it, what about the ball? If this heated gas comes into contact with the ball, the pressure will rise, but it will only climb in discrete jumps, limiting the volume to a single, fixed figure. An explosion of high-energy particles pushes rubber outward, causing it to expand. Adhering to the Charles Law in the correct manner.

Applications Of Charles Law

Most people employ Charles’ Law with hot air balloons. Charles himself was prompted to consider the causes of inflation by an image he had in his mind of one of these undertakings. An item floating in a liquid is only possible if it weighs less than the amount of fluid it removes. Alternatively, an item will float if its thickness is greater than that of the liquid in which it is attempting to float. A summary of how hot air balloons function may be found in Charles’ law. Filling a heated gas-filled balloon should result in an increase in volume, according to Charles’ law. Because it has a lower density than cold air due to its increased volume, a balloon will rise when its volume is reduced by the weight of the surrounding air. In addition, this helps to explain why helium balloons contract when exposed to temperatures below zero degrees Fahrenheit. The stale air in the house naturally rises to the surface and escapes into the frigid air outside. Because cold air molecules travel slower and take up more space, internal pressure is reduced while warm air is moving. The volume of a balloon reduces as the temperature within it lowers.

Blown-out Tires: This is likely Charles’ Law’s second most often cited use. This rule is responsible for the thick tubes that come out of the tyre when it becomes stuck in the summer heat. As the temperature rises, the tyre expands, causing it to either malfunction or fully leak, as the heat pours into the tube. The tyre may burst at any time if it is subjected to additional expansion, fuelled by the inevitable heat dissipation generated by the impact. Ignorance and continual cycling might lead to highly severe outcomes. Tires should be checked often.

Whenever there is no liquid or liquid is right above the pistons in an automobile’s engine, a sequence of pistons are lined up and down. With a crankshaft that is unusually attached to either end of a piston, the pistons are able to rise and fall around the hole. Cars have two sets of rear wheels attached to this crankshaft, so as the rod spins, both wheels move in tandem with each other. Combustion generates a large amount of gas that drives the pistons in the engine. Heat radiates from a blazing fire. Thermal particles from transformed gas collide with moving pistons as temperatures rise. Then, they push the automobile in the right direction.

Conclusion

Charles’ law applies to gases only at high temperatures and low pressures. The relationship between volume and temperature is not naturally in line with high pressure. At high pressures, the resistance force between the molecules increases dramatically resulting in an increase in volume.

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Get answers to the most common queries related to the JEE Examination Preparation.

How is Charles' law formula applied?

Ans. Charles’ law is used to calculate an unknown volume or reaction temperature or process by continuous pres...Read full

How can you solve Charles's law formula?

Ans. Charles Law states that the given volume of gas is directly proportional to the total or Kelvin temperature of ...Read full

What is Boyle's law?

Ans. Boyle’s law states that “The given volume of a gas is equal to its pressure as long as the temperat...Read full

Ans. Charles’ law is used to calculate an unknown volume or reaction temperature or process by continuous pressure using the following calculation, VI /TI=VF /TF

Ans. Charles Law states that the given volume of gas is directly proportional to the total or Kelvin temperature of continuous pressure.

Let VI be a gas volume at a temperature of TI. By maintaining a constant pressure, if the gas temperature rises to TF, the volume will also rise to VF. Therefore, VI /TI=VF /TF

Ans. Boyle’s law states that “The given volume of a gas is equal to its pressure as long as the temperature remains constant”.

V∝1/P, at a constant temperature for a given weight of the gas.

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