JEE Exam » JEE Study Material » Chemistry » Aqueous Solutions of Salt of the Strong Acid and Weak Base

Aqueous Solutions of Salt of the Strong Acid and Weak Base

Salts can often react with the water to produce H3Oor OH–  when placed in water. This is called a hydrolysis reaction. It produces varying pH levels based on how strong the ion acts as a base or an acid. When the reaction of water and salts happens, there are lots of possibilities due to the varying structures of the salts. This salt can be made from either a strong acid and weak base or a strong base and weak acid. The reactants consist of a mixture of water and salt, and the product consists of a base (from the reaction side acid) or a binding acid (from the base of the reaction side).

These notes on pH aqueous will cover the meaning of pH aqueous, examples of strong acid and weak base combination, and aqueous solutions of salts.

Meaning of ph aqueous

The pH of an aqueous solution measures its acidity or alkalinity based on the concentration of hydrogen ions in it. The pH scale typically ranges from 0 to 14 in the water. Aqueous solutions with a pH of less than 7 are classified as acidic, while solutions with a pH of more than 7 are considered basic. Acidic solutions are high in hydronium concentrations and low in hydroxide concentrations. On the other hand, basic solutions are high in hydroxide concentrations and low in hydronium concentrations. Powerful acids may also have a negative pH, whereas strong bases could have a pH higher than 14.

Only in an “aqueous solution” or water can pH have any meaning. Many substances, especially liquids, do not even have pH values. If there is no water, there will be no pH. For example, there is no pH value for gasoline, vegetable oil, or pure alcohol. The term “pH” is derived from the German word “potenz”, which means “power”, combined with H, the chemical symbol for hydrogen. Thus pH stands for “power of hydrogen”. The pH equation was established in 1909 by Danish scientist Soren Peter Lauritz Sorensen. The ‘International Union of Pure and Applied Chemistry IUPAC uses a pH scale that is dependent on ‘electrochemical measurements of a standard buffer solution’.

According to this pH equation, the value of pH and hydrogen ions in an acidic or basic solution can be related as: 

pH = -log10[H+]  

The pH of an aqueous solution determines whether it will be acidic or basic. The ratio of hydronium ion concentration inside an aqueous solution can be used to determine and estimate the pH of the solution.

Strong acid and weak base examples

A complete ionisation reaction in water defines a strong acid. For example, when HCl is dissolved in water, the ionic bonds break, and hydrogen and chloride ions are produced. The solution contains no HCl molecules but ions; it is a strong acid. On the other hand, when a weak base is mixed into water, the solution contains hydroxyl ions, a metallic cation, and unionised molecules of the concerned base. 

The outcome of neutralising a weak base with a strong acid is a salt containing the conjugate acid of the weak base. This conjugate acid has a low pH Ammonium chloride, NH4Cl, a salt created by reacting the weak base ammonia with strong acid HCl.

Ammonium ions and chloride ions are present in this salt solution. The chloride ion has little effect on the pH of the solution because HCl is such a strong acid. Chloride is a fragile base that will not accept a proton substantially. Furthermore, the conjugate ‘acid of ammonia’ and ‘ammonium ion’ react with water and increase the ‘hydronium ion’ concentration.

Aqueous solutions of salts

The pH level should be kept constant at 7. Because this cation has no influence on the H+ and the anion does not absorb the H+ through water, ‘halides and alkaline metals’ dissolve and affect the H+. As a result of this, NaCl becomes a neutral salt. Salts containing halides and an alkaline metal degrade into observer ions.

Salts are formed from a weak base, and a weak acid hydrolysis in the same way as others, and they’re more complicated and must account for the Ka and Kb (dissociation constant of acid and base, respectively). When acid is more potent, it determines whether the solutions are acidic or basic. The cation will act as the acid, whereas the anion will act as the base, creating a hydronium ion or hydroxide ion, depending on which ion reacts with water more quickly.

Conclusion

The concentration of hydronium ions gives aqueous solutions acids their unique qualities. The reaction of the hydronium and hydroxide ions to generate water causes the neutralisation. It happens when aqueous solutions of acids and bases are mixed. Some salts generated during neutralisation processes can cause the resulting solutions to be acidic or primary. The pH of solutions containing hydrated metal ions or salts is dictated by the degree of hydrolysis of the ions present in the solution.

faq

Frequently Asked Questions

Get answers to the most common queries related to the JEE Examination Preparation.

What is aqueous pH?

Ans. The pH level of an ‘aqueous solution’ indicates whether it is acidic or basic. The percentage of hy...Read full

Do only aqueous solutions have pH values?

Ans. Since it is dependent on the ‘logarithm of the equilibrium process&...Read full

Can pH be negative?

Ans: Negative pH is possible and easy to calculate, but it is not something that can be easily measured. To evaluate...Read full

What is meant by non-aqueous solvent?

Ans: An inorganic non-aqueous solvent is a type of solvent that is not an organic chemical and is not watery. Such s...Read full

Do solvents have varying pH?

Ans: The pH scales of various solvents vary. For example, the neutral pH of acetonitrile is around 19, while that of...Read full