TS EAMCET Chemistry Syllabus – Engineering
Candidates appearing for TS EAMCET or Telangana State Engineering, Agriculture, and Medical Common Entrance Test in Engineering stream should refer the below mentioned Chemistry syllabus:
Chemistry
1. Classification of Elements and Periodicity in Properties
- Need to classify elements
- Genesis of periodic classification
- Modern periodic law and the present form of the periodic table
- Nomenclature of elements with atomic number greater than 100
- Electronic configuration of elements and the periodic table
- Electronic configuration and types of elements s, p, d and f blocks
- Trends in physical properties: (a) Atomic radius, (b) Ionic radius (c) Variation of size in inner transition elements, (d) Ionisation enthalpy, (e) Electron gain enthalpy, (f) Electronegativity
- Periodic trends in chemical properties: (a) Valence or Oxidation states, (b) Anomalous properties of second-period elements – diagonal relationship
- Periodic trends and chemical reactivity
2. Atomic Structure
- Introduction
- Sub-atomic particles
- Atomic models – Thomson’s Model
- Rutherford’s Nuclear Model of atom, Drawbacks
- Developments to Bohr’s model of the atom
- Nature of electromagnetic radiation
- Particle nature of electromagnetic radiation- Planck’s quantum theory
- Bohr’s model for the Hydrogen atom
- Explanation of line spectrum of hydrogen
- Limitations of Bohr’s model
- Quantum mechanical considerations of subatomic particles
- Dual behaviour of matter
- Heisenberg’s uncertainty principle
- Quantum mechanical model of an atom. Important features of the Quantum mechanical model of the atom
- Orbitals and quantum numbers
- Shapes of atomic orbitals
- Energies of orbitals
- Filling of orbitals in atoms. Aufbau Principle, Pauli’s exclusion Principle and Hund’s rule of maximum multiplicity
- Electronic configurations of atoms
- Stability of half-filled and completely filled orbitals
3. States of Matter: Gases and Liquids
- Thermal Energy
- Kinetic Molecular Theory Of Gases
- The Gas Laws
- Intermolecular Forces
- Thermal Interactions
- Intermolecular Forces and The Gaseous State
- Graham’s Law of Diffusion
- Dalton’s Law of Partial Pressures
- Ideal Gas Equation
- Kinetic Gas Equation of an Ideal Gas (No Derivation)
- Deduction of Gas Laws From Kinetic Gas Equation
- Distribution of Molecular Speeds – Rms, Average And Most Probable Speeds-Kinetic Energy of Gas Molecules
- Liquefaction of Gases
- The behaviour of Real Gases
- Deviation From Ideal Gas Behaviour
- Compressibility Factor and Pressure Diagrams of Real Gases
- Viscosity And Surface Tension (Qualitative Idea Only. No Mathematical Derivation)
- Liquid State – Properties of Liquids in terms of Intermolecular Interactions
- Vapour pressure
- Viscosity and Surface tension (Qualitative idea only, No mathematical derivation)
4. Chemical Bonding and Molecular Structure
- Kossel – Lewis approach to chemical bonding, Octet rule, Representation of simple molecules, formal charges, limitations of the octet rule
- General properties of ionic compounds
- Bond Parameters – bond length, bond angle, bond enthalpy, bond order, resonance – Polarity of bonds dipole moment
- Ionic or electrovalent bond – Factors favourable for the formation of the ionic compounds-Crystal structure of sodium chloride, Lattice enthalpy
- Hybridisation- different types of hybridization involving s, p and d orbitals- shapes of simple covalent molecules
- Valence Shell Electron Pair Repulsion (VSEPR) theory
- Predicting the geometry of simple molecules
- Valence bond theory-Orbital overlap concept-Directional properties of bonds-overlapping of atomic orbitals, the strength of sigma and pi bonds-Factors favouring the formation of covalent bonds
- Coordinate bond -definition with examples; Molecular orbital theory – Formation of molecular orbitals, Linear combination of atomic orbitals (LCAO)-conditions for the combination of atomic orbitals – Energy level diagrams for molecular orbitals -Bonding in some homo nuclear diatomic molecules- H2, He2, Li2, B2, C2, N2 and O2
- Hydrogen bonding-cause of formation of hydrogen bond – Types of hydrogen bonds-inter and Intra molecular-General properties of hydrogen bonds
5. Thermodynamics
- Thermodynamic Terms
- The System and The Surroundings
- Types of Systems and Surroundings
- The State of The System
- The Internal Energy As A State Function (a) Work (b) Heat (c) The general case, the first law of Thermodynamics
- Applications
- Work
- Thermodynamic Terms
- Enthalpy, H- A Useful New State Function
- The Relationship between Cp and Cv
- Measurement of ∆U And ∆H
- Calorimetry
- Heat Capacity
- Extensive and Intensive Properties
- Enthalpy Change, ∆rh of Reactions – Reaction Enthalpy – (a) Enthalpy Changes During Phase Transformations – (b) Standard Enthalpy of Reactions – (c) Thermochemical Equations – (d) Hess’s Law of Constant Heat Summation – (e) Standard Enthalpy of Formation
- Enthalpies For Different Types of Reactions – (a) Enthalpy of Atomization (∆ah ), Sublimation, Phase Transition And Ionisation – (b) Standard Enthalpy of Combustion (∆ch ) – (c) Bond Enthalpy (∆bondh ) – (d) Enthalpy of Dilution and Solution (∆solh )
- Spontaneity – (a) Entropy and Spontaneity, The Second Law of Thermodynamics – (b) Is the Decrease in Enthalpy a Criterion For Spontaneity? – (c) Gibbs Energy And Spontaneity
- Absolute Entropy and The Third Law of Thermodynamics
- Gibbs Energy Change And Equilibrium
6. Hydrogen and its Compounds
- Dihydrogen-Occurrence and Isotopes
- Properties And Preparation of Dihydrogen
- Position of Hydrogen in The Periodic Table
- Hydrides: Covalent, Ionic, and Non-Stoichiometric Hydrides
- Water: Physical Properties
- Structure of Water, Ice
- Chemical Properties of Water
- Hard And Soft Water, Permanent and Temporary Hardness of Water
- Hydrogen Peroxide: Preparation
- Physical Properties
- Chemical Properties and Structure
- Storage and Uses
- Heavy Water
- Hydrogen as a Fuel
7. Stoichiometry
- Some basic concepts – Properties of matter – uncertainty in Measurement – significant figures, dimensional analysis
- Percentage composition of compounds and calculations of empirical and molecular formulae of compounds
- Stoichiometry and stoichiometric calculations
- Methods of expressing concentrations of solutions-mass percent, mole fraction, molarity, molality and normality
- Laws of Chemical Combinations – Law of Conservation of Mass, Law of Definite Proportions, Law of Multiple Proportions, Gay-Lussac’s Law of Gaseous Volumes, Dalton’s Atomic Theory, Avogadro’s Law, Atomic and molecular masses- mole concept and molar mass. Concept of equivalent weight
- Redox reactions-classical idea of redox reactions, oxidation and reduction reactions-redox reactions in terms of electron transfer
- Balancing of redox reactions – oxidation number method Half reaction (ion-electron) method
- Redox reactions in Titrimetry
- Oxidation number concept
- Types of Redox reactions combination, decomposition, displacement and disproportionation reactions
8. The s Block Elements ( Alkaline And Alkali Earth Metals)
Group 1 Elements
- Alkali Metals
- Atomic And Ionic Radii
- Electronic Configurations
- Hydration Enthalpy
- Ionisation Enthalpy
- Chemical Properties
- Physical Properties
- General Characteristics of The Compounds of The Alkali Metals
- Oxides
- Uses
- Salts of Oxoacids
- Halides; Similarities Between Lithium And Magnesium
- Anomalous Properties of Lithium: Differences and Similarities with Other Alkali Metals, Diagonal Relationship; Sodium Hydrogen Carbonate
- Some Important Compounds of Sodium: Sodium Carbonate; Sodium Hydroxide; Sodium Chloride; Electronic Configuration
- Ionisation Enthalpy; Biological Importance of Sodium and Potassium
Group 2 Elements: Alkaline Earth Elements
- Hydration Enthalpy
- Physical Properties
- Chemical Properties
- Uses
- General Characteristics Of Compounds of The Alkaline Earth Metals: Oxides, Hydroxides
- Halides, Salts of Oxoacids (Carbonates; Sulphates And Nitrates)
- Anomalous Behaviour of Beryllium
- Its Diagonal Relationship with Aluminium
- Some Important Compounds of Calcium: Preparation and Uses of Calcium Oxide
- Calcium Carbonate
- Plaster of Paris
- Calcium Hydroxide
- Cement
- Biological Importance of Magnesium and Calcium
9. P- Block Elements Group 13 (Boron Family)
- General Introduction
- Ionisation Enthalpy
- Atomic Radii
- Electronic Configuration
- Electronegativity
- Chemical and Physical Properties
- Some Important Compounds of Boron
- Borax, Ortho Boric Acid, Diborane
- Important Trends And Anomalous Properties of Boron
- Uses of Aluminium, Boron, and Their Compounds
10. P-Block Elements – Group 14 (Carbon Family)
- General Introduction
- Electronic Configuration
- Atomic Radii
- Ionisation Enthalpy
- Electronegativity
- Physical & Chemical Properties
- Important Trends And Anomalous Properties Of Carbon
- Allotropes Of Carbon
- Uses Of Carbon
- Some Important Compounds Of Carbon And Silicon – Carbon Monoxide, Carbon Dioxide, Silica, Silicones, Silicates And Zeolites
11. Chemical Equilibrium and Acids-Bases
- Equilibrium in Physical processes
- Equilibrium in chemical processes – Dynamic Equilibrium
- Heterogeneous Equilibria
- Law of chemical Equilibrium – Law of mass action and Equilibrium constant
- Homogeneous Equilibria, Equilibrium constant in gaseous systems. Relationship between KP and Kc
- Applications of Equilibrium constant; Relationship between Equilibrium constant K, reaction quotient Q and Gibbs energy G
- Ionic Equilibrium in solutions
- Acids, bases and salts- Arrhenius, Bronsted-Lowry and Lewis’s concepts of acids and bases
- Factors affecting Equilibrium.- Le Chatelier’s principle application to the industrial synthesis of Ammonia and Sulphur trioxide
- The ionisation of Acids and Bases – Ionisation constant of water and its ionic product- pH scale-ionisation constants of weak acids-ionisation of weak bases-relation between Ka and Kb-Di and poly basic acids and di and poly acidic Bases-Factors affecting acid strength-Common ion effect in the ionisation of acids and bases-Hydrolysis of salts and pH of their solutions
- Solubility Equilibria of sparingly soluble salts
- Solubility product constant, Common ion effect on the solubility of ionic salt
- Buffer solutions designing of buffer solution-Preparation of Acidic buffer
12. Organic Chemistry – Some Basic Principles, Techniques And Hydrocarbons
Some Basic Principles And Techniques:
- General Introduction
- Tetravalency Of Carbon – Shapes Of Organic Compounds
- Structural Representations Of Organic Compounds
- Classification Of Organic Compounds
- Isomerism
- Nomenclature Of Organic Compounds
- Fission Of Covalent Bond
- Nucleophiles And Electrophiles
- Electron Movements In Organic Reactions
- Fundamental Concepts In Organic Reaction Mechanisms
- Electron Displacement Effects In Covalent Bonds
- Inductive Effect
- Electromeric Effect Resonance Effect
- Resonance
- Hyperconjugation
- Methods Of Purification Of Organic Compounds
- Types Of Organic Reactions
- Quantitative Elemental Analysis Of Organic Compounds
- Qualitative Elemental Analysis Of Organic Compounds
Hydrocarbons:
Classification of Hydrocarbons:
Alkanes –
- Nomenclature, isomerism (structural and conformations of ethane only); Preparation of alkanes
- Properties – Physical properties and chemical Reactivity, Substitution reactions – Halogenation(a free radical mechanism), Combustion, Controlled Oxidation, Isomerisation, Aromatization, reaction with steam and Pyrolysis
Alkenes-
- Nomenclature, the structure of ethene, Isomerism (structural and geometrical)
- Methods of preparation
- Properties- Physical and chemical reactions: Addition of Hydrogen, halogen, water, sulphuric acid, and Hydrogen halides (Mechanism- ionic and peroxide effect, Markovnikov’s, anti-Markovnikov’s or Kharasch effect). Oxidation, Ozonolysis and Polymerization
Alkynes –
- Nomenclature and isomerism, the structure of acetylene- Methods of preparation of acetylene
- Physical properties, Chemical reactions- the acidic character of acetylene, addition reactions- of hydrogen, Halogen, Hydrogen halides and water. Polymerization
Aromatic Hydrocarbons –
- Nomenclature and isomerism, Structure of benzene, Resonance and aromaticity
- Preparation of benzene
- Physical properties
- Chemical properties: Mechanism of electrophilic substitution
- Electrophilic substitution reactions – Nitration, Sulphonation, Halogenation, Friedel-Crafts alkylation and acylation
- Directive influence of functional groups in mono substituted benzene, Carcinogenicity and toxicity
13. Solutions
- Types of Solutions
- Expressing Concentration of Solutions – Volume Percentage, Mass Percentage, Parts Per Million, Mole Fraction, Mass By Volume Percentage, Molarity And Molality
- Solubility: Solubility of a Solid in a Liquid, Henry’s Law, The Solubility of a Gas in a Liquid
- Vapour Pressure of Liquid Solutions: Vapour Pressure of Liquid-Liquid Solutions, Raoult’s Law as a Special Case of Henry’s Law -Vapour Pressure of Solutions of Solids in Liquids
- Ideal and Non-Ideal Solutions
- Colligative Properties and Determination of Molar Mass-Relative Lowering of Vapour Pressure-Elevation of Boiling Point-Depression of Freezing Point-Osmosis and Osmotic Pressure-Reverse Osmosis and Water Purification
14. Environmental Chemistry
- Definition of Terms: Soil, Air and Water Pollution
- Environmental Pollution
- Tropospheric Pollution
- Atmospheric Pollution
- Gaseous Air Pollutants (Oxides of Nitrogen; Oxides of Sulphur
- Oxides of Carbon (Co, Co2)
- Hydrocarbons
- Greenhouse Effect and Global Warming
- Acid Rain- Particulate Pollutants- Smog
- Stratospheric Pollution: Breakdown and Formation of Ozone- Ozone Hole- Effects of Depletion of The Ozone Layer
- Water Pollution: Causes of Water Pollution
- International Standards for Drinking Water
- Soil Pollution: Industrial Wastes, Pesticides
- Strategies to Control Environmental Pollution- Waste Management- Collection And Disposal; Green Chemistry: Green Chemistry in Day-To-Day Life
- Dry Cleaning of Clothes
- Synthesis of Chemicals
- Bleaching of Paper
15. Solid State
- General Characteristics of Solid-State
- Classification of Crystalline Solids Based on Different Binding Forces ( Metallic, Ionic, Molecular, And Covalent Solids)
- Amorphous and Crystalline Solids
- Probing The Structure of Solids
- X-Ray Crystallography
- Crystal Lattices and Unit Cells
- The Number of Atoms in a Unit Cell (Primitive, Body Centred and Face Centred Cubic Unit Cell); Packing Efficiency in Simple Cubic, Bcc and in Ccp, Hcp Lattice;
- Close Packed Structures
- Close Packing in One Dimension, in Two Dimensions and in Three Dimensions- Tetrahedral and Octahedral Voids- Formula of a Compound And Number of Voids Filled-Locating Tetrahedral and Octahedral Voids
- Imperfections in Solids-Types of Point Defects-Stoichiometric And Non-Stoichiometric Defects
- Calculations Involving Unit Cell Dimensions-Density of The Unit Cell
16. Electrochemistry and Chemical Kinetics
Electrochemistry
- Nernst equation-equilibrium constant from Nernst equation – electrochemical cell and Gibbs energy of the cell reaction
- Electrolysis: Faraday’s laws of electrolysis-products of electrolysis
- Conductance of electrolytic solutions – measurement of the conductivity of ionic solutions-variation of conductivity and molar conductivity with concentration-strong electrolytes and weak electrolytes-applications of Kohlrausch’s law
Chemical Kinetics
- Rate of a chemical reaction
- Factors influencing the rate of a reaction: dependence of rate on concentration- rate expression and rate constant- order of a reaction, molecularity of a reaction
- Pseudo-first-order reaction
- Temperature dependence of the rate of a reaction – Effect of catalyst
- Integrated rate equations-zero order reactions-first order reactions – the half-life of a reaction
17. P-Block Elements
Group-15 Elements:
- Occurrence- electronic configuration, atomic and ionic radii, ionisation enthalpy, electronegativity, physical and chemical properties
- Dinitrogen Preparation, properties and uses
- Compounds of nitrogen-preparation, properties and uses of ammonia
- Oxides of nitrogen
- Preparation and properties and uses of nitric acid
- Phosphorus Allotropic forms
Group-16 Elements:
- Occurrence – atomic and ionic radii, electronic configuration, ionisation enthalpy, electronegativity, electron gain enthalpy, physical and chemical properties
- Dioxygen-preparation, properties and uses
- Simple oxides
- Sulphur-allotropic forms
- Ozone-preparation, properties, structure and uses
- Sulphuric acid- properties and uses only
- Sulphur dioxide-preparation, properties and uses
- Oxoacids of sulphur
Group-17 Elements
- Occurrence, electronic configuration, atomic and ionic radii, ionisation enthalpy, electron gain enthalpy, electronegativity, physical and chemical properties
- Hydrogen chloride- preparation, properties and uses
- Oxoacids of halogens
- Chlorine- preparation, properties and uses
- Interhalogen compounds
Group-18 Elements
- Occurrence, electronic configuration, atomic radii, electron gain enthalpy, ionization enthalpy, physical and chemical properties (a) Xenon-fluorine compounds – XeF2, XeF4 and XeF6 -preparation, hydrolysis and formation of fluoro anions-structures of XeF2, XeF4 and XeF6 (b) Xenon-oxygen compounds XeO3 and XeOF4 – their formation and structures. Uses
18. Surface Chemistry
- Adsorption and absorption: Distinction between adsorption and absorption-mechanism of adsorption-types of adsorption-characteristics of physisorption characteristics of chemisorption-adsorption isotherms-adsorption from solution phase applications of adsorption
- Colloids
- Classification of colloids: Classification based on physical state of dispersed phase and dispersion medium- classification based on nature of interaction between dispersed phase and dispersion medium- classification based on type of particles of the dispersed phase- multi molecular, macromolecular and associated colloids- cleansing action of soaps-preparation of colloids-purification of colloidal solutions- properties of colloidal solutions Tyndal effect, colour, Brownian movement-charge on colloidal particles, electrophoresis. Coagulation or precipitation, Coagulation of lyophilic sols, protection of colloids, Colloids around us, Applications of colloids
19. d and f Block Elements and Coordination Compounds
d And f Block Elements:
- Position In The Periodic Table
- Electronic Configuration Of The D-Block Elements
- General Properties Of The Transition Elements (D-Block)
- Variation In Atomic And Ionic Sizes Of Transition Series
- Oxidation States
- Ionisation Enthalpies
- Physical Properties
- Trends In The M²+ /M And M³+ /M²+ Standard Electrode Potentials
- Trends Instability Of Higher Oxidation States
- Chemical Reactivity And Eθ Values
- Catalytic Properties
- Formation Of Coloured Ions
- Magnetic Properties
- Formation Of Complex Compounds
- Alloy Formation
- Formation Of Interstitial Compounds
Coordination Compounds:
- Werner’s Theory Of Coordination Compounds
- Definitions Of Some Terms Used In Coordination Compounds
- Nomenclature Of Coordination Compounds – IUPAC Nomenclature
- Isomerism in Coordination Compounds –
- Structural Isomerism– Linkage, Ionisation, Coordination and Hydrate Isomerism,
- Stereo Isomerism– Geometrical and Optical Isomerism
- Bonding In Coordination Compounds
(a) Crystal Field Theory
(i) Crystal Field Splitting Into Octahedral And Tetrahedral Coordination Entities
(ii) Colour In Coordination Compounds-Limitations Of Crystal Field Theory
(b) Valence Bond Theory – Magnetic Properties Of Coordination Compounds-Limitations Of Valence Bond Theory
- Bonding In Metal Carbonyls
- Importance And Applications Of Coordination Compounds
- Stability Of Coordination Compounds
20. Haloalkanes and Haloarenes
- Classification And Nomenclature
- Nature Of C-X Bond
- Methods Of Preparation: Alkyl Halides And Aryl Halides-From Alcohols, From Hydrocarbons
(a) By Electrophilic Substitution
(b) By Free Radical Halogenation
(c)By The Addition Of Hydrogen Halides And Halogens To Alkenes-By Halogen Exchange (Finkelstein Reaction)
(d) By Replacement Of Diazonium Group (Sandmeyer Reaction)
- Physical Properties-Melting And Boiling Points, Density And Solubility
- Chemical Reactions: Reactions Of Haloalkanes
(i) Nucleophilic Substitution Reactions
-SN¹ Mechanism
-SN² Mechanism
-Stereochemical Aspects Of Nucleophilic Substitution Reactions-Optical Activity
(ii)Reaction With Metals-Reactions Of Haloarenes:
-Nucleophilic Substitution
-Electrophilic Substitution
-Elimination Reactions
(iii) Elimination reactions
21. Biomolecules
Carbohydrates– Classification of carbohydrates-Monosaccharides: preparation of glucose from sucrose and starch- Properties and structure of glucose – D, L and (+), (-) configurations of glucose- Structure of fructose.
Amino acids– Natural amino acids – classification of amino acids – structures and D and L forms-Zwitterions.
Proteins– Structures, classification, fibrous and globular- primary, secondary, tertiary and quaternary structures of proteins- Denaturation of proteins.
Nucleic acids– chemical composition of nucleic acids, structures of nucleic acids, DNA fingerprinting, biological functions of nucleic acids.
22. Organic Compounds Containing C, H And O (Alcohols, Phenols, Ethers, Aldehydes, Ketones and Carboxylic Acids)
Alcohols, Phenols And Ethers Alcohols, Phenols And Ethers –
- Classification
- Nomenclature
(a) Phenols
(b) Alcohol
(c) Ethers
- Structures of Hydroxy and Ether Functional Groups
- Methods of Preparation-Phenols from Haloarenes, Alcohols From Alkenes and Carbonyl Compounds (Reduction And Reaction with Grignard Reagents); Benzene Sulphonic Acid, Diazonium Salts, Cumene
- Chemical Reactions of Alcohols and Phenols
(i)Reactions Involving Cleavage of C-O Bond – Reactions With HX, PX3, Dehydration And Oxidation
(ii)Reactions Involving Cleavage of O-H Bond-Acidity Of Alcohols And Phenols, Esterification
(iii)Reactions of Phenols – Electrophilic Aromatic Substitution, Kolbe’s Reaction, Physical Properties of Alcohols and Phenols
- Reimer – Tiemann Reaction, Oxidation, Reaction with Zinc Dust
- Ethers – Methods of Preparation: By Dehydration of Alcohols
- Williamson Synthesis
- Physical Properties
- Chemical Reactions: Cleavage of C-O Bond and Electrophilic Substitution of Aromatic Ethers
Carboxylic Acids:
- Nomenclature and Structure of Carboxyl Group
- Methods of Preparation of Carboxylic Acids
(i) From Alkylbenzenes
(ii) From Primary Alcohols and Aldehydes
(iii) From Grignard Reagents
(iv) From Nitriles and Amides
(v) From Esters
(vi) From Acyl Halides and Anhydrides
- Physical Properties
- Chemical Reactions-
(i) Reactions Involving Cleavage of C-Oh Bond-Formation of Anhydride, Reactions With PCl5, PCl3, SOCl2, Esterification And Reaction With Ammonia
(ii) Reactions Involving Cleavage of O-H Bond-Acidity, Reactions With Metals And Alkalis
(iii) Substitution Reactions in The Hydrocarbon Part – Halogenation and Ring Substitution
(iv) Reactions Involving-Cooh Group-Reduction, Decarboxylation
- Uses of Carboxylic Acids
Aldehydes And Ketones:
- Nomenclature And Structure of Carbonyl Group
- Preparation of Aldehydes And Ketones-
(i) From Hydrocarbons
(ii) By Oxidation of Alcohols
(iii) By Dehydrogenation of Alcohols
- Preparation of Aldehydes
(i) From Chlorides and Esters
(ii) From Acyl Hydrocarbons
(iii) From Nitriles
- Preparation of Ketones
(i) From Acyl Chlorides
(ii) From Benzene or Substituted Benzenes
(iii) From Nitriles
- Physical Properties of Aldehydes and Ketones
- Chemical Reactions of Aldehydes And Ketones-Nucleophilic, Oxidation, Reduction, Addition, Reactions Due to Alpha Hydrogen and Other Reactions ( Electrophilic Substitution Reaction, Cannizzaro Reaction)
- Uses of Ketones and Aldehydes
23. Organic Compounds Containing Nitrogen: Amines
- Structure of amines
- Classification
- Nomenclature
- Preparation of amines: reduction of nitro compounds, reduction of nitriles, reduction of amides, ammonolysis of alkyl halides, Gabriel phthalimide synthesis and Hoffmann bromamide degradation reaction
- Physical properties
- Chemical reactions: the basic character of amines, acylation, carbylamine reaction, reaction with nitrous acid, alkylation, electrophilic substitution of aromatic amines-bromination, reaction with aryl sulfonyl chloride, nitration and Sulphonation
Note: Candidates must note that the following topics are deleted for the Academic Year 2020-21 by the TSBIE for the TS EAMCET-2021 Examination.
Chapter 1 Solid State
- Magnetic Properties (Band Theory of Metals, Conductors, Semiconductors
- Insulators And N And P-Type Semiconductors)
- Electrical Properties
Chapter 2 Solutions
- Abnormal Molar Masses-Van’t Hoff Factor
Chapter 3 Electrochemistry and Chemical Kinetics
Electrochemistry
- Galvanic Cells
- Electrochemical Cells
- Corrosion Of Metals-Hydrogen Economy
- Batteries: Primary And Secondary Batteries
- Electrolytic Cells
- Fuel Cells
Chemical Kinetics
- Collision Theory Of Chemical Reaction Rates
Chapter 4 Surface Chemistry
- Emulsions – Types of Emulsions
- Catalysis, Homogenous and Heterogenous, Adsorption Theory of Heterogeneous Catalysis, Activity And Selectivity of Solid Catalysis, Shape-Selective Catalysis by Zeolites, Enzyme Catalysis, Catalysts in Industry
Chapter 5 General Principles of Metallurgy
- Entire Chapter is Deleted
Chapter 6 p-Block Elements
Group-15 Elements
- Oxoacids of Phosphorus
- Phosphine-Preparation, Properties and Uses
- Phosphorus Halides
Group -16 Elements
- Sulphuric Acid-Manufacture
Chapter 7 D and F Block Elements & Coordination Compounds
D And F Block Elements
- Inner Transition Elements
- Some Important Compounds of Transition Elements
- Some Applications of D And F Block Elements
- Actinoids
Chapter 8 Polymers
- Entire Chapter Is Deleted
Chapter 9 Biomolecules
- Enzymes: Enzymes, Mechanism of Enzyme Action
- Disaccharides (Sucrose, Lactose, Maltose), Polysaccharides (Starch, Cellulose,
- Glycogen), Importance of Carbohydrates.
- Hormones
- Vitamins
Chapter 10 Chemistry in Everyday Life
- Entire Chapter Is Deleted
Chapter 11 HaloAlkanes and Halo Arenes
- Polyhalogen Compounds
Chapter 12 Organic Compounds Containing C, H And O
- Some Commercially Important Alcohols (Uses With Special Reference To Methanol And Ethanol)
Chapter 13 Organic Compounds Containing Nitrogen
Diazonium Salts
- Physical Properties
- Methods of Preparation of Diazonium Salts
- Importance of Diazonium Salts in Synthesis of Aromatic Compounds
- Chemical Reactions
Cyanides and Isocyanides
- Preparation, Physical Properties and Chemical Reactions of Cyanides
- Isocyanides
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