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Answer: Tallying the number of atoms on both sides, we find that they are unbalanced.
On left Fe=1, O=2, on right Fe=2, O=3
Fe+O2 → Fe2O3
Balancing O2 molecules,
Fe+3O2 → Fe2O3
Left: O= 3 x 2= 6, Fe=1
Right: O= 3, Fe=2
Balancing right side to obtain 6 molecules of O,
Fe+3O2 → 2Fe2O3
Right: O= 6, Fe=4
O is balanced, on left Fe=1 and on right Fe=4
So, 4Fe+3O2 → 2Fe2O3
Left: O= 6, Fe=4
Hence, the equation is balanced.