There are many compounds known as “oxides” that are made up of chemical components that are bonded mostly to oxygen. The inert and more stable character of noble gases, on the other hand, prevents them from forming these compounds. In contrast to most metals and nonmetals, which create oxides with varying oxidation states, some chemical elements form oxides with a constant oxidation state. For example, magnesium only forms magnesium oxide, with the chemical formula MgO, while vanadium forms multiple oxides, such as V2O3 and V2O5.
Oxygen atoms are the primary binding partner for the metals in metal oxides, an inorganic chemical molecule. The oxidation state -2 of these compounds makes oxygen effectively an anion. As a result, metal serves as the compound’s cation. Alkaline earth metals (group 2 elements), alkali metals (group 1 elements), and elements of the d block, including transition metals, are the metals that can form oxides. These compounds are made up of ionic oxides, which have an ionic character. However, some chemical elements produce covalent oxides, particularly those with higher oxidation states.
Metal Oxides
Metal oxides are frequently crystallised solids and often basic substances in nature. This reaction results in an alkaline solution, which can be used as a cleaning agent. Through neutralisation, they can also generate salts by reacting with acids. Oxides with oxidation states of -1 and -1/2, which we refer to as peroxides and superoxides, exist even though most have oxygen with a -2 oxidation state. As the metal undergoes oxidation, its oxygen atom count changes.
Non-metallic Oxides
Oxides of nonmetals are inorganic chemical compounds that are made up of nonmetals and oxygen. The nonmetals we have include p block elements. Thus these compounds are mainly composed of these elements. Because they tend to share electrons with other atoms, such as oxygen atoms, nearly all nonmetal oxides are covalent compounds.
Because they are acidic chemicals, when dissolved in water, they produce acid. In the same way, they can react with bases to generate salts by neutralisation. In addition, they can form oxyacids, which can then react with water to create hydroxides.
Differences between Metal and Nonmetal Oxides
These two chemical compounds have a significant difference:
Metal oxides | Non metal oxides |
Inorganic chemical compounds made up of metals . | Inorganic chemical compounds made of nonmetals and oxygen |
Examples of metallic oxides are CO2, SO2, P2O5, CO, etc. | Examples of non metallic oxides are SO ₂ , ClO ₂ ,SO ₃ , NO ₂ etc. |
Metal oxides are acidic substances. | Non-metal oxides are basic in nature. |
Metal oxides are usually ionic substances | Nonmetal oxides are covalent. |
Metal oxides tend to create alkaline solutions in water. Metal oxide + Water → Metal hydroxide Example: CaO + H2O → Ca(OH)2 | Non-metal oxides prefer to form acidic ones. Non metal + water→ Oxy acids Example: CO2 +H2O → H2CO3 |
Metal oxides react with acids. Metal oxide + Acid → Salt + Water Example: CaO + HCl → CaCl2 + H2O | Non-metal oxides reacts with bases. Non-metal oxide + Base→ Salt + Water Example: CO2 +2NaOH → Na2CO3+ H2O |
Chemical Properties of Oxides
At least one oxygen atom and another element are found in the chemical formula of an oxide. An oxygen anion in the oxidation state of -2 is common in metal oxides. Solid oxides make up the vast majority of Earth’s crust, the byproducts of elements being oxidised by oxygen in the atmosphere or water, resulting in solid oxides. Carbon monoxide (CO) and carbon dioxide (CO2) are the two primary carbon oxides produced during hydrocarbon burning (CO2). Sometimes even the purest elements develop an oxide layer. For example, aluminium foil is protected from further corrosion by a thin layer of Al2O3.
Because of oxygen’s electronegativity, it forms stable chemical bonds with nearly every element to produce the oxides. Due to their resistance to direct chemical reactions with oxygen, noble metals (such as gold or platinum) are highly sought after. Hydrolysis and oxidation by oxygen are two separate ways that elements can be corroded. The corrosive effects of water and oxygen are amplified. Oxygen or an oxygen-rich environment is required for the combustion of nearly all elements.
As water and oxygen (or just air) react with specific elements, such as sodium (for example), hydroxide products are formed. Alkali and alkaline earth metals do not occur naturally in metallic form partly because of this. Because of its high reactivity with oxygen, caesium is commonly employed in vacuum tubes as a getter. Some organic solvents can be deoxygenated and dehydrated using solutions of potassium and salt.
Conclusion
Oxides are chemical compounds containing one or more oxygen atoms and either a metal or a nonmetal as a bonding agent. The key to understanding the distinction between metal and nonmetal oxides is that metal oxides are acidic while the latter is basic.Oxidation occurs more frequently on materials considered to be pure elements. At least one element must be present for oxide to be a chemical compound. When oxygen and another element are combined to form a metallic or non-metallic oxide, the resulting product is a binary compound.