Phosphoric acid

In chemical laboratories, phosphoric acid is often found as an 85 percent aqueous solution, which is a colourless, odourless, and non-volatile syrupy liquid. Despite the fact that phosphoric acid does not satisfy the legal definition of a strong acid, the 85 percent solution can cause significant skin irritation and eye damage. To variable degrees, all three hydrogens are acidic and can be lost from the molecule as H+ ions (protons). The orthophosphate ion PO43−, sometimes known as “phosphate,” is formed when all three H+ ions are eliminated. The dihydrogen phosphate ion H2PO4−  and the hydrogen phosphate ion HPO42- are formed by removing one or two protons, respectively.            

Phosphoric acid formula and structure:

H3PO4 is the chemical formula for phosphoric acid.  H3O4P is the molecular formula for it. The structure of Phosphoric Acid is made up of a core Phosphorus atom that is linked to an oxygen atom by a double bond. A single connection connects it to three hydroxyls as well.

Physical properties:

Phosphoric acid has the following physical properties:

• It is a colourless, odourless, viscous liquid with a high degree of reddening litmus property and a density of 1.834 .
• It has a melting point of 42.35 degrees Celsius and is white and crystal-like when solid.
• It is naturally non-toxic and non-volatile.
• When exposed to red heat and cooled, it creates a clear brittle glass.
• When heated, the acid preserves its original composition while gaining new properties.
• In  water, the most widely utilised Phosphoric acid content is 85 percent.

Chemical properties:

Phosphoric acid has the following chemical properties: 

• It can release up to three hydrogen ions, allowing it to react differently than mineral acids.
• By substituting one, two, or three hydrogen atoms in a reaction with bases, three kinds of salts are formed. 
• As observed in Polyphosphoric and Meta Phosphoric acids, when molecules are subjected to high temperatures, they form dimers, trimers, and lengthy polymeric chains.

Preparation of phosphoric acid:

Wet process:

Phosphoric acid is generated in a wet process from fluorapatite, a crystal rock that includes the phosphate mineral. Concentrated sulfuric acid and water are used to react the chemical. The reaction produces phosphoric acid and sulphate, as well as several additional contaminants. Filtration and evaporation are used to eliminate surplus chemical compounds and contaminants. This procedure produces impure acid, which is frequently utilised in fertiliser production without additional purification.

 Thermal process:

The phosphorus is heated or burned at a high temperature in the presence of air in this chemical reaction. Phosphorous pentoxide is produced as a result of the burning or heating, and it is condensed to form a white powder. Phosphoric acid is made by hydrating this white powder in a separate procedure.

 Uses of phosphoric acid:

• It’s used in agriculture to make fertilisers and as a flavouring agent in animal and poultry feed.
• Dentistry: It is used as an etching solution and for tooth cleaning in dentistry. It’s also found in a variety of mouthwashes. It can also be present in anti-nausea medications.
• When phosphate conversion coating is used to treat rust, phosphoric acid is employed to prevent corrosion. It is used to remove rust from metal compositions and to treat them.
• It’s utilised in skin care products as a pH-controlling ingredient. It’s in toothpaste, soaps, and detergents, among other things.
• It’s utilised in food processing as a food additive as well as to acidify foods and beverages. It’s also employed in the dairy industry.

 Hazards of phosphoric acid:

Phosphoric acid is not poisonous or dangerous. It is safe to apply on the skin and even to eat in low amounts (it is used in food, cosmetics and dental products). It is, however, caustic in high doses and can cause skin burns. The skin and mucous membranes are irritated by strong phosphoric acid solutions. If phosphoric acid vapours are inhaled, they can be lethal. The vapours produced by high temperatures can irritate the respiratory tract, as well as the eyes and skin. 

Conclusion

Phosphoric acid is a naturally occurring mineral acid. This indicates that it is an inorganic acid. One or more inorganic substances are used to make them. They are made from inorganic phosphate rocks in the case of phosphoric acid. White phosphorus can also be used to make acid with a higher purity. Sulphuric acid, hydrochloric acid, and nitric acid are examples of mineral acids. Mineral acids, when dissolved, produce hydrogen ions and conjugate base ions.