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NEET UG 2026 » NEET UG Study Material » Chemistry » Graham’s law
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Graham’s law

In this lecture, we are going to learn about Graham's law In brief with different examples.

Table of Content
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Graham’s Law, also known as Graham’s Law of Effusion, was developed by Thomas Graham in 1848 and became popular in 1849. Thomas Graham studied the effusion process and discovered an important characteristic: lighter gas molecules travel faster than heavier gas molecules.

r1/r2 = √M2/M1

Where, 

r1- rate effusion of gas 1

r2- rate effusion of gas 2

M1- Molar mass of gas 1

M2- Molar mass of gas 2

According to Graham’s Law, molecules or atoms with a lower molecular mass will effuse more quickly than molecules or atoms with a higher molecular mass at constant pressure and temperature, and vice versa. Thomas even figured out how quickly they dissipate through the air via diffusion. According to the law of inverse proportional proportionality, the rate of effusion of a gas is proportional to the square root of its molecular mass. When comparing the rates of two different gases operating at the same pressures and temperatures, this formula is usually used. An example of a formula is as follows:

a phenomenon that occurs when a single material moves from a high-concentration area to a low-concentration area. This means that the particles or molecules are evenly distributed throughout the medium. If you spray at one end of a room, for example, you will be able to smell it at the other end. This is due to the diffusion phenomenon.

What exactly is Graham’s law, and how does it operate?

Graham Law is a law firm that helps clients with a wide range of legal issues. The rate of effusion of a gaseous substance is inversely proportional to the square root of the substance’s molar mass. The square root of the inverse ratio of the molar masses of two gases is the ratio of the rates of diffusion or effusion of the two gases when they are in equilibrium, according to Graham’s law.

What is the most effective way to convey Graham’s law?

Graham’s law states that the rate of diffusion or effusion of a gas is proportional to the square root of the gas’s molecular weight.

Graham’s law was created by who?

Thomas Graham’s Laws of Diffusion and Effusion  is a pseudonym for Thomas Graham Graham’s Laws of Diffusion and Effusion  One of these physical properties can be observed when observing the movement of gases. Thomas Graham invented a device that is similar to the one used today to study gas diffusion the rate at which two gases mix in 1829.

Graham’s law of effusion: what is it and how does it work?

Graham’s law states that the rate at which a gas effuses is inversely proportional to the square root of the gas’s density.

What is Graham’s law’s significance?

Graham’s law is the foundation for isotope separation by diffusion, which was later used in the development of the atomic bomb and is still used today. When it comes to molecular effusion, which is the movement of one gas at a time through a hole in the ground, Graham’s law is the most accurate.

What are some examples of Graham’s rule in practice?

It helps to separate gases of different densities by separating them. It aids, among other things, in the separation of isotopes of certain elements. Through the use of rates, it assists in determining the molecular weight of an unknown gas.

What part of Graham’s law is required to explain why we smell?

Gas particles, according to this theory, are constantly moving in a random and rapid manner. Because the particles move in a random and rapid manner, when there is a sufficient number of particles in one central location, they will eventually spread out.

Is it possible to predict how a balloon’s size will change once it’s placed in an oven?

The frozen balloon had to shrink because the average kinetic energy of the gas molecules in a balloon decreases as the temperature of the gas molecules drops. As a result, the molecules move more slowly, resulting in fewer and weaker collisions with the inside wall of the balloon, causing the balloon to shrink slightly.

Is it possible to use different gas laws to explain the existence of LPA and HPA?

Yes, gas laws can explain the formation of LPA and HPA as long as the volume remains constant. High pressure areas form as the temperature rises, while low pressure areas form as the temperature falls.

What is the density calculation formula?

The formula p=m/V is used by the Density Calculator, which states that density (p) equals mass (m) divided by volume (V), or vice versa (V). The calculator can calculate the third value using any two of the other values. The amount of mass contained within a unit volume is defined as density.

Conclusion

As we studied that the lighter gas diffuses more quickly than expected, we were able to validate Graham’s Law through this article. This is in accordance with Graham’s Law, according to which the lighter the gas, the faster it diffuses. Additional Concerns Graham’s law states that if the temperature is changed, nothing happens because temperature is not a factor. When the molar masses are changed, however, the rate changes in an inversely proportional manner.

faq

Frequently Asked Questions

Get answers to the most common queries related to the NEET UG Examination Preparation.

What is Graham's law's practical application?

Ans: The application of Graham’s law in real life can be easily observed by lighting an incense stick and watc...Read full

For Graham's law of diffusion, which of the following relationships holds true?

Ans: Under similar temperature and pressure conditions, the rates of diffusion of gases are inversely proportional t...Read full

In Graham's law of diffusion, what is the formula for calculating time?

Ans: Let t1 and t2 denote the time it takes to pass the same volume of the two gases through the same pinhole at the...Read full

Ans: The application of Graham’s law in real life can be easily observed by lighting an incense stick and watching the molecules of smoke that are produced. This is due to the diffusion process, which causes the smoke from the burning incense stick to spread quickly throughout the surrounding area.

Ans: Under similar temperature and pressure conditions, the rates of diffusion of gases are inversely proportional to the square roots of their densities, according to the law.

Ans: Let t1 and t2 denote the time it takes to pass the same volume of the two gases through the same pinhole at the same temperature and pressure.

There are no changes in temperature or pressure, and both gases have the same molar volume.

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