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NEET UG 2026 » NEET UG Study Material » Chemistry » Ethanoic Acid
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Ethanoic Acid

Ethanoic acid (also known as acetic acid) is a two-carbon acid that is the second member of the carboxylic acid family after methanoic acid.

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Today, the majority of ethanoic acid is synthesised and used to make other important chemicals such as plastics. However, for thousands of years, it was only produced biologically by microbes known as acetic acid bacteria. 

This biologically produced acid is what we call vinegar, and it is the only type of ethanoic acid that Trading Standards allows to be labelled as vinegar in the UK. Chip shops can’t just put synthetically produced ethanoic acid in a bottle and call it vinegar – that’s technically ‘non-brewed condiment.’

To make what is known as “real vinegar,” a biological process similar to that used to make beer must be used. Acid-producing bacteria are round or rod-shaped bugs that thrive on grapes and winery barrels, where they spoil wine by converting the alcohol (ethanol) in it to acid. Winemakers deal with this issue by keeping the barrels airtight, because depriving bacteria of oxygen reduces their population.

Ethanoic acid definition

Ethanoic acid (also known as acetic acid) is a two-carbon acid that is the second member of the carboxylic acid family after methanoic acid (which is a one-carbon carboxylic acid).

Although ethanoic acid is the correct and technically correct IUPAC term for this acid, its common name, acetic acid, is frequently used as its IUPAC designation. Vinegar is a popular household product made from a 5-8 percent Ethanoic Acid solution in water. It is frequently used in kitchens. Ethanoic acid freezes throughout the winter, resembling a glacier; as a result, it is also known as glacial acetic acid and is a common laboratory chemical.

Chemical Properties of Ethanoic Acid

Esterification Reaction: When a carboxylic acid reacts with alcohol, esters are formed, which are a new chemical family. The chemical process that results in the production of esters is known as esterification. When Ethanoic Acid (a carboxylic acid) reacts with Ethanol (ethyl alcohol), ethyl ethanoate (an ester) is formed, as shown below:

CH3 COOH + CH3 CH2 OH → CH3 COOCH2 CH3

This reaction results in the formation of a new class of chemical compounds with a distinct fruity odour that makes them easily identifiable. Esters are used in the food industry as synthetic flavouring agents, and they are also used in the perfume industry for their pleasant scents. Aside from that, one of the most common applications of esters is in the production of soap. When esters react with any base (especially alkalis), a carboxylic acid salt (the basic molecular structure of soap) is formed. This process is known as the saponification reaction. This reaction works best with higher molecular weight esters.

Ethanoic acid physical properties

(i)Ethanoic acid is a liquid that smells like vinegar. Lower carboxylic acids are liquids, while higher carboxylic acids are solids.

(ii) Ethanoic acid has a sour taste. Other lower carboxylic acids have a sour taste as well.

(iii) The boiling point of ethanol is 391 K. The boiling points of carboxylic acids are higher than those of the corresponding alcohols, aldehydes, and ketones.

(iv) Acetic acid is soluble in water, which means it is miscible in all proportions with water. Lower carboxylic acids are soluble in water, but as molecular weight increases, solubility decreases.

(v) At 290 K, acetic acid freezes. As a result, acetic acid crystallisation can occur in cold weather, which is why pure acetic acid is known as glacial acetic acid.

Ethanoic acid uses

1.)It is used as a solvent in a number of processes that require an aprotic solvent.

2.)It is used to make vinegar, esters, and synthetic polymers.

3.)It is used in laboratories as a blood cell lysing agent.

4.)It is employed in the treatment of fungal infections.

5.)Soap Manufacturing: To make soap, animal fats or vegetable oils (olive oil, castor oil, or palm oil) are heated with sodium hydroxide or potassium hydroxide. To make soap, combine fat or vegetable oils with a strong sodium hydroxide solution and heat until soap and glycerol form. The process of making soap is known as the saponification reaction. Glycerol is a valuable byproduct of this process because it is used in the production of a wide range of chemical compounds, explosives, and pharmaceuticals.

Conclusion

Today, the majority of ethanoic acid is synthesised and used to make other important chemicals such as plastics. This biologically produced acid is what we call vinegar, and it is the only type of ethanoic acid that Trading Standards allows to be labelled as vinegar in the UK. Ethanoic acid is a two-carbon acid that is the second member of the carboxylic acid family after methanoic acid (which is a one-carbon carboxylic acid). Ethanoic acid freezes throughout the winter, resembling a glacier; as a result, it is also known as glacial acetic acid and is a common laboratory chemical. The chemical process that results in the production of esters is known as esterification.  Ethanoic acid is a liquid that smells like vinegar.

 
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Frequently asked questions

Get answers to the most common queries related to the NEET UG Examination Preparation.

In what ways is ethanoic acid used in everyday life?

Ans : Vinegar containing ethanoic acid is a common food ingredient. As a result, ethanoic acid is f...Read full

How acidic is ethanoic acid?

Ans : approximately pH 3 Carboxylic acids are, predict...Read full

How is ethanoic acid produced?

Ans : Ethanoic acid can be synthesised by oxidising ethanol (which is an alcohol ). In this case, o...Read full

What is the dissociation mechanism of ethanoic acid?

Ans : In water, ethanoic acid (acetic acid) dissociates to form the ethanoate (acetate) anion, and ...Read full

Ans : Vinegar containing ethanoic acid is a common food ingredient. As a result, ethanoic acid is found in many foods and food additives as a flavouring, a preservative, or both. Ethanoic acid, for example, is used in marinated meat or fish, as well as pickles or pickled vegetables in general.

 

Ans : approximately pH 3

Carboxylic acids are, predictably, acidic! Because they are only partially ionised in solution, they are weak acids. For example, 0.1M ethanoic acid has a pH of about 3, implying that only about 1 in 100 acid molecules is ionised.

Ans : Ethanoic acid can be synthesised by oxidising ethanol (which is an alcohol ). In this case, oxidation entails the addition of an oxygen atom and the removal of two hydrogen atoms.

 

Ans : In water, ethanoic acid (acetic acid) dissociates to form the ethanoate (acetate) anion, and water is protonated to form the hydronium cation. Because ethanoic acid is a weak acid, it is not completely dissociated in water, so this is depicted as an equilibrium.

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