Chemical Reactivity of Calcium Oxide with Oxygen

Calcium oxide, popularly known as quicklime, is a mineral that has been used since the Middle Ages. Quicklime is thought to be one of the earliest compounds known to mankind. It can also be known as charred lime or lime.

Calcium oxide has a medium viscosity, a high surface tension, and an expansion and contraction rate that ranges from fast to slow. At ceramic temperatures, this substance is not volatile. Calcium oxide has a minor effect on colour, except in high concentrations, where it may bleach iron oxide. It is also available in kaki/tomato reds.

Preparation  of Calcium Oxide 

1. Calcium oxide can be created in a lime kiln by thermal breakdown of materials containing calcium carbonate (CaCO₃; mineral calcite), such as limestone or seashells.
2. Calcination is the process through which burnt lime is produced. It is a procedure that begins by thermally decomposing the reactants at high temperatures while keeping the temperature much below the melting point.
3. Calcium carbonate undergoes calcination at temperatures ranging from 1070^oC to 1270^°C. These reactions are typically carried out in a rotary kiln. The reaction produces burnt lime and carbon dioxide as byproducts.

According to Le-principle, Chatelier’s the carbon dioxide that is created is quickly eliminated, so that the reaction is preceded until the process is completed.

CaCO₃ → CaO + CO₂

In the forward motion, this reaction is reversible and exothermic.

CaO Molecule Structure

Calcium oxide molecules are made up of one calcium cation (with a charge of +2) and one oxygen anion (which holds a charge of -2). The structure of calcium oxide is depicted in the diagram below.

Ca²⁺O^2-

Structure of Calcium Oxide

As a result, calcium oxide is an ionic molecule that contains an ionic link between calcium and oxygen.

Formula for Lime Water 

Ca(OH)₂ is the formula for lime water, while calcium hydroxide is the chemical name for lime water. When water is introduced to lime, calcium hydroxide Ca(OH)₂ is generated through the reaction shown below.

CaO + H₂O →  Ca(OH)₂

This reaction is very exothermic and results in the creation of clouds of steam.

What Is the Difference Between Lime Water and Quicklime?

CaO is the chemical formula for lime or quicklime. Calcium oxide is the chemical formula for lime. Limewater, on the other hand, has the chemical formula Ca(OH)₂ and the chemical name calcium hydroxide.

Properties of Calcium Oxide 

Quick lime is a white amorphous solid with a melting point of 2600°.

It is an extremely stable chemical that can tolerate extreme temperatures.

Slaked lime is formed in the presence of water. This is referred to as lime slaking.

CaO+H₂O → Ca(OH)₂

It is a basic oxide that creates salts when it comes into touch with an acid.

This chemical forms a cubic crystal structure when crystallised.

Calcium oxide has a standard molar entropy of 40 joules per mole kelvin.

When heated to temperatures above 2400 degrees Celsius, this chemical is known to create a bright glow.

CaO+H₂SO₄ → CaSO₄+H₂O

Calcium Oxide (CaO)

Molar Mass 56.0774 g/mol Density 3.34 g/cm3

Solubility

Water and glycerol are both soluble.

2.850 °C Boiling Point

2,572 °C melting point

Application  of Calcium Oxide 

1. It is widely used as a pesticide and in medicine.
2. It is used to make cement, paper, and high-quality steel.
3. Lime is employed as a reagent in laboratories for dehydration, precipitation processes, and other purposes.
4. It is the cheapest alkali available and is used in the manufacture of caustic soda.
5. Calcium is essential for animal life since it is found in bones, shells, and teeth. Calcium carbonate is the most prevalent calcium compound, and it is used by potters to generate calcium oxide for glazes.

Important Safety Tips

1. There are a few things that people should be aware of when dealing with Calcium Oxides.
2. In most cases, the reaction between quicklime and water is violent.
3. Quicklime can be extremely irritating, especially when inhaled or in touch with damp skin or eyes.
4. Sneezing, coughing, and laboured breathing are all side effects of inhalation.
5. Additionally, it can cause abdominal discomfort, nausea, burns with nasal septum rupture, and vomiting.
6. When quicklime combines with water, it produces enough heat to ignite flammable materials.

Conclusion 

The   high solubility of calcium oxide makes the production of phosphate-based cements challenging. Calcium oxide, on the other hand, can be transformed to less soluble compounds such as silicates, aluminates, or even hydro phosphates, which can then be employed in an acid-base reaction with phosphate.