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Lyophobic Multi-Molecular and Macromolecular Colloids

Lyophilic colloids:

  • Liquid-loving colloids are known as lyophilic colloids. There is a strong gravitational attraction between the friction cells and the fluid when these colloids are mixed with the appropriate fluid.
  • The potential difference between a solid particle’s surface and the majority of conductive fluid (such as water).
  • Association colloids are microscopic systems in which a group of molecules or ions of matter dissolved in a dispersion medium form colloid particles dispersed phase (mycelium).

Example:

Starch sol:

Using water as a dispersing medium, starch produces the lyophilic sol. Sol creation is sped it up by heating the medium, in this example water, to 100 degrees Celsius. It’s quite stable, and it’s unaffected by the presence of electrolyte impurities.

Lyophobic colloids:

Liquid-hating colloids are known as lyophobic colloids. The particles of the dispersed phase do not come into contact with the diffusion medium in lyophobic colloids, which are frictional solutions. By stirring with a dispersing media, the solid obtained by their precipitation cannot be turned back into a colloid solution.

Example:

iron(Fe(OH)3)(As2s3)

The distinction between the lyophilic colloids and lyophobic colloids:

Lyophilic colloids

Lyophobic colloids

These are solvent loving species

Solvent hating species

These can be prepared by very simple methods like shaking and warming

We cannot prepare easily

Reversible

Irreversible

Particles can not be seen

Particles can be seen under the microscope.

Surface tension lower than the dispersion medium

Surface Tension higher than the dispersion medium.

Colloid particles may not be charged.

Colloid particles are electrically charged.

Viscosity more than the dispersion medium

Viscosity is nearly the same as the dispersion medium.

It does not show the Tyndall effect

It shows the Tyndall effect.

Tyndall effect:

The Tyndall effect is a phenomenon in which light rays are directed at cells in a colloid scatter. All colloidal fluids and certain very fine suspensions exhibit this effect. As a result, it can be used to determine whether or not a given solution is colloidal. The density of the impact particles and the frequency of the incident light determine the intensity of the dispersed light.

The colloid particles in the solution prevent the light beam from passing entirely through the colloid as it goes through. Light is scattered when it collides with scattered particles (it deviates from its normal trajectory, which is a straight line). 

The Tyndall effect is light scattering’s effect on the friction amplitude, although it doesn’t exhibit light in the actual solution. This effect is used to identify whether a mixture is colloidal or a true solution.

Based on the type of particles present in the dispersed phase colloids are categorised as follows;

Multimolecular colloids:

A large number of atoms or small ones are dispersed in a dispersing medium when a substance is dispersed. Multimolecular colloids are generated when atoms of matter collide to form species with a range of degrees in the collision.

Example: 

Macromolecular colloids:

When large molecules termed macromolecules with a large molecular mass are dissolved in a suitable liquid, they produce a solution with macromolecules or colloids, which are matter molecules with size within the colloidal range.

Example: Nylon

Associated colloids: 

Aggregate particles, known as associative colloids, form when a substance with a high density is dissolved in a medium at low concentrations, it exhibits colloidal state features. Micelles are the aggregation cells that result from this process.

Conclusion:

Lyophilic colloids are those that prefer liquids. When these colloids are mixed with the proper fluid, there is a significant gravitational attraction between the friction cells and the fluid. Lyophobic colloids are those that hate liquid. In lyophobic colloids, the particles of the dispersed phase do not come into touch with the diffusion medium. When a substance is dispersed, it disperses a large number of atoms or a small number of atoms in a dispersing medium. When atoms of matter contact, they produce multimolecular colloids with a range of degrees of collision.When huge molecules with a large molecular mass are dissolved in a suitable liquid, macromolecules or colloids, which are matter molecules with size within the colloidal range, form a solution. 

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What are lyophobic colloids?

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