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Acids and Bases-Concept of Indicator

An indicator of acid-base, or pH, changes colour as the concentration of hydrogen ions changes. You will learn about the definition of acid-base indicators and how they're used to determine whether a solution is basic or acidic.

Analysing the Concept of Indicator  (acid-base indicators) can provide information about a chemical reaction’s completion. In other words, they determine when the response ends. Indicators come in a variety of types. Based on the pH value of the solution, acid-base indicators can absorb or emit different colours in acidic or alkaline mediums. The term acid-base indicator refers to measuring hydrogen ion concentration or neutralisation.

What is an Indicator?

Generally known as an indicator, it is a large organic compound similar to “colour dyes” and is often used as an indicator. The basic concept of markers is that they cannot be affected by acidic or basic conditions. There are a limited number of molecules called acid-base indicators whose behaviour will be affected by the number of hydrogen ions present in a solution. For the most part, acid-base indicators are used to determine the pH of solutions because they can indicate whether the solution is acidic or alkaline. As a rule, acidic symbols are used to indicate acidic solutions. A different concept of indicator turns different colours according to pH levels. 

An acid-base indicator’s pH range

There are different colours for acid-base indicators, which depend on the pH of the solution. Unlike an acid-base concept of indicator, which changes colour at a fixed pH, the pH range determines how the indicator changes colour.

A weak alkaline solution of phenolphthalein does not have colour. A colourless solution with a pH of between 8.0 and 9.8 is colourless, whereas a pink solution with a pH greater than 9.8 is considered an indicator. When pH values are reached, the indicator’s colour becomes different, which is a sign that an acid or base is reactive. With an acid-base indicator, one may be able to visually “indicate” the approximate pH of a sample.

It should be noted that acid-base indicators should have the same colour in all acidic solutions. An alkaline solution does not need to have the same colour as an acid-base indicator as it does with an acidic solution. A similar requirement does not apply to alkaline solutions as well.

A guide to Acid-Base Indicators

Acids and the bases of their conjugate acids are different colours when the indicator is a weak acid. A weak indicator will display different colours depending on the acid conjugated.

For example, phenolphthalein is colourless as a weak acid but is dissociated into a magenta or red-purple anion in water. When pH is low, the solution is colourless (not enough magenta anion is visible), but when pH is high, the equilibrium shifts to the left, and the magenta colour appears. 

The dissociation constant KIn is used here. At the point of equal concentrations of acid and anion base, the colour changes:

[HIn] = [In]

When it reaches this point, the concept of an indicator is 50% acid and 50% conjugate base.

Universal Indicator

A mixture that displays different colours in mediums with varying ph values can be prepared by mixing several indicators. Universal indicators are such mixtures. Five different indicators are mixed: methyl red, phenolphthalein, bromothymol blue, thymolphthalein, and -naphthalene. Depending on the pH, the mixture exhibits a different colour. For instance, Kolthoff can be viewed as a universal indicator.

Indicator Color Change: Molecular Basis

A more significant amount of confinement absorbs more blue light, and a lesser amount absorbs redder. A benzene molecule has three rings. A double bond comprises atoms with p orbitals that overlap with nearby atoms. A ‘pi bond’ is created when the overlap of two atoms allows electrons to be found in the p orbital on either atom. 

Acid-Base Indicators: Features

  • Chemicals used to measure aqueous solutions’ acidity, neutrality, and alkalinity are acid-base indicators. pH indicators are also known as acidity and alkalinity because they relate to pH.
  • Citrus juice, phenolphthalein, and litmus paper are acid-base indicators.
  • The colour of the indicator changes from period to period. Each concept of the indicator has a specific pH range over which it can be used. A good indicator for one solution might not be appropriate for another.
  • Some indicators can only tell about the ph of the base or an acid. Methyl orange, for example, only works at acidic pH values. It is the same colour at neutral and alkaline pH levels and above a certain pH (acidic).

Conclusion

Water can be acidic, basic, or alkaline by dissolving many substances. By using the concept of indicator, one can tell about the pH solution estimate. When titration is conducted to identify the endpoint of an acid-base reaction, acids-base indicators are most often used. They are also used in pH tests and colour-change demonstrations in science classes.