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CSIR NET EXAM » CSIR UGC-NET Exam Study Materials » Chemical Sciences » Physical Chemistry
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Physical Chemistry

Physical chemistry is the branch of chemistry concerned with material interactions and changes. Unlike other branches, it is concerned with the physical principles underlying all chemical interactions (e.g., gas laws), with the goal of measuring, correlating, and explaining the quantitative features of reactions.

Table of Content
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Physical Chemistry 

Physical chemistry is the branch of chemistry concerned with the study of matter’s behavior at the atomic or molecular level. It also entails the investigation of the properties of things at many scales, ranging from the macroscopic scale, which includes particles visible to the naked eye, to the subatomic scale, which comprises extremely small subatomic particles such as electrons.

Physical chemistry varies from other fields of chemistry in that it uses physics concepts and principles to comprehend chemical systems and processes. The various scales with which this discipline of chemistry works are described below.

We can research how molecules or atoms combine to generate specific compounds in the discipline of physical chemistry. We can also learn about the different qualities of matter, such as why a combination burns or how to turn a liquid to a solid. Without a doubt, this field is crucial in the realm of science, especially because it paves the way for the discovery of new hypotheses.

Theories are offered scientific explanations for what may be happening in our world. A theory, for example, may seek to explain why certain atoms in a molecule act in a certain way. In addition to this fundamental goal, physical chemistry has various sub-branches with their own distinct goals. Let’s go over some examples:

1.Electrochemistry is a subfield of physical chemistry that investigates how atoms, electrons, and ions interact in an electrical current.

2.Photochemistry investigates what happens when light is used in a chemical reaction.

3. Thermochemistry investigates why this chemical reaction produces heat.

4. Spectroscopy-:What happens to matter that emits radiation, according to spectroscopy?

5.Chemical kinetics investigates how quickly a chemical reaction occurred.

The Macroscopic Scale

The macroscopic scale includes substances that are large enough to be seen with the naked eye (without the help of optical instruments to provide a magnified view). On the macroscopic scale, certain essential quantities are dealt with:

1.Points of melting and boiling

2.The linear thermal expansion coefficient

3.vaporisation latent heat

4.Fusion enthalpy

In the case of a water molecule, the macroscopic scale is concerned with its physical state (solid, liquid, or gaseous) but not with its chemistry.

The  Microscopic Scale

The microscopic scale is concerned with qualities of things that can only be observed by the human eye when magnified by optical equipment such as microscopes.

This scale includes the study of crystal forms and formations. The structures of crystals influence the behavior of massive sections of crystals used in bridges and airplanes.

The Atomic  Scale

1.At the atomic scale, the properties of matter differ from one element to the next.

2.Some elements, however, have comparable properties and are placed together in the periodic chart.

3.Atomic mass and atomic number are two examples of matter properties examined at the atomic scale in physical chemistry.

4.The atomic radii of elements can be used to calculate the bond length between two atoms in a molecule.

The Subatomic Scale

1.The study of particles smaller than the size of atoms, known as subatomic particles, takes place on the subatomic scale.

2.The dual nature of particles at this scale is why subatomic particles are sometimes referred to as waves or energy.

3.At the most advanced level, physical chemistry involves the study of subatomic particles.

4.The study of these particles has relevance in nuclear chemistry as well.

As the name implies, physical chemistry employs physics-related techniques, theories, and concepts to explain various aspects of chemistry. Temperature and pressure, for example, have an impact at the macroscopic and microscopic levels, but their impact lessens at the atomic and subatomic dimensions.

Branches of Physical Chemistry

The key principles of physical chemistry are the ways in which physics can be used to explain or solve chemical problems. The following sections cover some of the fields of physical chemistry that investigate these issues.

Spectroscopy is a discipline of physical chemistry that studies the interaction of materials with electromagnetic radiation.

Quantum chemistry investigates the strength and forms of chemical bonds, as well as the movement of atom nuclei.

Chemical thermodynamics investigates the spontaneity of a chemical reaction as well as the features of chemical mixtures.

Chemical kinetics is concerned with the feasibility and rate of chemical reactions, as well as a variety of other parameters that influence reaction rates, such as the presence of a catalyst or the concentration of reactants.

Physical chemistry, as described above, is a very broad part of chemistry that has been divided into various disciplines in order to apply physics in the study of certain aspects of chemistry.

Conclusion

We conclude that a physical change affects the physical qualities of the substance, whereas a chemical change affects the chemical properties of the substance. Physical change does not result in the formation of new substances, whereas chemical change results in the formation of new substances.

faq

Frequently asked questions

Get answers to the most common queries related to the CSIR Examination Preparation.

What exactly is physical chemistry?

Ans. Physical chemistry is a field of chemistry concerned with understanding chemical systems through the use of physics concepts.

What are the main subfields of physical chemistry?

Ans. The key branches of physical chemistry are thermodynamics, quantum chemistry, and physical spectroscopy.

In physical chemistry, what properties of materials are explored at the atomic scale?

Ans. Physical chemistry investigates atomic mass and atomic number at the atomic scale.

Why is physical chemistry so important?

Ans. Physical chemistry is essential to understanding the other branches of chemistry. It provides a basis for under...Read full

How does physical chemistry apply to everyday life?

Ans. Physical chemistry is a part of our everyday life. The batteries in our vehicles use the principle of electroch...Read full

Ans. Physical chemistry is a field of chemistry concerned with understanding chemical systems through the use of physics concepts.

Ans. The key branches of physical chemistry are thermodynamics, quantum chemistry, and physical spectroscopy.

Ans. Physical chemistry investigates atomic mass and atomic number at the atomic scale.

Ans. Physical chemistry is essential to understanding the other branches of chemistry. It provides a basis for understanding the thermodynamic influences (principally, the entropy changes accompanying reactions) that drive chemical reactions forward.

Ans. Physical chemistry is a part of our everyday life. The batteries in our vehicles use the principle of electrochemistry. The photosynthetic process of green plants is an example of physical chemistry applied by biological systems. Solar devices change energy from sunlight into electrical energy.

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