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CBSE Class 12 » CBSE Class 12 Study Materials » Chemistry » Corrosion
CBSE

Corrosion

When a metal deteriorates due to chemical interactions with its surroundings, this is called corrosion.

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Corrosion is a natural process that changes a refined metal into a stable chemical state like oxide, hydroxide, or sulphide. It is the slow degradation of materials (often metals) caused by chemical and electrochemical interactions with their environment. It corrodes and deteriorates the material by reducing its strength, appearance, and durability.

Corrosion

Corrosion is a typical occurrence in our daily lives. You’ve probably seen that some iron things have an orange or reddish-brown coloured coating on top of them at some point. This layer forms as a result of rusting, a kind of corrosion.

In general, corrosion converts refined metals into more stable compounds such as metal oxides, metal sulphides, or metal hydroxides. Similarly, iron rusting is caused by iron oxides due to air moisture and oxygen. When we examine the underlying science of corrosion, we may conclude that it is a spontaneous/irreversible process in which metals transform into far more stable chemical compounds such as oxides, sulphides, hydroxides, and so on. In this lesson, we will go deeper into the idea of corrosion and learn about its various aspects, such as its meaning, kinds, prevention and more.

What causes corrosion?

Let us now the corrosion meaning. The surface of reactive metal is progressively attacked by moisture and air in the surrounding environment, resulting in the formation of a compound on the metal’s surface as a consequence. The metal seems dull due to the compound developed on its surface. Water, air, and (in rare situations) chemicals (such as acids and alkalis) may eat away at the metal, which is known as corrosion.

Different Factors leading to Corrosion

  • The electrochemical series is essential in corrosion because it determines the position of the metals within it. Higher-reactive metals corrode faster as electrons are lost to the environment more quickly than lower-reactive metals. The difference between gold and iron is that gold is less reactive than iron. As an example, iron oxidises rapidly, whereas gold does not.
  • Corrosion caused by impurities in metals – The presence of contaminants in metals typically enhances the corrosion rate because these pollutants operate as a miniature electrochemical cell, causing pollution to occur.
  • Due to the presence of electrolytes in water, the dissolved salt in the water functions as an electrolyte, conducting ions between the two molecules. Because of electrolytes in water, the corrosion rate is sped up significantly.
  • The concentration of oxygen – As the concentration of oxygen increases, the rate of corrosion increases. Regional oxygen concentrations are lower in anode regions than in cathode regions, and the reverse is true for cathode regions. Corrosion happens as a result of this process.
  • Moisture in the air and high temperatures combine to enhance corrosion rate when humid weather. As ions gain energy and begin to move quicker as the temperature rises, they collide more frequently and cause more corrosion.

Types of Corrosion

Corrosion can be classified into several types:

  • Galvanic corrosion is the form of corrosion that happens when two metals with differing electrochemical charges are joined together by a conductive route, resulting in a corrosion reaction. During this process, metal ions are transferred from the anodic metal to the cathodic metal. The weaker and less resistant anodic metal loses ions to the stronger and more positively charged cathodic metal.
  • Intergranular corrosion happens when one impure metal is present in the mixture of pure metals. Whenever metal is formed from a mixture of alloys with varying charges, one of the metals is susceptible to corrosion.
  • Stress-corrosion cracking (SCC) is corrosion that can cause irreparable damage to a component. Extreme tensile stress, such as that induced by cold work, welding, and thermal treatment, can cause fractures to grow in a metal component, which can then serve as a target for additional corrosion.
  • In electrochemical corrosion, rust is the cause of this condition. After being exposed to water for an extended period, steel suffers from surface oxidation and a thin film of rust forms on its surface.
  • Localised corrosion occurs when a tiny component comes into contact with corrosion-causing stress exclusive to that component. In part because the corrosion occurs at a considerably quicker pace than the corrosion that occurs elsewhere on the component, and because the corrosion occurs in conjunction with other processes such as stress and fatigue, the outcome is far worse than the effect of only stress or fatigue.
  • Caustic corrosion is the corrosion of a material caused by an acidic agent that happens when impure gas, liquid, or particles wear away the substance’s surface. When these gases are exposed to moisture, they break down and condense into caustic droplets that are hazardous to human health. In this category of caustic agents, hydrogen sulphide comes to mind as an example.
  • Cavitation corrosion happens when vapour bubbles form due to low pressure. When the bubbles collapse on a surface, the protective oxide is damaged and worn away, and then the protective oxide is regenerated and reestablished. A series of deep holes characteristic of cavitation corrosion is produced on the surface due to this process being repeated several times. It is possible to see them on the trailing edge when looking at impellers and propellers.

Protection Against Rust Corrosion

To avoid massive losses, preventing corrosion is critical. Metals make up the vast bulk of the buildings we encounter and utilize daily. This includes bridges, autos, machines, domestic products like window grills, doors, and railway lines. Though corrosion damage to metallic things may be a severe problem, there are a variety of treatments that can delay or even prevent it. Particularly vulnerable materials like metals and plastics are treated this way. There are many techniques for prevention of corrosion that are widely used include:

  • Electroplating \sGalvanization \sAnodization
  • Passivation
  • Anti-Corrosion Protective Coatings for Biofilm
  • Painting and lubricating automobiles.
  • Use of corrosion inhibitors or dehydrating agents
  • Metal surfaces need to be cleaned at least once a year.

Conclusion

This article looked at how metals erode or degrade and how many elements contribute to this deterioration. Some of the preventive steps that may be taken to improve the quality and longevity of metals were also investigated. Natural corrosion happens to metal and non-metals, and it makes a dry, flaky layer on their surface that makes them break down. There are a lot of different metals and alloys that we use in our daily lives that have this kind of thing in them.

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