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CBSE Class 12 » CBSE Class 12 Study Materials » Chemistry » Chemistry » Dinitrogen
CBSE

Dinitrogen

Dinitrogen is a chemical molecule created when two nitrogen atoms form a covalent bond.

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Dinitrogen is a chemical molecule created when two nitrogen atoms form a covalent bond. That is pure nitrogen with two atoms. Because of the temperature and pressure, it is a colourless, odourless gas that accounts for approximately 78 per cent of the Earth’s atmosphere.

Dinitrogen, denoted by the symbol (N2), is the most stable form of nitrogen, also known as molecular nitrogen or nitrogen gas, in which two nitrogen atoms are connected by a triple covalent bond that fulfils the Lewis electron rules; the two lone, non-bonding electron pairs on each N atom are located at a deficient energy level.

Fundamental properties of dinitrogen (gaseous dinitrogen)

  • In nature, nitrogen is colourless, odourless, and diamagnetic.
  • It is a harmless gas.
  • It is just very slightly soluble in water.
  • Nitrogen condenses to generate a colourless liquid that solidifies to form a snow-like pile.

Chemical characteristics of dinitrogen (gaseous dinitrogen)

  • Due to the N = N bond, Dinitrogen has a high bond enthalpy. As a result, it is entirely inert at ambient temperature. However, when the temperature rises, the reactivity increases. Nitrogen molecules react with metals to generate ionic nitrides and non-metals to form covalent nitrides at elevated temperatures.

6Li+N2→2Li3N

  • At around 773 K, Haber’s Process combines with hydrogen to generate ammonia.

N2(g)+3H2(g) ↔ 2NH3(g)

  • When a nitrogen molecule combines with an oxygen molecule at a temperature of 2000 K, nitric oxide is generated.

N2(g)+O2(g)↔2NO(g)

Dinitrogen preparation

  • Air is liquefied and fractionally distilled to produce nitrogen for commercial use. Essentially, there are just two phases to this procedure:

Step 1: A high pressure of between 100 and 200 atmospheres is applied. After being compressed, the air is inflated using a small jet. Liquid air is produced as a consequence of this operation is performed over and over again.

Step 2: The resultant liquid is subjected to fractional distillation. A lower boiling point for Dinitrogen than for liquid oxygen causes it to be separated from the mixture. Nitrogen is extracted from the contaminated liquid.

  • Ammonium chloride and sodium nitrite combine to form dinitrogen in an aqueous solution.

NH4Cl(aq) + NaNO2(aq) → N2(g)+ 2H2O(l) + NaCl(aq)

  • The resulting products contain NO and HNO3, which can be eliminated using ammonium dichromate heat decomposition. Another way of purifying the gaseous mixture is to run it via sulphuric acid containing potassium dichromate.

(NH4)2Cr2O7 → N2+ 4H2O+ Cr2O3

  • Pure nitrogen is also formed when sodium or barium azide is decomposed at a high temperature.
  • Industrial nitrogen gas is produced using cryogenic fractional distillation of liquefied air, adsorption separation of gaseous atmosphere, or membrane permeation. Cryogenic distillation of philosophy is the earliest technique of making nitrogen invented in 1895.

Advantages of dinitrogen (nitrogen pentoxide uses)

  • Nitrogen cools your tyre’s running temperature.
  • Nitrogen is more stable than oxygen.
  • Nitrogen enhances the quality of the ride.
  • Nitrogen extends the life of tires.
  • When a tyre is subjected to extreme temperatures, its pressure increases.

Use of dinitrogen

  • It is primarily utilised in the industrial manufacture of ammonia, calcium cyanamide, and other chemicals.
  • It creates an inert environment in industrial industries such as iron and steel.
  • Liquid nitrogen is employed as a preservative and a refrigerant in the food industry. Nitrogen gas production has many applications, particularly in the oil and gas industry. The following section discusses some essential applications for industrial nitrogen.

Incredible Facts About Dinitrogen

  • Dinitrogen is generated when two nitrogen atoms establish a covalent connection.
  • Titan’s atmosphere is primarily composed of Dinitrogen.
  • It occurs naturally in the atmosphere, the oceans, and rivers, as well as in soils.
  • It was named after the Greek words nitron, which means “native soda,” and genes, which means “forming.”
  • Organic materials, foods, fertilisers, explosives, and toxins contain nitrogen molecules. While it is necessary for life, an excess of it can be detrimental to the ecosystem.
  • Nitrogen, which is an odourless and colourless gas, is considered inert.
  • It is not combustible.
  • Once at average temperature, nitrogen gas is somewhat lighter than air.
  • Nitrogen accounts for 75% of the air we breathe.

Conclusion

Dinitrogen is an extremely inactive molecule, and scientists have long wished for a gentle technique of turning this large molecule into valuable chemicals, a process known as ‘fixing’ nitrogen. By covalently bonding N2 to a metal, the nitrogen is ‘activated,’ sometimes weakly and sometimes more powerfully. It is one of the most critical molecules for human life, as it is involved in various biological activities such as cellular respiration.

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Ans: The de Broglie principle states that matter, like light, may behave as waves and particles (photons). As a result, each particle will have a wavelength that corresponds to its wave behaviour.

Ans: De Broglie developed his groundbreaking idea of electron waves, which he had previously published in scientific publications, in this thesis (1924). … Experiments have shown that the electron must travel around a nucleus and that its mobility is restricted for reasons that were then unknown.

Ans: Dual behaviour of matter indicates that material particles at the atomic scale act as particles in certain conditions and as waves in others.

Ans: The matter has a twofold character, according to the de Broglie idea of matter waves. It means that while matter is moving, wave qualities (such as interference, diffraction, and so on) are linked with it, and when matter is at rest, particle properties are associated with it. As a result, the matter has a dual character.

Ans: Light and other electromagnetic radiations have a dual nature, namely particle and wave. Wave Radiation’s Nature: Radiation is a type of energy that may be transported from one place in space to another. The velocity of the wave is defined as the distance travelled by the wave in one second.

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