If you ask what is Colloidal solutions and suspensions are, they are a mix of substances suspended in a regular pattern in a fluid. A colloid or colloidal system is a dispersion of one substance (the dispersed phase) in another (the dispersion medium), where the dispersed-phase has the same order as the medium but on a much smaller scale. At this small scale, it is believed that large particles are continuous with each other and the rest on the medium. The dispersed-phase parts of a colloid are called sols, and the medium is usually called the solvent.
This allows some substances to dissolve in certain solvents; for example, milk and water are well known colloids whose dispersed phase (sol) is very finely divided. In the case of fog, the dispersed phase is water (liquid), while the dispersion medium is various gases. We can’t detect scattered phase particles in colloids with our naked eyes since they’re so tiny.
Colloidal systems come in three states such as liquid, solid and gas. On the other hand, a colloidal solution is considered to be a liquid mix. The size of the component parts distinguishes a genuine solution from a colloidal solution.
Colloidal solutions are created of particles that are of size from 1 nm to 500 nm, and in between is the size of real solution and colloidal suspension. In multiple cases, it is also considered a heterogeneous system and is in two phases, whereas in different states, it is called a homogenous system.
A colloid’s particles preferentially absorb ions and gain an electric charge. A colloid’s particles all have the same charge (either positive or negative) and are hence repellent to one another. Electrophoresis is the process of charged colloidal particles moving toward an oppositely charged electrode when an electric potential is applied to them. The particles may precipitate out of the suspension if their charge is neutralised. Another colloid with oppositely charged particles can be used to precipitate a colloid.
The particles then come together to coagulate and then spread out. The ions in saltwater precipitate the properties of a colloid silt spread in river water, making a delta; the ions in seawater precipitate the colloidal silt dispersed in river water, generating a delta.
Electric precipitators are used to remove colloidal particles (such as smoke, dust, and fly ash) from exhaust gases, according to a process invented by F. G. Cottrell.
Lyophilic colloids | Lyophobic colloids |
dispersed phase’s affinity for the dispersion medium | |
There is a high affinity for the dispersion medium from the dispersed phase. | The dispersed phase has zero affinity for the dispersion medium. |
Preparation of the colloidal suspension | |
Preparation is easy. It requires the dispersed phase to be mixed, shaken or heated with the dispersion medium. | Preparation is tedious and requires unique methods and the intervention of electrolytes for stabilisation of the procedure. |
The stability of the colloidal suspension | |
Lyophilic colloids are highly stable. | Lyophobic colloids are unstable. |
Reversibility | |
The addition of the dispersion medium results in the reconstitution of the suspension, and hence they are reversible. | Colloidal suspensions are irreversible, and once they are precipitated, they cannot be reconstituted by adding a dispersion medium. |
Solvation of the dispersed phase | |
In lyophilic colloids are highly solvated and are covered by a layer of the dispersion medium. | Dispersed phases in lyophobic colloids are not solvated. |
The surface tension of the dispersed phase | |
is lower than the dispersion medium. | The surface tension of the dispersed phase is the same as the dispersion medium. |
The viscosity of the dispersed phase | |
is much higher than the dispersion medium. | The viscosity of the dispersed phase is the same as the dispersion medium. |
Visibility of particles | |
There is zero visibility of particles even under an ultramicroscope. | Particles are detectable under an ultramicroscope. |
Migration of particles | |
may occur in either direction, or migration would not occur in an electric field as they are not carriers of any form of charge. | Migration of particles occurs towards the cathode or anode in an electric field as they are carriers of a charge. |
Reaction with electrolytes | |
The addition of electrolytes in small quantities has no effect. | Coagulation takes place as a result of the addition of electrolytes. |
Hydration | |
Results in extensive hydration | Does not result in hydration |
Examples | |
Gum, starch, etc. | Metals like Silver (Ag) and Gold (Au), hydroxides like aluminium hydroxide Al(OH3), ferric oxyhydroxide Fe(OH)3 metal sulphides like arsenic trisulfide As2S3 , etc. |
Colloidal Solution Properties
The name colloid is derived from the terms colla and oids. Glue is referred to as ‘Kolla,’ while something comparable to glue is referred to as ‘Oids.’ Particles in colloidal solutions are bigger than those found in sugar or salt solutions in water, but smaller than those seen in suspensions.Colloids are widely employed in meals and the food industry. Many of the foods we consume are colloidal in nature. Cheese, milk and other dairy products are some examples.Colloidal particles have an extremely tiny size. The size of their particles ranges from 1 to 1000 nanometers.It demonstrates the Tyndall effect. It scatters the light and reflects its route across itself.Colloidal solutions are highly stable since they do not settle down when left undisturbed for a long period.Filtration will not be able to separate them.