The d-block of the periodic table lies from group-3 to group-12. There are mainly three series transition metals, 3d series(Sc to Zn), 4d series(Y to Cd) and 5d series (La to Hg, omitting Ce to Lu).
The d-block occupies the larger middle section flanked by s-block and p-block. Electronic Configuration is defined as the distribution of electrons of atoms or molecules in an atomic or molecular orbital. Electronic Configuration is represented by 2(n2) where n is the shell number.
Electronic configurations are the summary of where the electrons are around the nucleus. The electronic configuration of an atom in a shell atomic model may be expressed by indicating the number of electrons beginning with first. The electronic configuration of an atom in the quantum mechanical model is stated by listening to the occupied orbitals, in order of filling, with the number of electrons in each orbital indicated by superscript. The electronic configuration of d-block elements is represented by (n-1) (d0-10) n(s1-2). d- block elements can find stability in half-filled orbital or completely filled full orbital.
The general properties of d-block elements are:
The transition elements consist of 4 rows of 10 elements. These rows are called first, second, third and fourth transition series which involve filling of 3d, 4d, 5d and 6d orbitals respectively.
The first transition series elements start from Scandium, Sc (Z= 21) to Zinc, Zn (Z = 30).
Element | Symbol | Atomic number | Electronic configuration |
Scandium | Sc | 21 | [Ar]3d14s2 |
Titanium | Ti | 22 | [Ar]3d24s2 |
Vanadium | V | 23 | [Ar]3d34s2 |
Chromium | Cr | 24 | [Ar]3d54s1 |
Manganeses | Mn | 25 | [Ar]3d54s2 |
Iron | Fe | 26 | [Ar]3d64s2 |
Cobalt | Co | 27 | [Ar]3d74s2 |
Nickel | Ni | 28 | [Ar]3d84s2 |
Copper | Cu | 29 | [Ar]3d104s1 |
Zinc | Zn | 30 | [Ar]3d104s2 |
The second transition series consists of elements from yttrium, Y (Z=39) to cadmium, Cd (Z=48).
Element | Symbol | Atomic number | Electronic configuration |
Yttrium | Y | 39 | [Kr]4d15s2 |
Zirconium | Zr | 40 | [Kr]4d25s2 |
Niobium | Nb | 41 | [Kr]4d45s1 |
Molybdenum | Mo | 42 | [Kr]4d55s1 |
Technetium | Tc | 43 | [Kr]4d55s2 |
Ruthenium | Ru | 44 | [Kr]4d75s1 |
Rhodium | Rh | 45 | [Kr]4d85s1 |
Palladium | Pd | 46 | [Kr]4d105s0 |
Silver | Ag | 47 | [Kr]4d105s1 |
Cadmium | Cd | 48 | [Kr]4d105s2 |
This series consists of elements of lanthanum (Z=57) and all the elements from hafnium (Z=72) to mercury (Z=80). This series involves the filling of 5d orbitals.
Element | Symbol | Atomic number | Electronic configuration |
Lanthanum | La | 57 | [Xe]5d16s2 |
Hafnium | Hf | 72 | [Xe]4f145d26s2 |
Tantalum | Ta | 73 | [Xe]4f145d36s2 |
Tungsten | W | 74 | [Xe]4f145d46s2 |
Rhenium | Re | 75 | [Xe]4f145d56s2 |
Osmium | Os | 76 | [Xe]4f145d66s2 |
Iridium | Ir | 77 | [Xe]4f145d76s2 |
Platinum | Pt | 78 | [Xe]4f145d96s1 |
Gold | Au | 79 | [Xe]4f145d106s1 |
Mercury | Hg | 80 | [Xe]4f145d106s2 |
It involves the filling of 6d-subshells starting from actinium (Z=89). It includes elements with atomic number 104 onwards.
Element | Symbol | Atomic number | Electronic configuration |
Actinium | Ac | 89 | [Rn]6d17s2 |
Rutherfordium | Rf | 104 | [Rn]5f146d27s2 |
Hafnium | Ha | 105 | [Rn]5f146d37s2 |
Seaborgium | Sg | 106 | [Rn]5f146d47s2 |
Bohrium | Bh | 107 | [Rn]5f146d57s2 |
Hassium | Hs | 108 | [Rn]5f146d67s2 |
Meitnerium | Mt | 109 | [Rn]5f146d77s2 |
Darmstadtium | Ds | 110 | [Rn]5f146d87s2 |
Roentgenium | Rg | 111 | [Rn]5f146d107s1 |
Copernicium | Cn | 112 | [Rn]5f146d107s2 |
Electronic configuration of iron is [Ar]3d64s2 . Iron has an atomic number of 26 which means the number of electrons present in iron is 26 and it belongs to group eight of the periodic table. Iron is also known as the second most abundant metal which is present in the crust of the earth. The electronic configuration of iron is1s 2 2s 2 2p 6 3s 2 3p 6 3d 6 4s 2.
Electronic configuration of the d block is divided into four series and the d block lies from group-3 to group-12 of the periodic table. The electronic configuration of elements makes the study of electrons easy and understandable for the students. The d block elements have high melting and boiling point and also form coloured compounds with other elements of the periodic table. Configuration of iron plays an important role in the study of iron. In the end, we conclude that electronic configuration is a very important aspect of the periodic table as it makes the study and discovery of new elements easy.